Differential absorption measurements of mesospheric and lower thermospheric electron densities using the Buckland Park MF radar

The differential absorption experiment (DAE) was first proposed in the 1950s for the estimation of mesospheric and lower thermospheric electron density using MF/HF radars. The technique was used extensively until the late 1970s, when interest in the technique declined, due to experimental limitations and questions regarding the assumptions of the technique. This paper describes the application of the DAE within the online observations of the Buckland Park MF (BPMF) radar. The experimental limitations of the technique for the BPMF radar are discussed, with particular attention paid to effects of complex gain differences between receiving channels used to decompose the linearly received signals into circular components. Hourly and monthly averaged midday DAE electron densities are presented, revealing good agreement with IRI model estimates. Monthly averaged midnight DAE electron densities are also presented, revealing good qualitative agreement with the IRI model estimates.     

Multivariate statistical analysis of geochemical data as indicative of the hydrogeochemical evolution of groundwater in a sedimentary rock aquifer system

The study of groundwater hydrogeochemistry of the Paleozoic Basses-Laurentides sedimentary rock aquifer system in Québec produced a large geochemical dataset. Groundwater samples were collected at 153 sites over a 1500 km² study area and analyzed for major and minor ions. The large number of data can lead to difficulties in the integration, interpretation and representation of the results. Two multivariate statistical methods, hierarchical cluster analysis (HCA) and principal components analysis (PCA), were applied to a subgroup of the dataset to evaluate their usefulness to classify the groundwater samples, and to identify geochemical processes controlling groundwater geochemistry. This subgroup consisted of 144 samples and 14 parameters (Ca²⁺, Mg²⁺, Na⁺, K⁺, , Cl⁻, , Fe²⁺, Mn²⁺, Br⁻, Sr²⁺, F⁻, Ba²⁺, HS⁻). Seven geochemically distinct clusters, C1–C7, resulted from the HCA. Samples from clusters C3, C4, C6 and C7 are mostly located in preferential recharge areas. The majority of these samples have Ca–Mg–HCO₃ recharge groundwater (C3, C6, C7) and Na–HCO₃ evolved groundwater (C4). Samples from the other three clusters (C1, C2, C5) are characteristic of an aquifer system under confined conditions. The majority of these samples have Na–HCO₃ evolved groundwater (C1, C5) and Na–Cl ancient groundwater that exhibits elevated concentrations in Br⁻ (C2). In addition to recognizing the importance of hydrogeological conditions on groundwater geochemistry, the distribution of clusters also showed the importance of the geological formations on minor and trace elements, such as Fe²⁺, Mn²⁺, Sr²⁺, F⁻ and Ba²⁺. The first five components of the PCA account for 78.3% of the total variance in the dataset. Component 1 is defined by highly positive loadings in Na⁺, Cl⁻ and Br⁻ and is related to groundwater mixing with Champlain Sea water and solute diffusion from the marine clay aquitard. The high positive loadings in Ca²⁺ and Mg²⁺ of component 2 suggest the importance of dissolution of carbonate rocks in this aquifer system. From their characteristic loadings, the first two components are defined as the “salinity” and “hardness” components, respectively. Components 3–5 are related to more local and geological effects. The integration of the HCA and the PCA, with conventional classification of groundwater types, as well as with the hydrogeological and geological contexts, allowed the division of the region into four main geochemical areas, providing an improved regional picture of the aquifer system dynamics and hydrogeochemical evolution of groundwater. The following factors were recognized as influencing the evolution of groundwater identified in every geochemical area: (1) geological characteristics including sedimentary rock type and till mineralogy; (2) hydrogeological characteristics represented by the level of confinement and the hydraulic gradient; and (3) the geological history including the latest glaciation and the Champlain Sea invasion. With its integrated approach, this hydrogeochemical study contributes to the characterization and understanding of complex groundwater flow systems, and provides an example of the long-term geochemical evolution of hydrogeological systems after a major perturbation, in this case seawater invasion.     

