A comparative study of three methods for the determination of iodate in seawater

A comparative study of three methods for the determination of iodate-iodine in seawater is described. In one method the iodate is determined polarographically while in the others the iodate is determined colorimetrically as iodonium ions. In one of the colorimetric methods each sample is pre-treated with excess iodine-water in an attempt to eliminate suspected interference from naturally occurring reducing agents. The tests were conducted on a selection of open-ocean and near-shore waters with iodate concentrations ranging from 0 to 60 μg 1^?1-I. The tests indicated that the polarographic method and the colorimetric method without iodine-water give the more reliable measurement of iodate concentration. Also, the method with iodine water was found to be in error especially at low iodate concentrations. Reducing agents, if present, were found not to interfere significantly.     

High to low velocity succession in the upper crust related to tectonic emplacement: Tras os Montes-Galicia (Iberia), Brittany and Limousin (France)

Summary. Seismic probing of the upper crust in a catazonal massif in Tras os Montes, Hercynian Iberia, demonstrates the absence of a root towards the lower crust and favours a mechanism of thrust and nappe emplacement. Similar high to low velocity successions in the upper crust are evidenced in particular segments of the Hercynian domain of France. All these occurrences are related to a type region to which a particular meaning has been given in a recent plate tectonics interpretation of the Hercynian orogenesis. This model, implying large-scale nappe displacement and intracrustal thrusts furnishes in turn a general mechanism for the tectonic formation of upper crustal high and low velocity layers of limited extent in orogenic cycles.     

THE AMUR-YAKUTSK MAINLINE: A SOVIET CONCEPT OR REALITY?

The assimilation of Siberia's northeast frontier has been a subliminal goal of Soviet planners since the 1930s, but economic problems, including inaccessibility, have thwarted their aim at almost every turn. The completion of the Baykal-Amur Mainline (BAM) and the renewed planning and construction of the Amur-Yakutsk Mainline (AYAM) at first promised to inspire new regional development efforts. The new policies of the Gorbachev administration appear to have altered the course, at least temporarily. This article analyzes these developments and relationships.     

High-latitude methane sulphonic acid variability and solar activity: the role of the total solar irradiance

The direct impact of solar activity on climate has been widely studied through Total Solar Irradiance (TSI). Biological processes also impact climate and are deeply affected by TSI. Marine phytoplankton emissions into the atmosphere have been proposed to change cloud albedo through cloud formation. In this work, we use wavelet analysis to investigate the decadal relation between high-latitude concentrations of methane sulphonic acid, a product of seawater algae, and TSI. We found that some of the methane sulphonic acid main periodicities coincide with periods of solar activity periods.     

A mixed finite element/control volume model of wind-driven circulation in lakes

A three-dimensional numerical circulation model is described. The model is based on non-linear hydrodynamic equations, modified according to hydrostatic and Boussinesq approximations. A space-splitting scheme is used for numerical approximations of governing equations. The simple hypothesis on elliptic stream functions shape is utilized to reconstruct the near-surface wind field. The calculated currents correspond reasonably well with observed velocities in different locations lake-wide.     

Structure and tectonic history of the foreland basins of southernmost South America

The common elements and differences of the neighboring Austral (Magallanes), Malvinas and South Malvinas (South Falkland) sedimentary basins are described and analyzed. The tectonic history of these basins involves Triassic to Jurassic crustal stretching, an ensuing Early Cretaceous thermal subsidence in the retroarc, followed by a Late Cretaceous–Paleogene compressional phase, and a Neogene to present-day deactivation of the fold–thrust belt dominated by wrench deformation. A concomitant Late Cretaceous onset of the foreland phase in the three basins and an integrated history during the Late Cretaceous–Cenozoic are proposed. The main lower Paleocene–lower Eocene initial foredeep depocenters were bounding the basement domain and are now deformed into the thin-skinned fold–thrust belts. A few extensional depocenters developed in the Austral and Malvinas basins during late Paleocene–early Eocene times due to a temporary extensional regime resulting from an acceleration in the separation rate between South America and Antarctica preceding the initial opening of the Drake Passage. These extensional depocenters were superimposed to the previous distal foredeep depocenter, postdating the initiation of the foredeep phase and the onset of compressional deformation. Another pervasive set of normal faults of Paleocene to Recent age that can be recognized throughout the basins are interpreted to be a consequence of flexural bending of the lithosphere, in agreement with a previous study from South Malvinas basin. Contractional deformation was replaced by transpressive kinematics during the Oligocene due to a major tectonic plate reorganization. Presently, while the South Malvinas basin is dominated by the transpressive uplift of its active margin with minor sediment supply, the westward basins undergo localized development of pull-apart depocenters and transpressional uplift of previous structures. The effective elastic thickness of the lithosphere for different sections of each basin is calculated using a dynamic finite element numerical model that simulates the lithospheric response to advancing tectonic load with active sedimentation.     

