Spatio-temporal dynamics of heavy metals in sediments of the river estuarine system: Mahanadi basin (India)

Dynamics of heavy metals in the surface sediments of Mahanadi river estuarine system were studied for three different seasons. This study demonstrates that the relative abundance of these metals follows in the order of Fe > Mn > Zn > Pb > Cr > Ni ≥ Co > Cu > Cd. The spatial pattern of heavy metals supported by enrichment ratio data, suggests their anthropogenic sources possibly from various industrial wastes and municipal wastes as well as agricultural runoff. The metal concentrations in estuarine sediments are relatively higher than in the river due to adsorption/accumulation of metals on sediments during saline mixing, while there is a decreasing trend of heavy metal concentrations towards the marine side. The temporal variations for metals, such as Fe, Mn, Zn, Ni and Pb exhibit higher values during monsoon season, which are related to agricultural runoff. Higher elemental concentrations are observed during pre-monsoon season for these above metals (except Ni) at the polluted stations and for metals, such as Cr, Co and Cd at all sites, which demonstrate the intensity of anthropogenic contribution. R-mode factor analysis reveals that “Fe–Mn oxy hydroxide”, “organic matter”, “CaCO₃”, and “textural variables” factors are the major controlling geochemical factors for the enrichment of heavy metals in river estuarine sediment and their seasonal variations, though their intensities were different for different seasons. The relationships among the stations are highlighted by cluster analysis, represented in dendrograms to categorize different contributing sites for the enrichment of heavy metals in the river estuarine system.     

Utilization of ochre as an adsorbent to remove Pb(II) and Cu(II) from contaminated aqueous media

The ability of ochre to remove Pb(II) and Cu(II) from aqueous media has been studied by batch sorption studies varying the contact time, initial metal concentration, initial solution pH and temperature to understand the adsorption behaviour of these metals through adsorption kinetics and isotherms. The pH of the solution and the temperature controlled the adsorption of metal ions by ochre and rapid uptake occurred in the first 30 min of reaction. The kinetics of adsorption followed a pseudo-second-order rate equation (R ² > 0.99) and the isotherms are well described by the Freundlich model. Adsorption of metals onto ochre is endothermic in nature. Between the two metals, Pb(II) showed more preference towards the exchangeable sites on ochre than Cu(II). This study indicates that ochre is a very effective adsorbent in removing Pb(II) and Cu(II) from the aqueous environment with an adsorptive capacity of 0.996 and 0.628 mg g^?1 and removal efficiency of 99.68 and 62.80 %, respectively.     

Mangrove sediments a sink for heavy metals? An assessment of Muthupet mangroves of Tamil Nadu,southeast coast of India

Mangrove forests are one of the most productive and biodiverse wetlands on earth. Yet, these unique coastal tropical forests are among the most threatened habitats in the world. Muthupet mangroves situated in the southeastern coast of India, has a reverse “L” shaped structure. Four cores were collected in 2008, sliced and subsampled at 2.5 cm length. The heavy metals (Mn, Cu, Zn, Ni, Pb, Cr, Cd) and other associated geochemical parameters were evaluated to determine pollution history of Muthupet. An evaluation of the status of heavy metal pollution through the index analysis approach was attempted by computing geoaccumulation index, anthropogenic factor, enrichment factor, contamination factor and degree of contamination, pollution load index and metal pollution index. To compensate for the natural variability of heavy metals in the core sediments, normalization using Al was carried out so that, any anthropogenic metal contributions may be detected and quantified. Results of the study reveal that significant metal contamination exists, and all the metals are found to be higher than continental crustal values. The fine sediments of Muthupet vary between uncontaminated and moderately contaminated with almost no enrichment (EF < 1) to severe enrichment (EF > 10). On comparison, the core collected close to aquafarms and dense mangrove forest (C3) is the most polluted core and the core retrieved where minor rivers drain (C2) is the least polluted.     

Environmental characteristics of tropical coral reef-seagrass dominated lagoons (Lakshadweep,India) and implications to resilience to climate change

Environmental characteristics of the coral reef-seagrass ecosystem of selected Lakshadweep Islands (India) were assessed with a view to understanding the future climate change scenario in the region. Images obtained from the Indian remote sensing satellite (IRS P6) were used to identify the different zones such as the corals, the seagrass and the sandy region. The pH (7.6–8.6) of sediment was relatively high in the coral reef compared to the seagrass area, possibly indicating a climate shift-induced coral bleaching. The water quality and sediment texture generally showed marked intra- and inter-island variations illustrating that these coral reef ecosystems are highly vulnerable to climate change brought about by increased human interventions. Future research should therefore explore the habitat and resource connections, to predict their restoring capabilities for a sustainable exploitation. With an alarming increase in the population and associated developmental activities, the island ecosystems are expected to respond severely to the climate change, which may eventually lead to mass mortality of corals due to bleaching.     