Bacterial dominance of phototrophic communities in a High Arctic lake and its implications for paleoclimate analysis

The phototrophic communities in meromictic, perennially ice-covered Lake A, on Ellesmere Island in the Canadian High Arctic, were characterized by pigment analysis using high performance liquid chromatography. Samples were taken to determine the vertical changes down the water column as well as a variation between years. These analyses showed that Lake A had distinct phototrophic communities in its oxic and anoxic layers. The pigment analyses indicated that phototrophic biomass in the upper, oxic waters was dominated by picocyanobacteria, while in the lower, anoxic layer photosynthetic green sulphur bacteria were dominant. Interannual variation in pigment concentrations was related to the penetration of photosynthetically active radiation in the water column, suggesting that light availability may be limiting the net accumulation of photosynthetic bacterial biomass in Lake A. Pigment analysis of the surface sediments indicated that deposition was dominated by the photosynthetic sulphur bacterial contribution. The sedimentary record of bacterial pigments in polar meromictic lakes offers a promising tool for the reconstruction of past changes in ice cover and therefore in climate.     

Sedimentary pellets as an ice-cover proxy in a High Arctic ice-covered lake

Sediment aggregates (“sedimentary pellets”) within the sedimentary record of Lake A (83°00′ N, 75°30′ W), Ellesmere Island, Canada, are used to construct a 1000 year proxy record of ice-cover extent and dynamics on this perennially ice-covered, High Arctic lake. These pellets are interpreted to form during fall or early winter when littoral sediment adheres to ice forming around the lake’s periphery or during summer through the development of anchor ice. The sediment likely collects in ice interstices and is concentrated in the upper ice layers through summer surface ice melt and winter basal ice growth. The pellets remain frozen in the ice until a summer or series of summers with reduced ice cover allows for their deposition across the lake basin. Sedimentary pellet frequency within multiple sediment cores is used to develop a chronology of ice-cover fluctuations. This proxy ice-cover record is largely corroborated by a record of unusual sedimentation in Lake A involving iron-rich, dark-orange to red laminae overlying more diffuse laminae with a lighter hue. This sediment sequence is hypothesized to represent years with reduced ice cover through increased chemocline ventilation and iron deposition. During the past millennium, the most notable period of inferred reduced ice cover is ca. 1891 AD to present. Another period of ice cover mobility is suggested ca. 1582–1774 AD, while persistent ice cover is inferred during the 1800s and prior to 1582 AD. The proxy ice-cover record corresponds well with most regional melt-season proxy temperature and paleoecological records, especially during the 1800s and 1900s.

The cosmological dependence of galactic specific angular momenta

Hydrodynamical simulations of galaxy formation in spatially flat cold dark matter (CDM) cosmologies with and without a cosmological constant (Λ) are described. A simple star formation algorithm is employed and radiative cooling is allowed only after redshift z =1 so that enough hot gas is available to form large, rapidly rotating stellar discs if angular momentum is approximately conserved during collapse. The specific angular momenta of the final galaxies are found to be sensitive to the assumed background cosmology. This dependence arises from the different angular momenta contained in the haloes at the epoch when the gas begins to collapse and the inhomogeneity of the subsequent halo evolution. In the Λ-dominated cosmology, the ratio of stellar specific angular momentum to that of the dark matter halo (measured at the virial radius) has a median value of ∼0.24 at z =0. The corresponding quantity for the Λ=0 cosmology is over three times lower. It is concluded that the observed frequency and angular momenta of disc galaxies pose significant problems for spatially flat CDM models with Λ=0 but may be consistent with a Λ-dominated CDM universe.     

Roughness length in the turbulent Ekman layer above the sea bed

Roughness lengths were determined from average current profiles in the logarithmic boundary layer at a site in the southern North Sea. Grab samples indicated that the bed configuration controlling the bed roughness was unlikely to change even at maximum spring tides, but the measured roughness lengths were found to decrease as the speed of the flow 10 m above the bed increased. This has been qualitatively interpreted in terms of the size of the turbulent eddies within the flow and their effectiveness at “feeling” the size of the elements forming the bed roughness. It is also shown that the dependence of the observed drag coefficient on the Rossby number follows closely the theoretical form when the roughness length decreases with increasing flow speed.     

