Aeolian dust in the Talos Dome ice core (East Antarctica,Pacific/Ross Sea sector): Victoria Land versus remote sources over the last two climate cycles

A new ice core (TALDICE) drilled at Talos Dome (East Antarctica, Ross Sea sector) preserves a ca. 250 ka long record of palaeoclimate and atmospheric history. We investigate dust variability and provenance at the site during glacial periods and the Holocene through the Sr–Nd isotopic composition of ice core dust and potential source areas (PSA). We provide new isotopic data on dust sources from Victoria Land such as regoliths, glacial drifts, aeolian sands and beach deposits. Some of these sources are located at high altitude and are known to have been ice free throughout the Pleistocene. The major features of the TALDICE dust record are very similar to those from central East Antarctica. During glacial times, South America was the dominant dust supplier for Talos Dome as well as for the entire East Antarctic plateau. Conversely, during the Holocene the principal input of mineral dust at Talos Dome probably derives from proximal sources which are the ice‐free areas of northern Victoria Land, located at similar altitude with respect to the drilling site. Atmospheric mobilisation of dust from these neighbouring areas and transport inland to Talos Dome can be ultimately associated with advection of maritime air masses from the Pacific/Ross Sea region. Copyright © 2010 John Wiley & Sons, Ltd.     

Earth walls as repositories of background levels of soil metal contaminants

Data about the background concentration of potentially toxic elements in soils are indispensable for establishing legislative limits, risk thresholds and, in general, assess the intensity of the pollution. Crude earth buildings are diffuse in the Mediterranean area and may be used as archives for original concentration of various metals. The building technique uses local soil which is mixed with water, let dry in formworks and covered with plaster. This has protected the soil material from external additions. The aim of this work was to evaluate the crude earth walls as repositories of the original concentration of some metals. Six crude earth walls were investigated in a location in northwestern Italy. Their concentration in Cd, Cu, Cr, Ni, Pb and Zn were measured and compared with those of surrounding soil profiles. Also, the results were compared with those of the Province. Organic carbon and pH seem to confirm the different evolution of the soils in the field with respect to that in the wall while iron oxides were not useful in discriminating the samples. Cadmium and Pb appeared to be the most reliable for the evaluation of the accumulated contamination evaluated while Cr and Ni are influenced by the lithogenic substratum.     

Oxygen ion escape at Mars in a hybrid model: High energy and low energy ions

We have studied the escape and energization of several O⁺ populations and an population at Mars by using a hybrid model. The quasi-neutral hybrid model, HYB-Mars model, included five oxygen ion populations making it possible to distinguish photoions from oxygen ions originating from charge exchange processes and from the ionosphere.We have identified two high-energy ion components and one low-energy ion component of oxygen. They have different spatial and energy distributions near Mars. The two high-energy oxygen ion components, consisting of a high-energy “beam” and a high-energy “halo”, have different origins. (1) The high-energy (>∼100 eV) “beam” of O⁺ and ions are originating from the ionosphere. These ions form a highly asymmetric spatial distribution of escaping oxygen ions with respect to the direction of the convective electric field in the solar wind. (2) The high-energy (>∼100 eV) “halo” component contains O⁺ ions which are formed from the oxygen neutral exosphere by extreme ultraviolet radiation (EUV) and by charge exchange processes. These energetic halo ions can be found all around Mars. (3) The low energy O⁺ and ions (<∼100 eV) form a relatively symmetric spatial distribution around the Mars-Sun line. They originate from the ionosphere and from charge exchange processes between protons and exospheric oxygen atoms.The existence of the low- and the high-energy oxygen components is in agreement with recent in situ plasma measurements made by the ASPERA-3 instrument on the Mars Express mission. The analysis of the escaping oxygen ions suggests that the global energization of escaping planetary ions in the martian tail is controlled by the convective electric field.     

