Reactive iron(III) in sediments: Chemical versus microbial extractions

The availability of particulate Fe(III) to iron reducing microbial communities in sediments and soils is generally inferred indirectly by performing chemical extractions. In this study, the bioavailability of mineral-bound Fe(III) in intertidal sediments of a eutrophic estuary is assessed directly by measuring the kinetics and extent of Fe(III) utilization by the iron reducing microorganism Shewanella putrefaciens, in the presence of excess electron donor. Microbial Fe(III) reduction is compared to chemical dissolution of iron from the same sediments in buffered ascorbate-citrate solution (pH 7.5), ascorbic acid (pH 2), and 1 M HCl. The results confirm that ascorbate at near-neutral pH selectively reduces the reactive Fe(III) pool, while the acid extractants mobilize additional Fe(II) and less reactive Fe(III) mineral phases. Furthermore, the maximum concentrations of Fe(III) reducible by S. putrefaciens correlate linearly with the iron concentrations extracted by buffered ascorbate-citrate solution, but not with those of the acid extractions. However, on average, only 65% of the Fe(III) reduced in buffered ascorbate-citrate solution can be utilized by S. putrefaciens, probably due to physical inaccessibility of the remaining fraction of reactive Fe(III) to the cells. While the microbial and abiotic reaction kinetics further indicate that reduction by ascorbate at near-neutral pH most closely resembles microbial reduction of the sediment Fe(III) pool by S. putrefaciens, the results also highlight fundamental differences between chemical reductive dissolution and microbial utilization of mineral-bound ferric iron.     

CARBON IN DARK INCLUSIONS OF THE ALLENDE METEORITE

Carbon contents of three Dark Inclusions (DI's) of the Allende meteorite, measured chemically, range from 0.56 to 1.17 weight %. When one includes the data reported by Bunch, Chang, and Ott (two DI's), the lower limit is 0.44%. The C-concentration map of a 1.6 × 1.6 mm² area straddling the boundary of a DI and matrix, or else of a DI and its dark halo, obtained with a ¹²C (d,p)¹³ C nuclear microprobe, shows that the C-content of the core of the DI is very uniform, and that the C-content of the rim is 2.9 ± 0.3 times larger. Variability of C-content of matrix and matrix-like areas of Allende appears to be the rule. DI's cannot be reworked bulk Allende, or precursor for bulk Allende without the addition, respectively removal of significant amounts of carbon. However, some Type 1 DI's might be reworked Allende matrix or precursor matter for that matrix.     

Mesoarchean mafic dykes of the Belomorian eclogite province (Gridino Village Area,Russia)

Archean processes of eclogitization in the Gridino metamorphic association (the Belomorian eclogite province) developed in mafic dykes, boudins, and acidic rocks of the Archean continental crusts. To determine the U-Pb age of the intrusion of the latest dykes, the geochronological samples were taken from the dyke of ferriferious metagabbro that cross-cuts the dyke of eclogitzed and granulitized olivine gabbronorite. The igneous zircons were dated by the SHRIMP II technique. The zircons showed a concordia age of 2846 ± 7 Ma, which is considered as the time of intrusion of a mafic melt. The younger low-thorium zircon rims of 2.78–2.81 Ga age around the igneous cores are typical formations that appeared under metamorphic conditions in equilibrium with a migmatite melt, and may characterize the time of formation of the granite leucosome under metamorphism, probably of eclogite facies.     

Multi-gas Emissions Pathways to Meet Climate Targets

So far, climate change mitigation pathways focus mostly on CO₂ and a limited number of climate targets. Comprehensive studies of emission implications have been hindered by the absence of a flexible method to generate multi-gas emissions pathways, user-definable in shape and the climate target. The presented method ‘Equal Quantile Walk’ (EQW) is intended to fill this gap, building upon and complementing existing multi-gas emission scenarios. The EQW method generates new mitigation pathways by ‘walking along equal quantile paths’ of the emission distributions derived from existing multi-gas IPCC baseline and stabilization scenarios. Considered emissions include those of CO₂ and all other major radiative forcing agents (greenhouse gases, ozone precursors and sulphur aerosols). Sample EQW pathways are derived for stabilization at 350 ppm to 750 ppm CO₂ concentrations and compared to WRE profiles. Furthermore, the ability of the method to analyze emission implications in a probabilistic multi-gas framework is demonstrated. The probability of overshooting a 2 ^∘C climate target is derived by using different sets of EQW radiative forcing peaking pathways. If the probability shall not be increased above 30%, it seems necessary to peak CO₂ equivalence concentrations around 475 ppm and return to lower levels after peaking (below 400 ppm). EQW emissions pathways can be applied in studies relating to Article 2 of the UNFCCC, for the analysis of climate impacts, adaptation and emission control implications associated with certain climate targets. See for EQW-software and data.     

The Modelling Of Landslide Hazards Using Gis

Slope instability hazard assessment is based on theanalysis of the terrain conditions at sites whereslope failures occurred in the past. For the analysisof the causative factors the application of geographicinformation systems (GIS) is an essential tool in thedata analysis and the subsequent hazard assessment.Three scale levels of hazard mapping are defined – adirect experience-driven mapping at reconnaissancelevel, a statistical approach to determine thecausative factors in a quantitative susceptibilitymapping, and a methodology at large scale making use ofdeterministic models.     