The relative impact of climate change and urban expansion on peak flows: a case study in central Belgium

An essential part of hydrological research focuses on hydrological extremes, such as river peak flows and associated floods, because of their large impact on economy, environment, and human life. These extremes can be affected by potential future environmental change, including global climate change and land cover change. In this paper, the relative impact of both climate change and urban expansion on the peak flows and flood extent is investigated for a small‐scale suburban catchment in Belgium. A rainfall‐runoff model was coupled to a hydrodynamic model in order to simulate the present‐day and future river streamflow. The coupled model was calibrated based on a series of measured water depths and, after model validation, fed with different climate change and urban expansion scenarios in order to evaluate the relative impact of both driving factors on the peak flows and flood extent. The three climate change scenarios that were used (dry, wet winter, wet summer) were based on a statistical downscaling of 58 different RCM and GCM scenario runs. The urban expansion scenarios were based on three different urban growth rates (low, medium, high urban expansion) that were set up by means of an extrapolation of the observed trend of urban expansion. The results suggest that possible future climate change is the main source of uncertainty affecting changes in peak flow and flood extent. The urban expansion scenarios show a more consistent trend. The potential damage related to a flood is, however, mainly influenced by land cover changes that occur in the floodplain. Copyright © 2011 John Wiley & Sons, Ltd.     

Derivation of detrital rutile in the Yaoundé region from the Neoproterozoic Pan-African belt in southern Cameroon (Central Africa)

Rutile, as an important component in alluvial or eluvial heavy mineral deposits, is known in southern Cameroon. These deposits are underlain by the Neoproterozoic low- to high-grade Yaoundé Group. Geochemical, thermometric, fluid inclusion and Pb isotopic studies of the rutile from alluvial and eluvial concentrates and from medium-grade micaschist from the nearby Yaoundé region permit the following conclusions: (1) alluvial and eluvial rutile of the Yaoundé region are derived from the degradation of metapelites, metamafic rocks and pegmatites of the nearby Yaoundé Group; (2) rutile in the Yaoundé Group formed during the Pan-African metamorphism, or was inherited as detrital rutile from a 900 Ma source. The study also shows that the rutile can be used to trace the history of the Pan-African belt north of the Congo craton.     

Building a VO-compliant Radio Astronomical DAta Model for Single-dish radio telescopes (RADAMS)

The Virtual Observatory (VO) is becoming the de-facto standard for astronomical data publication. However, the number of radio astronomical archives is still low in general, and even lower is the number of radio astronomical data available through the VO. In order to facilitate the building of new radio astronomical archives, easing at the same time their interoperability with VO framework, we have developed a VO-compliant data model which provides interoperable data semantics for radio data. That model, which we call the Radio Astronomical DAta Model for Single-dish (RADAMS) has been built using standards of (and recommendations from) the International Virtual Observatory Alliance (IVOA). This article describes the RADAMS and its components, including archived entities and their relationships to VO metadata. We show that by using IVOA principles and concepts, the effort needed for both the development of the archives and their VO compatibility has been lowered, and the joint development of two radio astronomical archives have been possible. We plan to adapt RADAMS to be able to deal with interferometry data in the future.