Complete Tertiary exhumation history of the Menderes massif, western Turkey: an alternative working hypothesis

The main exhumation of the Menderes massif, western Turkey, occurred along an originally N‐dipping Datça–Kale main breakaway fault that controlled depositions in the Kale and the Gökova basins during the Oligocene – Early Miocene interval. The isostatically controlled upward bending of the main breakaway fault brings the lower plate rocks to the surface. In the Early Miocene, E–W‐trending N‐ and S‐dipping graben‐bounding faults fragmented the exhumed, dome‐shaped massif. The development of half grabens by rolling master fault hinges has allowed further exhumation of the central Menderes massif. After the Pliocene, high‐angle normal faults cut all of the previous structures. This model suggests that the Menderes massif is a single large metamorphic core complex that has experienced a two‐stage exhumation process.     

Surface Geophysical Methods used to Verify the Karst Geological Structure in the Built-up Area: A Case Study of Specific Engineering-Geological Conditions

This article presents a research study of complex limestone karst engineering-geological conditions in the municipality Valaská near Banská Bystrica in Slovakia. The aim of the study is to demonstrate the impossibility of spatial identification of cave spaces using surface geophysical methods due to the specific engineering-geological conditions of a thick surface layer of anthropogenic fill containing highly heterogeneous anthropogenic material. Its maximum thickness is 3 m. Another specificific condition of the study area is its location in the built-up area, due to which the applicability of geophysical methods was limited. The article contains methodological recommendations to be used in analogous geological conditions with karst structures topped with anthropogenic fill, which complicates the identification of cave spaces. The recommended solution herein is the identification of the cave system using underground mapping of the karst and its projection onto the surface for which surface geophysical methods have been combined.     

Zoobenthos of Lake Uluabat,a Ramsar Site in Turkey,and Their Relationship with Environmental Variables

The numerical and proportional distributions of zoobenthos in lake Uluabat, which is located in the Northwestern part of Turkey and having international importance according to the Ramsar Convention, were determined from August 2004 to July 2005 at monthly intervals (except for December 2004, January and February 2005) at 12 different stations. Thirty‐three taxonomic groups were recorded. It was found that the zoobenthos consisted of 35.6 % Oligochaeta, 27.7 % Nematoda, 12.3 % Chironomidae larvae, 10.7 % Gastropoda, 3.6 % Ostracoda, and 10.1 % Varia by numbers (Bivalvia, Ceratopogonidae, Hirudinea, Odonata, Ephemeroptera, Asilidae, Hydraacarina, Hemiptera, Argulidae, and Gammaridae). The average number of invertebrates was 160 individuals for 33 taxa at the 12 different stations. Also some environmental parameters of the lakewater were analyzed (temperature, pH, dissolved oxygen, biochemical oxygen demand, chemical oxygen demand, NO₂–N, NO₃–N, NH₃–N, PO₄^–3, fecal coliform, and total coliform). The relationships between the dynamics of the Oligochaeta and the physicochemical variables were supported by the Pearson correlation index and the canonical correspondence analysis (CANOCO). It was found that the relation between the average number of P. hammoniensis and P. albicola (p < 0.05, r = 0.590 and 0.593, respectively) and L. hoffmeisteri (p < 0.01, r = 0.777) was directly proportional while the relation between the average number of some taxa Trichodrillus sp., Rhyacodrilus coccineus, Nais communis, N. variabilis, and N. barbata and NO₃–N (p < 0.05, r = –0.685) was inversely proportional.     

Late orogenic crustal extension in the northern Menderes massif (western Turkey): evidence for metamorphic core complex formation

The Simav metamorphic core complex of the northern Menderes massif, western Turkey, consists of a plutonic (Tertiary) and metamorphic (Precambrian) core (footwall) separated from an allochthonous cover sequence (hanging wall) by a low-angle, ductile-to-brittle, extensional fault zone (i.e. detachment fault). The core rocks below the detachment fault are converted into mylonites with a thickness of a few hundred metres. Two main deformation events have affected the core rocks. The first deformational event (D₁) was developed within the Precambrian metamorphic rocks. The second event (D₂), associated with the Tertiary crustal extension, includes two distinct stages. Stage one is the formation of a variably developed ductile (mylonitic) deformation (D_2d) in metamorphic and granitic core rocks under greenschist facies conditions. The majority of the mylonites in the study area have foliations that strike NNW to NNE and dip SW to SE. Stretched quartz and feldspar grains define the mineral lineation trending SW-NE direction and plunging gently to SW. The kinematic indicators indicate a top-to-NE sense of shear. Stage two formation of brittle deformation (D_2b) that affected all core and cover rocks. D_2b involves the development of cataclasites and high-angle normal faults. An overall top towards the north sense of shear for the ductile (mylonitic) fabrics in the core rocks is consistent with the N-S regional extension in western Turkey.     