专用气候数据空间插值软件ANUSPLIN及其应用

空间化的气候数据作为环境因子参数是区域气候模型和地学模型的基础,而插值软件是实现气候观测点数据空间化的工具.ANUSPLIN基于薄盘样条函数理论,引入多个影响因子作为协变量进行气象要素空间插值,大大提高插值精度,且能同时进行多个表面的空间插值,对时间序列的气象要素更加适合.     

Comparison of techniques for pre-concentrating radium from seawater

In the framework of the KEOPS project (KErguelen: compared study of the Ocean and the Plateau in Surface water), we aimed to provide information on the water mass pathways and vertical mixing on the Kerguelen Plateau, Southern Ocean, based on ²²⁸Ra profiles. Because ²²⁸Ra activities are extremely low in this area (~ 0.1 dpm/100 kg or ~ 2.10^− 18 g kg^− 1), the filtration of large volumes of seawater was required in order to be able to detect it with minimal uncertainty. This challenging study was an opportunity for us to test and compare methods aimed at removing efficiently radium isotopes from seawater. We used Mn-fiber that retains radium and that allows the measurement of all four radium isotopes (²²⁶Ra, ²²⁸Ra, ²²³Ra, ²²⁴Ra). First, we used Niskin bottles or the ship's seawater intake to collect large volumes of seawater that were passed onto Mn-fiber in the laboratory. Second, we filled cartridges with Mn-fiber that we placed in tandem on in situ pumps. Finally, we fixed nylon nets filled with Mn-fiber on the frame of in situ pumps to allow the passive filtration of seawater during the pump deployment.Yields of radium fixation on the cartridges filled with Mn-fiber and placed on in situ pumps are ca. 30% when combining the two cartridges. Because large volumes of seawater can be filtered with these pumps, this yields to effective volumes of 177–280 kg (that is, higher than that recovered from fourteen 12-l Niskin bottles). Finally, the effective volume of seawater that passed through Mn-fiber placed in nylon nets and deployed during 4 h ranged between 125 and 364 kg. Consequently, the two techniques that separate Ra isotopes in situ are good alternatives for pre-concentrating radium from seawater. They can save ship-time by avoiding repeated CTD casts to obtain the large volumes of seawater. This is especially true when in situ pumps are deployed to collect suspended particles. However, both methods only provide ²²⁸Ra/²²⁶Ra ratios. The determination of the ²²⁸Ra specific activity is obtained by multiplying this ratio by the ²²⁶Ra activity measured in a discrete sample collected at the same water depth.     

2008年汶川地震同震滑移特征、最大滑移量及构造意义

2008年汶川地震（M_s8.0）形成了迄今为止空间上分布最为复杂、长度最大的逆冲型同震地表破裂带。沿约275km长的地表破裂带的同震滑移及其最大滑移量的确定,对认识和理解汶川地震地表破裂过程及其变形机制具有重要意义。我们沿地表破裂带进行了详细的滑移特征考察及其同震位移测量,发现沿映秀-北川破裂带分布南北两个滑移峰值区段,南段以深溪沟-虹口破裂段为中心,以逆冲为主伴随右旋走滑运动为特征,最大垂直位移量为6.0～6.7m,北段以北川破裂段为中心,以右旋走滑为主伴随逆冲运动为特征,最大垂直位移量为11～12m,南北两滑移峰值区段所代表的两次地表破裂事件与地震波数据反演结果一致。通过对北川段破裂带的精细地形剖面测量,以及地震前后对比,在北川县曲山镇沙坝村一组获得该破裂段的最大右旋水平位移为12～15m,最大垂直位移为11～12m,这是目前世界上一次地震产生的最大同震垂直位移,最大斜向滑移量为14～17m,为整个汶川地震地表破裂最大滑移量,是汶川地震的宏观震中。北川破裂段高角度的地震断裂、逆冲断裂面的倒转作用以及具最大滑移量的强烈变形作用是北川县城遭受到最强的地表破坏和地质灾害的主要原因。具有走滑量和逆冲量近一致（走滑水平位移/逆冲垂直位移比值为1）的斜向逆冲作用可能是山脉快速隆升的重要机制。     

青藏高原西北部帕米尔东北缘构造地貌与活动构造研究

新生代以来,印度板块与欧亚大陆的碰撞和持续的汇聚在青藏高原西北部的帕米尔地区造成了强烈的陆内变形,形成一系列典型的构造地貌。文章在卫片解译、DEM数据处理的基础上,结合野外地质、地貌观察与测量,对帕米尔东北缘的构造地貌与活动构造特征进行了研究,取得以下认识： 1)在英吉沙地区,通过测量地貌变形面计算出英吉沙背斜隆起高度约为230m,并利用面积平衡法估算出英吉沙背斜的最小构造缩短量约为110m,参考前人的年代学数据计算出英吉沙背斜在中更新世以来的最低隆升速率约为0.23mm/a,最小构造缩短速率约为0.11mm/a; 2)在帕米尔前缘,乌泊尔断裂为一条伴随右旋走滑分量的逆冲断裂,该断裂的右旋走滑作用错断了古近纪地层及流过断裂的河流,通过测量单次地震造成的水系错断量并参考前人研究的该地区大震复发周期约为1000年,估算出该断裂的平均走滑速率为 4.0～6.8mm/a,并推测断裂开始活动的时间大约在 2.2～3.0Ma以前; 3)对喀什地区构造地貌特征的观察与研究表明,明尧勒－喀什背斜和阿图什－踏浪河背斜可能分别为帕米尔东北缘西昆仑山山前冲断带和西南天山山前冲断带的前缘,该地区以西,帕米尔东北缘西昆仑山和西南天山两大构造系统已经发生了碰撞和拼贴。