The influence of carbon on trace element partitioning behavior

Carbon has been proposed as a potential light element in planetary cores, included in models of planetary core formation, and found in meteoritic samples and minerals. To better understand the effect of C on the partitioning behavior of elements, solid/liquid partition coefficients (D = (solid metal)/(liquid metal)) were determined for 17 elements (As, Au, Co, Cr, Cu, Ga, Ge, Ir, Ni, Os, Pd, Pt, Re, Ru, Sb, Sn, and W) over a range of C contents in the Fe-Ni-C system at 1 atm. The partition coefficients for the majority of the elements increased as the C content of the liquid increased, an effect analogous to that of S for many of the elements. In contrast, three of the elements, Cr, Re, and W, were found to have anthracophile (C-loving) preferences, partitioning more strongly into the metallic liquid as the C content increased, resulting in decreases to their partition coefficients. For half of the elements examined, the prediction that partitioning in the Fe-Ni-S and Fe-Ni-C systems could be parameterized using a single set of variables was not supported. The effects of S and C on elemental partitioning behavior can be quite different; consequently, the presence of different non-metals can result in different fractionation patterns, and that uniqueness offers the opportunity to gain insight into the evolution of planetary bodies.     

Environmental impact of the 1.8 ka Taupo eruption, New Zealand: Landscape responses to a large-scale explosive rhyolite eruption

Large-scale ignimbrite eruptions from rhyolitic caldera volcanoes can trigger geologically instantaneous changes in sedimentary systems over huge areas by either burying existing environments or overloading them with vast quantities of unconsolidated particulate material. The post-eruption readjustment of the landscape to such perturbations is one of the most dramatic processes in physical sedimentology, exemplified here by the 1.8 ka Taupo eruption in the central North Island of New Zealand. This eruption generated voluminous fall deposits, then climaxed with emplacement of a c. 30 km³ non-welded ignimbrite over a near-circular area of c. 20 000 km². Approximately 90% of the area, but < 50% of the ignimbrite volume, is represented by a landscape-mantling unit that covered the pre-eruption topography to a depth varying from c. 10 m in proximal areas to less than 15–30 cm distally. The remainder of the ignimbrite deposit is represented by landscape-modifying material that ponded in valley bottoms and depressions to thicknesses of up to 70 m, with no systematic variation in thickness with distance from source.The headwaters of many of the North Island's largest rivers were impacted by both the primary pyroclastic fall and flow material. Large-scale post-eruption remobilisation of this material, coupled with the re-establishment of fluvial systems, occurred in a distinct sequence as recorded by the evolution of sedimentary facies in different sub-environments. Following an initial period dominated by mass flows, re-establishment of fluvial systems began with the headward erosion of box canyons through the ponded ignimbrite deposits, a process often associated with the break-out of temporary lakes. Aggradational streams developed in these channels rapidly evolved from shallow, ephemeral, sediment-laden outbursts associated with flash flood events to deeper, permanent braided rivers, before declining sediment yields led to retrenchment of single thread rivers and a return to pre-eruption gradients and bedloads years to decades later. Typically the modern profile of many streams and rivers follow closely their pre-eruption profiles, and incision and erosion is overwhelmingly confined to the deposits of the eruption itself.Although the general remobilisation pattern is similar for all impacted river systems, detailed studies of the Waikato, Rangitaiki, Mohaka, Ngaruroro and Whanganui catchments show that the relative timing and scale of each eruption response phase differs between each catchment. These reflect differences in catchment physiography and hydrology, and the volume and type of pyroclastic material deposited in each. Ultimately, the landscape response reflects the relative spatial distributions of, and the volumetric ratios between, the volumes of pyroclastic debris, water, and accommodation space in the basin (cf. Kataoka and Manville, this volume).     