New approach for interpretation of scattered ground magnetic data in a part of Delhi Fold Belt-NW Indian shield

Randomly distributed ground magnetic data sets, collected along parallel and closely spaced profiles, in small blocks, the blocks being separated/distributed widely over a large area, become, sometimes, unamenable for deriving a meaningful geological model. In such a situation, an approach of “Cumulative Total Intensity Magnetic Anomaly Field (CTIMAF)” has been devised to interpret the sparsely distributed magnetic data sets. A case history has been presented from the lead–zinc mineralized provenance of Ajabgarh Formation of Delhi Fold Belt in the northern part of Ajmer Town. Log-normalized radially averaged power spectrum was computed for the Cumulative Total Intensity Magnetic Anomaly data and depth to the basement is derived. The computed depth of 4.5 km is in good agreement with the Deep Seismic Studies.     

Remote Sensing based assessment of glacial lake growth on Milam glacier,Goriganga basin,Kumaon Himalaya

The climate change of the twentieth century had an evident effect on glacier environments of the Himalaya. Temporal images of Indian Remote Sensing satellites provide an opportunity to monitor the recession of glacier and development of glacial lakes in the Himalayan cryosphere with a cost to time benefit ratio. The recession of Milam glacier and subsequent growth of a proglacial lake near the snout was analysed using Resourcesat-1 and Resourcesat-2 data. The recession of 480 m during 2004 to 2011 and growth of 47 epiglacial ponds over Milam glacier shows the glacier is in a state of imbalance and losing the ice by downwasting.     

Lithospheric structure below transantarctic mountain using receiver function analysis of TAMSEIS data

The lithospheric structure of Antarctica has been investigated from P- (PRF) and S- receiver functions (SRF) using the seismological data from Trans-Antarctic Mountain Seismic Experiment (TAMSEIS). For the stations deployed on the thick ice sheet, estimation of crustal parameters from PRF may be erroneous as the Moho conversions may interfere with the reverberations within the thick ice sheet. However, the free surface multiples are well observed in PRF. On the other hand, in SRFs, the primary conversions of interest and multiples are separated by the mother S-phase. Therefore, it is advantageous to interpret PRF and SRF jointly for the regions where we have thick low velocity layer at the top such as ice or sediments. The crustal structure and corresponding parameters have already been estimated by various workers, but here we interpret the PRF and SRF jointly to minimize the ambiguity and map the lithospheric architecture below TAM. Our analysis reveals that the average crustal thickness beneath the east Antarctica craton is ～44 km with Vp/Vs ranging between ～1.7 and 1.9. Below Trans-Antarctic Mountain (TAM), the average crustal thickness is ～36 km with higher Vp/Vs of ～1.8–2.0. The rift and the volcanic affected coastal region show erratic depths and Vp/Vs, primarily due to the absence of either primary conversion or multiples in the receiver functions. A small number of stations far from the volcano show that the crust is thinnest (～26 to 34 km thick) in the coastal part. The contribution of this study is the mapping of the lithospheric configuration, not done so far using SRF. The SRF section along a profile spanning E-, W- Antarctica and TAM reveals that the lithospheric thickness in the coast is ～80 km and below TAM it is ～120 km. In the central thick ice cover region, the lithosphere thickens upto ～150 km towards Vostok highlands. The most intriguing feature in our SRF section is that the crust and lithosphere are shallow below TAM compared to the E- Antarctica. Further, we observe a mid-lithospheric low velocity layer confined mostly below TAM, suggesting that the thermal buoyancy could be the prime cause for the upliftment of TAM.     

Nine years of GPS measurements of crustal deformation at Imphal,Indo-Burmese wedge

We report results of 9 years of GPS measurements of crustal deformation at Imphal, Manipur, a site located in the Indo-Burmese wedge of northwest Sunda arc. The analysis of these measurements suggests that the site moves at a rate of about 36.3±0.5 mm/year towards N55° in the ITRF2008. With respect to the Indian plate it moves at a rate of 16.7 mm/year towards N222°, i.e., predominantly towards southwest. The site is located about 15 km east of the Churachandpur Mao fault (CMF), which is reported to accommodate part of the India-Sunda motion. The site motion is not significantly affected by the earthquakes that occurred in the nearby region. However, the 2004 Sumatra-Andaman earthquake caused a coseismic displacement of ～ 3–5 mm predominantly towards southwest. The site motion is almost linear, with some seasonal variation, and does not show any evidence of accelerated slip or slow earthquake on the CMF or along the plate boundary.     

Estimation of specific yields of individual litho-units in a terrain with multiple litho-units: A water balance approach

In a terrain with more than one litho-unit, the traditional water balance approach provides a single spatially averaged specific yield. A methodology is proposed here, which can be applied to estimate specific yields of individual litho-units in such terrains. This approach is demonstrated here considering two watersheds, which are covered partly by limestone and partly by sandstone. Watershed wise specific yields were estimated using a traditional water balance method. The specific yields thus obtained are the volume-weighted averages of the specific yields of the individual litho-units in the watersheds. Based on the volumes of aquifers desaturated and the watershed wise specific yield values, a set of two linear equations in two variables was formulated. These linear equations were solved to get the specific yields of the individual litho-units. Specific yields of sandstone (Chandarpur Group) and limestone (Charmuria Formation) units in the study area were thus estimated to be 0.004 and 0.037 respectively.