Global crustal thickness from neural network inversion of surface wave data

We present a neural network approach to invert surface wave data for a global model of crustal thickness with corresponding uncertainties. We model the a posteriori probability distribution of Moho depth as a mixture of Gaussians and let the various parameters of the mixture model be given by the outputs of a conventional neural network. We show how such a network can be trained on a set of random samples to give a continuous approximation to the inverse relation in a compact and computationally efficient form. The trained networks are applied to real data consisting of fundamental mode Love and Rayleigh phase and group velocity maps. For each inversion, performed on a 2°× 2° grid globally, we obtain the a posteriori probability distribution of Moho depth. From this distribution any desired statistic such as mean and variance can be computed. The obtained results are compared with current knowledge of crustal structure. Generally our results are in good agreement with other crustal models. However in certain regions such as central Africa and the backarc of the Rocky Mountains we observe a thinner crust than the other models propose. We also see evidence for thickening of oceanic crust with increasing age. In applications, characterized by repeated inversion of similar data, the neural network approach proves to be very efficient. In particular, the speed of the individual inversions and the possibility of modelling the whole a posteriori probability distribution of the model parameters make neural networks a promising tool in seismic tomography.     

Assessing streams in Germany with benthic invertebrates: selection of candidate metrics

The process of selecting invertebrate-based candidate metrics for the German stream assessment system is described. The aim was to identify metrics indicating degradation types other than organic pollution and acidification (“general degradation”). For 18 out of 24 German stream types a data base of roughly 2,000 benthic invertebrate samples was generated; for each sample 79 metrics were calculated. Data on land use in the catchment were compiled for all sampling sites, together with data on hydromorphology for many sampling sites. Hydromorphological and land use parameters, which describe a clear gradient in the data sets were identified by Non-metric Multidimensional Scaling (NMS). Correlation analyses between land use/hydromorphological parameters and metric results were calculated separately for the individual stream types. Among those metrics best indicating catchment- and hydromorphological degradation in the majority of stream types are: proportion of Ephemeroptera, Plecoptera and Trichoptera; proportion of Plecoptera (mainly suited for mountain streams); number of Plecoptera taxa; proportion of xenosaprobic taxa; proportion of epirhithral preferring taxa. Differences of metric correlations between stream types and between degradation types are discussed, leading to a list of candidate metrics for assessing German streams.     

A theoretical study of the electronic structure of disiloxane [(SiH3)2O] and its relation to silicates

Ab initio selfconsistent field calculations have been carried out for disiloxane, (SiH₃)₂O, and the equilibrium structure determined. The Slater-type orbital STO-3G* basis set including d-functions on Si gave the equilibrium structure of r _e(Si-O)=1.58 Å and θ_e(Si-O-Si)=140.0° for the most stable C_ss conformer, in reasonable agreement with the experimental values of 1.634 Å and 144.1°, respectively. The barrier of internal rotation of the silyl-group has been found to be rather small. The influence of the d-function to the electronic structure is discussed and the calculated results are related to the silicates, especially to the sorosilicates.     

A comparison of lead-isotope measurements on exploration-type samples using inductively coupled plasma and thermal ionization mass spectrometry

Thermal ionization mass spectrometry (TI-MS) has long been the method of choice for Pb-isotope determinations. More recently, however, inductively coupled plasma mass spectrometry (ICP-MS) has been used to determine Pb-isotope ratios for mineral exploration. The ICP-MS technique, although not as precise as TI-MS, may promote a wider application of Ph-isotope ratio methods because it allows individual isotopes to be determined more rapidly, generally without need for chemical separation (e.g., Smith et al., 1984; Hinners et al., 1987). To demonstrate the utility of the ICP-MS method, we have conducted a series of Pb-isotope measurements on several suites of samples using both TI-MS and ICP-MS.     

DETERMINATION OF FLUORINE, CHLORINE, BROMINE AND IODINE IN SEVEN GEOCHEMICAL REFERENCE SAMPLES

The concentrations of fluorine, chlorine, bromine and iodine of seven geochemical reference samples have been determined. Analytical techniques were neutron activation analysis for chlorine, bromine and iodine and ion-selective potentiometry for fluorine. After irradiation of the samples, these halogens were separated from the matrix elements by pyrohydrolysis in presence of vanadium (V) oxide. This extraction allows to measure the four halogens in the same sample.     