Carbon dioxide segregation in 1:4 and 1:9 CO2:H2O ices

The mid-infrared spectra of mixed vapor deposited ices of CO₂ and H₂O were studied as a function of both deposition temperature and warming from 15 to 100 K. The spectra of ices deposited at 15 K show marked changes on warming beginning at 60 K. These changes are consistent with CO₂ segregating within the ice matrix into pure CO₂ domains. Ices deposited at 60 and 70 K show a greater degree of segregation, as high as 90% for 1:4 CO₂:H₂O ice mixtures deposited at 70 K. As the ice is warmed above 80 K, preferential sublimation of the segregated CO₂ is observed. The kinetics of the segregation process is also examined. The segregation of the CO₂ as the ice is warmed corresponds to temperatures at which the structure of the water ice matrix changes from the high density amorphous phase to the low density amorphous phase. We show how these microstructural changes in the ice have a profound effect on the photochemistry induced by ultraviolet irradiation. These experimental results provide a framework in which observations of CO₂ on the icy bodies of the outer Solar System can be considered.     

Stabilization of Expansive Clays Using Granulated Blast Furnace Slag (GBFS) and GBFS-Cement

Expansive clays undergo swelling when subjected to water. This can cause damage, especially to light weight structures, water conveyance canals, lined reservoirs, highways, and airport runways unless appropriate measures are taken. In this study, granulated blast furnace slag (GBFS) and GBFS-cement (GBFSC) were utilized to overcome or to limit the expansion of an artificially prepared expansive soil sample (sample A). GBFS and GBFSC were added to sample A in proportions of 5–25% by weight. The effects of these stabilizers on grain size distribution, Atterberg limits, swelling percentage and rate of swell of soil samples were determined. GBFS and GBFSC were shown to successfully decreasing the total amount of swell while increasing the rate of swell.     

Regional rating curve models of suspended sediment transport for Turkey

Estimations of annual suspended sediment loads are required for various types of water resources studies. Often estimation of the sediment load is needed for ungauged watersheds. Regionalization methods provide a practical solution to solve such problems. The purpose of this study is to classify suspended sediment yields in watersheds into homogeneous regions in order to identify their regional sediment rating curves. This study has been carried out for suspended sediment stations on 26 main basins of Turkey. Long term-scale suspended sediment rating curves of 115 gauging stations in Turkey were classified using cluster analysis on the basis of hydrological homogeneity. An agglomerative hierarchical clustering algorithm is used so that stations from different geographical locations are considered in the same cluster independently of their geographical location. 115 gauging stations were clustered into 4 different homogenous regions and the regional suspended sediment rating curve was developed for each region. The performance efficiencies of the developed regional rating curves were evaluated for 8 test stations and compared to the performances of rating curves in test sites. A regionalization model is developed for estimating suspended sediment rating curves for ungauged sites in Turkey. The developed regional rating curve models result in very close performances to those of their corresponding site rating curves.     

Photochemistry of methane-water ices

We report a study on the broadband ultraviolet photolysis of methane-water ice mixtures, at low methane concentrations and temperatures relevant to the icy satellites of the outer Solar System. The photochemistry of these mixtures is dominated by the action of hydroxyl radicals on methane and the resulting products. This implies that, given sufficient exposure time, the methane will eventually be completely oxidized to carbon dioxide. The presence of methane inhibits the formation of hydrogen peroxide by serving as a trap for hydroxyl radicals. The distribution of photochemical products is broadly similar to that previously conducted using ion and electron sources, with some differences possibly attributable to the difference in radiation source. The results are applicable to a variety of icy bodies in the Solar System. On Enceladus, where methane mixed with water is measured in the plumes, methane in the surface ices is subject to oxidation and will eventually be converted to CO₂. The CH stretch feature detected in the VIMS spectra of the Enceladus surface ice suggests that methane is currently being supplied to the surface ice, likely from re-condensation of the plume gas.     

Probability distributions for carbon emissions and atmospheric response

Probability distributions for carbon burning, atmospheric CO₂, and global average temperature are produced by time series calibration of models of utility optimization and carbon and heat balance using log-linear production functions. Population growth is used to calibrate a logistically evolving index of development that influences production efficiency. Energy production efficiency also includes a coefficient that decreases linearly with decreasing carbon intensity of energy production. This carbon intensity is a piecewise linear function of fossil carbon depletion. That function is calibrated against historical data and extrapolated by sampling a set of hypotheses about the impact on the carbon intensity of energy production of depleting fluid fossil fuel resources and increasing cumulative carbon emissions. Atmospheric carbon balance is determined by a first order differential equation with carbon use rates and cumulative carbon use as drivers. Atmospheric CO₂ is a driver in a similar heat balance. Periodic corrections are included where required to make residuals between data and model results indistinguishable from independently and identically distributed normal distributions according to statistical tests on finite Fourier power spectrum amplitudes and nearest neighbor correlations. Asymptotic approach to a sustainable non-fossil energy production is followed for a global disaggregation into a tropical/developing and temperate/more-developed region. The increase in the uncertainty of global average temperature increases nearly quadratically with the increase in the temperature from the present through the next two centuries.