Noise pollution

Noise, sometimes referred to as the unseen pollutant, is the most inescapable form of pollution — and one which poses a long list of potential health hazards. As the world becomes more urbanized, the use of machine-technology increases, and levels of development become higher and more complex, human exposure to noise increases. One authority estimates that the average noise level in the American city is increasing by 1 dB annually.Despite the importance and great scale of the problem, geographers generally have ignored the field of noise pollution research, perhaps because specialized equipment is necessary to accumulate the data required for analysis. As a result, most noise pollution research has been performed by traffic engineers, industrial designers and urban planners to solve immediate problems with little regard for more general consideration. This article provides background which may serve as a foundation for future research on this most significant human problem. The emphasis is upon developments in North America, but reference is made at appropriate points, to noise pollution research in Europe, China and elsewhere. *** DIRECT SUPPORT *** ABI02038 00003     

Depositional record of historic lahars in the upper Whangaehu Valley, Mt. Ruapehu, New Zealand: implications for trigger mechanisms, flow dynamics and lahar hazards

Mt. Ruapehu, in the central North Island of New Zealand, is one of the most lahar-prone volcanoes in the world. Since historic observations began in 1861 AD, more than 50 individual lahars have been recorded in the Whangaehu valley alone, the natural outlet to the summit Crater Lake. These lahars have been triggered by a variety of mechanisms, including explosive eruptions that displaced Crater Lake water over the outlet or ejected it onto the snow-clad summit area of the volcano; rain-remobilisation of tephra deposits on steep slopes; displacement over the outlet as a result of syn-eruptive changes in lake bathymetry; and lake break-outs from Crater Lake following impoundment of excess water behind temporary barriers of tephra and/or ice emplaced over the outlet. However, only 9 lahar deposits can be distinguished in the upper Whangaehu valley on sedimentological, stratigraphic, geomorphic and petrological grounds, and these are skewed towards either the largest or the most recent flows. In some cases magnitude can be reconstructed from deposit geometry, with the largest lahars producing the highest level terraces, the coarsest deposits, and crossing drainage divides into normally inactive channels. This under-representation of historic events reflects the low preservation potential of unconsolidated deposits in a steep alpine environment, and the overprinting and recycling effect of large magnitude lahars that rework material down to bedrock and effectively reset the stratigraphic record. Development of magnitude-frequency relationships for Ruapehu lahars therefore requires the identification of lahar deposits in proximal, medial and distal settings in order to ensure that the full range of events is represented.     

A fluid dynamics approach to modelling the 18th March 2007 lahar at Mt. Ruapehu,New Zealand

Lahars are water-sediment mass flows from a volcanic source. They can be triggered by a variety of mechanisms and span a continuum of flow rheology and hydraulic properties, even within the same event. Lahars are extremely powerful landscaping agents and represent a considerable hazard potential. However, this highly dynamic character and a lack of direct measurements has made modelling lahars difficult. This study therefore applies a fluid dynamics model; Delft3D, to analyse the 18th March 2007 dam break lahar at Mount Ruapehu, New Zealand. The modelled lahar routed through the Whangaehu gorge in ~30 min, crossed the Whangaehu fan in ~60 min, and then over a further 3 h travelled an additional ~22 km distance along the Whangaehu River to the Tangiwai bridge. The modelled mean frontal velocity was 6.5 m s⁻¹ along the gorge although peak velocity reached up to 19.6 m s⁻¹. The modelled lahar flow front progressively slowed across the fan but along the River it accelerated from 2.1–3.3 m s⁻¹. Calculated peak velocity along the River was <4.5 m s⁻¹. These results generally compare well with gauged records, with historical records, and with other modelling approaches. However, discrepancies in frontal velocity and time to peak stage arise due to (1) specifying roughness, which arises from slope variations between adjacent computational nodes, and which is stage-dependant, and (2) due to rapid topographic changes that produce frequent hydraulic jumps, which are inadequately accommodated in the numerical scheme. The overall pattern of discharge attenuation, and of relationships between topographic and hydraulic variables, is similar to that calculated for lahars on other volcanoes. This modelling method could be applied at other similar sites where a likely source hydrograph and high-resolution topographic data are available. These results have important implications for hazard management at Ruapehu and for examining geomorphic and sedimentary impacts of this lahar.     

