Late quaternary glacial stades in the Cordillera Central,Colombia, based on glacial geomorphology,tephra–soil stratigraphy,palynology, and radiocarbon dating

Using data from glacial geomorphology, tephra–soil stratigraphy and mineralogy, palynology, and radiocarbon dating, a sequence of glacial and bioclimatic stades and interstades has been identified for the last ca. 50000 yr in the Ruiz-Tolima massif, Cordillera Central, Colombia. Six Pleistocene cold stades separated by warmer interstades occurred: before 48000, between 48000 and 33000, between 28000 and 21000, from ≥16000 to ca. 14000, ca. 13000–12400, and ca. 11000–10000 yr BP. Although these radiocarbon ages are minimum-limiting ages obtained from tephra layers on top of tills, the tills are not significantly older because most are bracketed by dated tephra sets in measured stratigraphic sections. Two minor moraine stages likely reflect glacier standstill during cold intervals ca. 7400 yr BP and slightly earlier. Finally, glaciers readvanced between the seventeenth and nineteenth centuries. In contrast to the ice-clad volcanoes of the massif, ca. 34 km² in area above an altitude of ca. 4800 m, the ice cover expanded to 1200 km² during the Last Glacial Maximum (LGM) and was still 800 km² during Late-glacial time (LGT). Glacier reconstructions based on the moraines suggest depression of the equilibrium line altitude (ELA) by ca. 1100 m during the LGM and 500–600 m during LGT relative to the modern ELA, which lies at ca. 5100 m in the Cordillera Central. Glaciers in this region apparently reached their greatest extent when the climate was cold and wet, e.g. during stades corresponding to Oxygen Isotope Stage 3; glaciers were still expanding during the LGM ca. 28000–21000 yr BP, but they shrank considerably after 21000 yr BP because of greatly reduced precipitation. © 1997 John Wiley & Sons, Ltd.     

The Cretaceous and younger thermal history of the KTB site (Germany): apatite fission-track data from the Vorbohrung

A detailed fission-track analysis was carried out on 41 apatite samples from the 4001-m-deep pilot hole of the German Continental Deep Drilling Program (KTB). The investigations include dating by the population method and length measurements of horizontal confined tracks. Age and length information indicate that all samples above the present-day partial annealing zone cooled from temperatures above 120?°C in the Cretaceous. The top two kilometres of the profile show less variation of age with depth than was expected. Modelling of the profile indicates that the distribution of fission track ages with depth requires that the profile was disturbed during or after cooling through the partial annealing zone. Modelling of individual samples reveals that at least the upper 2?km experienced reverse faulting, effectively thickening the upper part of the rock column by up to 1000?m in the Tertiary. A present-day partial annealing zone for apatite was observed between 2000 and 4000?m (～60–110?°C). This confirms earlier in situ observations of the position of the partial annealing zone.     

Mechanical aspects of sedimentary basin formation: development of integrated models for lithospheric and surface processes

Different assumptions for the thermo-mechanical properties of the lithosphere strongly affect predictions inferred from quantitative sedimentary basin modeling. Examples from various basins, selected as natural laboratories, illustrate the importance of incorporating a finite strength of the extending lithosphere in forward stratigraphic modeling of large-scale basin stratigraphy. Current models can effectively couple erosion at uplifted rift shoulders of extensional basins with the basin fill architecture of the subsiding basin compartments. Modeling of the synrift strata integrates spatial scales characteristic for subbasins, such as the Oseberg field in the North Sea, with large-scale lithospheric properties characterizing the bulk strength of extending lithosphere. Modeling of compressional basins in foreland fold-and-thrust-belt settings can effectively link lithospheric flexure with surface processes. Scales pertinent to short-term spatial and temporal variations in basin fill and basin deformation can now be addressed, allowing the quantitative investigation of consequences of different modes of thrusting for basin fill geometry and facies characteristics.     