Geospace imaging using Thomson scattering

We evaluate the potential of imaging for the first time, the near-earth space plasma environment seamlessly from the ionosphere through the magnetosphere by remotely sensing Thomson scattering of solar visible light by geospace electrons. Using state of the art first principles models of the magnetosphere/ionosphere system, we show that the column emission rates are weak, generally less than 10 Rayleighs, but detectable with currently available instrument technology recently deployed for heliospheric imaging. We demonstrate that distinct features such as the bow shock, magnetosheath and magnetopause are detectable in synthetic images simulated using modified solar coronagraphs and white light imagers, providing that the large background signals are properly quantified. The availability of global geospace images of the electron concentration will enable major advances in our understanding of how Earth's near-space environment responds as a coupled system to changing solar forcings. Such images are expected to play a central role in space weather assessment and forecasting, from which significant capabilities will accrue, much as the imaging of the Earth's surface and lower atmosphere has advanced understanding and forecasting of tropospheric weather.     

Model based analysis of lateral and vertical soil carbon fluxes induced by soil redistribution processes in a small agricultural catchment

Soil redistribution on arable land significantly affects lateral and vertical soil carbon (C) fluxes (caused by C formation and mineralization) and soil organic carbon (SOC) stocks. Whether this serves as a (C) sink or source to the atmosphere is a controversial issue. In this study, the SPEROS‐C model was modified to analyse erosion induced lateral and vertical soil C fluxes and their effects upon SOC stocks in a small agricultural catchment (4·2 ha). The model was applied for the period between 1950 and 2007 covering 30 years of conventional tillage (1950–1979) followed by 28 years of conservation tillage (1980–2007). In general, modelled and measured SOC stocks are in good agreement for three observed soil layers. The overall balance (1950–2007) of erosion induced lateral and vertical C fluxes results in a C loss of ?4·4 g C m^–2 a^–1 at our test site. Land management has a significant impact on the erosion induced C fluxes, leading to a predominance of lateral C export under conventional and of vertical C exchange between soil and atmosphere under conservation agriculture. Overall, the application of the soil conservation practices, with enhanced C inputs by cover crops and decreased erosion, significantly reduced the modelled erosion induced C loss of the test site. Increasing C inputs alone, without a reduction of erosion rates, did not result in a reduction of erosion induced C losses. Moreover, our results show that the potential erosion induced C loss is very sensitive to the representation of erosion rates (long‐term steady state versus event driven). A first estimate suggests that C losses are very sensitive to magnitude and frequency of erosion events. If long‐term averages are dominated by large magnitude events modelled erosion induced C losses in the catchment were significantly reduced. Copyright © 2011 John Wiley & Sons, Ltd.     

European climate in the late twenty-first century: regional simulations with two driving global models and two forcing scenarios

A basic analysis is presented for a series of regional climate change simulations that were conducted by the Swedish Rossby Centre and contribute to the PRUDENCE (Prediction of Regional scenarios and Uncertainties for Defining EuropeaN Climate change risks and Effects) project. For each of the two driving global models HadAM3H and ECHAM4/OPYC3, a 30-year control run and two 30-year scenario runs (based on the SRES A2 and B2 emission scenarios) were made with the regional model. In this way, four realizations of climate change from 1961–1990 to 2071–2100 were obtained. The simulated changes are larger for the A2 than the B2 scenario (although with few qualitative differences) and in most cases in the ECHAM4/OPYC3-driven (RE) than in the HadAM3H-driven (RH) regional simulations. In all the scenario runs, the warming in northern Europe is largest in winter or late autumn. In central and southern Europe, the warming peaks in summer when it locally reaches 10 °C in the RE-A2 simulation and 6–7 °C in the RH-A2 and RE-B2 simulations. The four simulations agree on a general increase in precipitation in northern Europe especially in winter and on a general decrease in precipitation in southern and central Europe in summer, but the magnitude and the geographical patterns of the change differ markedly between RH and RE. This reflects very different changes in the atmospheric circulation during the winter half-year, which also lead to quite different simulated changes in windiness. All four simulations show a large increase in the lowest minimum temperatures in northern, central and eastern Europe, most likely due to reduced snow cover. Extreme daily precipitation increases even in most of those areas where the mean annual precipitation decreases.     

Flameless atomic-absorption determination of gold in geological materials

Gold in geologic material is dissolved using a solution of hydrobromic acid and bromine, extracted with methyl isobutyl ketone, and determined using an atomic-absorption spectrophotometer equipped with a graphite furnace atomizer. A comparison of results obtained by this flameless atomic-absorption method on U.S. Geological Survey reference rocks and geochemical samples with reported values and with results obtained by flame atomic-absorption shows that reasonable accuracy is achieved with improved precision. The sensitivity, accuracy, and precision of the method allows acquisition of data on the distribution of gold at or below its crustal abundance.