Out-burst flood (lahar) triggered by retrogressive landsliding, 18 March 2007 at Mt Ruapehu,New Zealand—a successful early warning

The summit crater of Mt Ruapehu volcano normally hosts a 15.4-ha warm lake, whose water has been repeatedly wholly or partly ejected by explosive and extrusive eruptions. Some of the larger eruptions have modified the lake outlet by burying it under unconsolidated tephra (volcanic ash and blocks), creating a dam-break flood hazard independently of the occurrence of an eruption. Eruptions in 1995 and 1996 followed this sequence; a break-out flood was anticipated and a warning system was installed to mitigate the risk from this event and subsequent lahars in the same catchment. The 11-year filling time allowed much planning and rehearsal. The warning system involved manual inspections of dam integrity, and seepage and lake-level monitoring to constrain the likely failure window, and telemetered instruments including a tripwire and geophones to detect breaching of the dam and propagation of the outbreak flood. The dam-collapse sequence, captured by a time-lapse camera, involved a series of retrogressing landslides initiated and accelerated by seepage forces and toe scour when the lake was 1.1 m below overtopping. The barrier failed in two phases on 18th March, 2007, beginning at 09:55 (NZST), with rapid retreat of one of the erosion scarps on the downstream slope of the eastern barrier, initiated by internal erosion. Headward retrogression of the scarp into the barrier formed an initial breach in the dam, after which increasing outflow led to erosion and undercutting of the wider downstream toe of the western barrier. A final, larger dam breach occurred between 11:21 and 11:22 as slope instability caused retrogressive failure of the remaining barrier. Five-hundred meters downstream of the dam, a large landslide was reactivated by toe scour during the flood, contributing about a million cubic meters of solid material to the volumetric bulking of the outflow, which reached the coast, 215 km away, 17 h later. The success of the planning and warning system allowed the whole event to occur with little damage to infrastructure and without causing injury.     

Impacts of explosive volcanism on distal alluvial sedimentation: Examples from the Pliocene–Holocene volcaniclastic successions of Japan

Volcanic activities can create cataclysmic hazards to surrounding environments and human life not only during the eruption but also by hydrologic remobilisation (lahar) processes after the cessation of eruptive activity. Although there are many studies dealing with the assessment and mitigation of volcanic hazards, these are mostly concentrated on primary eruptive processes in areas proximal to active volcanoes. However, the influence of volcaniclastic resedimentation may surpass the impacts of primary eruptive activity in terms of both extent and persistence, and can ultimately result in severe hazards in downstream areas.Examination of the volcaniclastic successions of non-marine Pliocene–Holocene sedimentary basins in Japan has revealed hydrological volcaniclastic sedimentation in fluvial and lacustrine environments hundreds of kilometres from the inferred source volcano. Impacts on these distal and often spatially separated basins included drastic changes in depositional systems caused by sudden massive influxes of remobilised pyroclastic material. Typical volcaniclastic beds comprise centimetre- to decimetre-thick primary pyroclastic fall deposits overlain by metre- to 10s of metres-thick resedimented volcaniclastic deposits, intercalated in sedimentary successions of non-volcanic provenance. The relatively low component of primary pyroclastic fall deposits in the volcaniclastic beds suggests that: 1) potential volcanic hazards would be underestimated on the basis of primary pyroclastic fall events alone; and 2) the majority of resedimented material was likely derived from erosion of non-welded pyroclastic flow deposits in catchment areas rather than remobilisation of local fallout deposits from surrounding hillslopes.The nature, distribution and sequence of facies developed by distal volcaniclastic sediments reflect the influence of: 1) proximity to ignimbrite, but not directly with the distance to the eruptive centre; 2) ignimbrite nature (non-welded or welded) and volume; 3) temporal changes in sediment flux from the source area; 4) the physiography and drainage patterns of the source area and the receiving basin, and any intervening areas; and 5) the formation of ephemeral dam-lakes and intra-caldera lakes whose potential catastrophic failure can impact distal areas. Models of the styles and timing of distal volcaniclastic resedimentation are thus more complicated than those developed for proximal settings of stratovolcanoes and their volcaniclastic aprons and hence present different challenges for hazard assessment and mitigation.