Geogene Versus Anthropogene Origin of Trace Metals in Sediments in Cua Luc Estuary and Ha Long Bay, Vietnam

In the present study, the geochemistry of 49 surficial-bed and 101 core sediment samples is investigated to clarify the origin of trace metals in the Cua Luc Estuary and Ha Long Bay, which is a famous World Natural Heritage Site in Vietnam. Moreover, the potential mobility of trace metals is also assessed and their relationship with reference elements (Al, Fe, and Ca) and organic matter is established in order to make recommendations for sediment management and monitor future pollution. Generally, trace metals display higher concentrations in Ha Long Bay compared to the Cua Luc Estuary. However, this is controlled by the distribution of the fine (clay?+?silt) fraction, and hence the concentrations of Al, Fe, Ca, and organic matter (OM). The comparison of concentrations of trace metals (normalized towards Al) between the surficial sediments and the subsurface core sediments based on ¹³⁷Cs datings indicates that almost all surficial-sediment data fall inside or deviate slightly from the 95 % prediction interval of a background regression line. In addition, as determined by a Community Bureau of Reference three-step extraction, trace metals mainly dominate in the residual fraction (assumed to relate to crystal lattice of primary and secondary minerals), and this fraction does not change much in recent sediment layers. Therefore, trace metals are supposed to be derived from natural bio/geochemical processes and are characterized by a low potential mobility. Consequently, the established linear regression relationships of trace metal vs. Al or multiple regression relationships of trace metal vs. multi-elements (Al, Fe, Ca, and OM) are useful for the prediction of background levels of trace metals in sediments in future pollution monitoring and assessment programs.     

Modeling approaches and strategies for data-scarce aquifers: example of the Dar es Salaam aquifer in Tanzania

Management of groundwater resources can be improved by using groundwater models to perform risk analyses and to improve development strategies, but a lack of extensive basic data often limits the implementation of sophisticated models. Dar es Salaam in Tanzania is an example of a city where increasing groundwater use in a Pleistocene aquifer is causing groundwater-related problems such as saline intrusion along the coastline, lowering of water-table levels, and contamination of pumping wells. The lack of a water-level monitoring network introduces a problem for basic data collection and model calibration and validation. As a replacement, local water-supply wells were used for measuring groundwater depth, and well-top heights were estimated from a regional digital elevation model to recalculate water depths to hydraulic heads. These were used to draw a regional piezometric map. Hydraulic parameters were estimated from short-time pumping tests in the local wells, but variation in hydraulic conductivity was attributed to uncertainty in well characteristics (information often unavailable) and not to aquifer heterogeneity. A MODFLOW model was calibrated with a homogeneous hydraulic conductivity field and a sensitivity analysis between the conductivity and aquifer recharge showed that average annual recharge will likely be in the range 80–100 mm/year.     

Impact of suboxia on sinking particulate organic carbon: Enhanced carbon flux and preferential degradation of amino acids via denitrification

Fluxes of particulate organic carbon (POC) through the oxygen deficient waters in the eastern tropical North Pacific were found to be relatively less attenuated with depth than elsewhere in the eastern North Pacific. The attenuation coefficient (b) for the flux was found to be 0.40 versus the composite value of 0.86 determined by Martin et al. (1987). To examine this further, sinking POC was collected using sediment traps and allowed to degrade in oxic and suboxic experiments. Using a kinetic model, it was found that degradation proceeded at similar rates (roughly 0.8 day⁻¹) under oxic and suboxic conditions, but a greater fraction of bulk POC was resistant to degradation in the suboxic experiments (61% vs. 23%). Amino acids accounted for 37% of POC collected at 75m, but following degradation the value dropped to 17% and 16% in the oxic and suboxic experiments respectively. POC collected from 500m was 10% amino acids. The non-AA component of POC collected at 75m was not degraded under suboxic conditions, while under oxic conditions it was. These results suggest that microbes degrading OC under suboxic conditions via denitrification preferentially utilize nitrogen-rich amino acids. This preferential degradation of amino acids suggests that 9% more nitrogen may be lost via water column denitrification than is accounted for when a more “Redfieldian” stoichiometry for POC is assumed.     