Assessment of groundwater recharge processes through karst vadose zone by cave percolation monitoring

Recharge processes of karst aquifers are difficult to assess given their strong heterogeneity and the poorly known effect of vadose zone on infiltration. However, recharge assessment is crucial for the evaluation of groundwater resources. Moreover, the vulnerability of karst aquifers depends on vadose zone behaviour because it is the place where most contamination takes place. In this work, an in situ experimental approach was performed to identify and quantify flow and storage processes occurring in karst vadose zone. Cave percolation monitoring and dye tracing were used to investigate unsaturated zone hydrological processes. Two flow components (diffuse and quick) were identified and, respectively, account for 66% and 34% of the recharge. Quickflow was found to be the result of bypass phenomenon in vadose zone related to water saturation. We identify the role of epikarst as a shunting area, most of the storage in the vadose zone occurring via the diffuse flow component in low permeability zones. Relationship between rainfall intensity and transit velocity was demonstrated, with 5 times higher velocities for the quick recharge mode than the diffuse mode. Modelling approach with KarstMod software allowed to simulate the hybrid recharge through vadose zone and shows promising chances to properly assess the recharge processes in karst aquifer based on simple physical models.     

Ecometrics and the paleoecological implications of Pleistocene faunas from the western coastal plains of the Cape Floristic Region,South Africa

The Pleistocene ungulate communities from the western coastal plains of South Africa's Cape Floristic Region (CFR) are diverse and dominated by grazers, in contrast to the region's Holocene and historical faunas, which are relatively species-poor and dominated by small-bodied browsers and mixed feeders. An expansion of grassy habitats is clearly implied by the Pleistocene faunas, but the presence of ruminant grazers that cannot survive the summer dry season typical of the region today suggests other important paleoecological changes. Here we use dental ecometrics to explore the paleoecological implications of the region's Pleistocene faunas. We show that the dental traits (hypsodonty and occlusal topography) of the ungulates that occurred historically in the CFR track annual and summer aridity, and we use these relationships to reconstruct past aridity. Our results indicate that the Pleistocene faunas signal paleoenvironments that were on average less arid than today, including during the summer, consistent with other lines of evidence that suggest a higher water table and expansion of well-watered habitats. Greater water availability can be explained by lower temperature and reduced evapotranspiration during cooler phases of the Pleistocene, probably coupled with enhanced groundwater recharge due to increased winter precipitation.     

Sulfide mineralogy and redox conditions in some shergottites

Abstract— Magmatic sulfide mineralogy has been studied in 2 olivine‐phyric shergottites (DaG 476 and SaU 005) and 4 basaltic shergottites (Zagami, Shergotty, Los Angeles, and NWA 480). Modal abundances of magmatic sulfides, as estimated by image analysis on thin section, are high (0.16 to 0.53 area percent) and correlate positively with abundances of Fe‐Ti oxides. Sulfides are mesostasis minerals, being mostly interstitial grains or locally enclosed in post‐cumulus melt inclusions (e.g., SaU 005) in olivine. Sulfides in shergottites are composed of major pyrrhotite containing pentlandite exsolutions associated with minor amounts of Cu sulfides (chalcopyrite and/or cubanite). Hot desert finds (e.g., DaG 476) show abundant fracture‐filling iron (oxy)hydroxides of probable terrestrial origin. Unaltered sulfides show metal‐rich hexagonal pyrrhotite compositions with metal/sulfur (M/S) ratio ranging between 0.936 ± 0.005 and 0.962 ± 0.01. This compositional range corresponds to the two‐phase structural domain 2C + nC of the Fe‐S system; however, the high‐temperature disordered hexagonal 1C pyrrhotite structure would be in better agreement with magnetic properties of shergottites. Ni contents in pyrrhotite increase from Los Angeles (<0.05 at%) to Shergotty, Zagami, and NWA 480 (0.2–0.5 at%), and DaG 476 and SaU 005 (up to 3 at%). The higher Ni values of pyrrhotite in olivine‐phyric shergottites correlate with the abundance of pentlandite exsolutions, both reflecting more primitive Ni‐rich sulfide liquids where abundant olivine crystallized. This result and the strong correlation between sulfide abundances and Fe‐Ti oxides argue for a primary magmatic origin of these sulfides. Although they reproduce the trend of magmatic oxygen fugacity conditions determined from Fe‐Ti oxide pairs, observed pyrrhotite compositions are systematically more metal‐deficient compared to those calculated from the Fe‐S‐O system. This suggests post‐magmatic oxidation during cooling on Mars, followed by terrestrial weathering for hot desert finds.