Surface chemistry and reactivity of biogenic silica

The surface chemistry of cultured diatoms was compared to that of biosiliceous material in Southern Ocean sediments, using potentiometric titrations and aluminum adsorption experiments. Aerosil 200, a well-studied synthetic amorphous silica, served as reference solid. Surface charge development and aluminum adsorption on cultured diatom shells were comparable to Aerosil. The surface chemical properties of biosiliceous material buried to depths of 15-25 cm in Southern Ocean sediments, however, deviated markedly from those of the cultured diatoms. In pH range 4-8.5, the surface charge density was systematically lower for biogenic silica from the sediments. In addition, the aluminum adsorption edge on the biosiliceous sediments was shifted to higher pHs by about 0.4 units. The results indicate that ionizable surface silanol groups on diagenetically altered diatom shells are less abundant and, possibly, less acidic than on freshly cultured diatoms. The observed differences in surface chemical structure are consistent with the progressive loss of reactivity, or aging, of biogenic silica which promotes its preservation in sediments.     

Origin of fine-scale sheeted granites by incremental injection of magma into active shear zones: examples from the Pilbara Craton, NW Australia

In the Archaean Pilbara Craton of Western Australia, three zones of heterogeneous centimetre- to metre-scale sheeted granites are interpreted to represent high-level, syn-magmatic shear zones. Evidence for the syn-magmatic nature of the shear zones include imbricated and asymmetrically rotated metre-scale orthogneiss xenoliths that are enveloped by leucogranite sheets that show no significant internal strain. At another locality, granite sheets have a strong shape-preferred alignment of K-feldspar, suggesting magmatic flow, while the asymmetric recrystallisation of the grain boundaries indicates that non-coaxial deformation continued acting upon the sheets under sub-solidus conditions. Elsewhere, randomly oriented centimetre-wide leucogranite dykes are realigned at a shear zone boundary to form semi-continuous, layer-parallel sheets within a magma-dominated, dextral shear zone.

It is proposed that the granite sheets formed by the incremental injection of magmas into active shear zones. Magma was sheared during laminar flow to produce the sheets that are aligned sub-parallel to the shear zone boundary. Individual sheets are fed by individual dykes, with up to 1000s of discrete injections in an individual shear zone. The sheets often lack microstructural evidence for magmatic flow, either because the crystal content of the magma was too low to record internal strain, or because of later recrystallisation.     

A groundwater isoscape (δD, δO) for Mexico

Numerous studies have shown that precipitation isocapes drive δD and δ¹⁸O patterns in surficial waters and in terrestrial food webs. While the GNIP (Global Network for Isotopes in Precipitation) dataset provided a key foundation for linking precipitation-terrestrial isoscapes globally, it has insufficient spatial coverage in many countries like Mexico. To overcome this limitation, we hypothesized that shallow phreatic groundwaters in Mexico could be used as an isotopic integrator of long-term seasonally weighted precipitation inputs to the landscape to aid in calibrating spatial H and O isotope datasets for terrestrial, biological and hydrological research. Groundwater was sampled from 234 sites in Mexico at ~ 50 km latitudinal spacing to obtain high spatial resolution and country-wide coverage for the construction of a groundwater isoscape. Our data revealed that shallow groundwater infiltration in Mexico appears largely unaffected by evaporation and reflects seasonally weighted precipitation inputs. These precipitation inputs are primarily biased to summertime when highest rainfall occurs, but a small degree of post-precipitation evaporation revealed a lower d-excess zone that corresponded to the interior semi-arid ecozone. We developed a predictive general linear model (GLM) for hydrogen and oxygen isotopic spatial patterns in Mexican groundwater and then compared the results to a validation subset of our field data, as well external data reported in the literature. The GLM used elevation, latitude, drainage basin (Atlantic vs. Pacific), and rainfall as the most relevant predictive variables. The GLM explained 81% of the overall isotopic variance observed in groundwater, 68% of the variance within our validation subset, and 77% of the variance in the external data set. Our predictive GLM is sufficiently accurate to allow for future ecological, hydrological and forensic isoscape applications in Mexico, and may be an approach that is applicable to other countries and regions where GNIP stations are lacking.