Comparing modeled and observed changes in mineral dust transport and deposition to Antarctica between the Last Glacial Maximum and current climates

Mineral dust aerosols represent an active component of the Earth’s climate system, by interacting with radiation directly, and by modifying clouds and biogeochemistry. Mineral dust from polar ice cores over the last million years can be used as paleoclimate proxy, and provide unique information about climate variability, as changes in dust deposition at the core sites can be due to changes in sources, transport and/or deposition locally. Here we present results from a study based on climate model simulations using the Community Climate System Model. The focus of this work is to analyze simulated differences in the dust concentration, size distribution and sources in current climate conditions and during the Last Glacial Maximum at specific ice core locations in Antarctica, and compare with available paleodata. Model results suggest that South America is the most important source for dust deposited in Antarctica in current climate, but Australia is also a major contributor and there is spatial variability in the relative importance of the major dust sources. During the Last Glacial Maximum the dominant source in the model was South America, because of the increased activity of glaciogenic dust sources in Southern Patagonia-Tierra del Fuego and the Southernmost Pampas regions, as well as an increase in transport efficiency southward. Dust emitted from the Southern Hemisphere dust source areas usually follow zonal patterns, but southward flow towards Antarctica is located in specific areas characterized by southward displacement of air masses. Observations and model results consistently suggest a spatially variable shift in dust particle sizes. This is due to a combination of relatively reduced en route wet removal favouring a generalized shift towards smaller particles, and on the other hand to an enhanced relative contribution of dry coarse particle deposition in the Last Glacial Maximum.     

Historical Trends of Organochlorine Pesticides in an Alpine Glacier

The significance of persistent organic pollutants, such as organochlorine compounds, as global contaminants in cold regions has been recognised for a long time. In particular, there is a growing interest on the role of high mountains as `cold condensers' for these chemicals. In this paper, for the first time, organochlorine pesticides (DDTs, HCHs, HCB) are analysed in an ice core sampled on a `cold' glacier in the Alps. Several methods were applied to achieve accurate dating of the core layers. Historical trends of organochlorine pesticides from the 1950s up to the year 2000 are reconstructed, showing, for each individual chemical, the influence of long range transport, as well as of local transport patterns. The role of mountain glaciers as natural archives for studying the local and global transport of persistent organic pollutants is highlighted, though results can be biased by volatilisation losses.     

On vector autoregressive modeling in space and time

Despite the fact that it provides a potentially useful analytical tool, allowing for the joint modeling of dynamic interdependencies within a group of connected areas, until lately the VAR approach had received little attention in regional science and spatial economic analysis. This paper aims to contribute in this field by dealing with the issues of parameter identification and estimation and of structural impulse response analysis. In particular, there is a discussion of the adaptation of the recursive identification scheme (which represents one of the more common approaches in the time series VAR literature) to a space-time environment. Parameter estimation is subsequently based on the Full Information Maximum Likelihood (FIML) method, a standard approach in structural VAR analysis. As a convenient tool to summarize the information conveyed by regional dynamic multipliers with a specific emphasis on the scope of spatial spillover effects, a synthetic space-time impulse response function (STIR) is introduced, portraying average effects as a function of displacement in time and space. Asymptotic confidence bands for the STIR estimates are also derived from bootstrap estimates of the standard errors. Finally, to provide a basic illustration of the methodology, the paper presents an application of a simple bivariate fiscal model fitted to data for Italian NUTS 2 regions.     

Comparing quality of estuarine and nearshore intertidal habitats for Carcinus maenas

Estuarine and nearshore marine areas are vital habitats for several fish and benthic invertebrates. The shore crab Carcinus maenas (Crustacea: Brachyura: Portunidae) inhabits a variety of coastal, estuarine and lagoon habitats. At low tide, habitat structural complexity may be most important for crabs in the intertidal, providing refuge from predation and desiccation. The quality of different vegetated and nonvegetated estuarine and rocky shore habitats in SW Portugal and SW England was evaluated for intertidal C. maenas populations. We estimated population density, size–structure, and potential growth (RNA/DNA ratios) to investigate habitat quality. Vegetated estuarine habitats supported higher crab densities, than nonvegetated estuarine and rocky shore habitats. Investigation of population size–structure revealed that all habitats seem important recruitment and nursery areas although estuarine habitats in SW Portugal appeared to support higher densities of new recruits than equivalent habitats in SW England. Significant variation was found in RNA/DNA ratios among habitats. Ratios were highest in the rocky shore suggesting a high quality habitat where growth potential is high. We speculate that competition from other top-predators (Pachygrapsus spp.) rather than low habitat quality may limit the occurrence of C. maenas in intertidal rocky shore habitats in SW Portugal. In estuarine environments RNA/DNA ratios were significantly higher in the vegetated than in the nonvegetated estuarine habitats in SW Portugal but not in SW England, suggesting geographic differences in the extent to which highly structure habitats represent high quality. Our results challenge the current paradigm that structured habitats are necessarily those of higher quality for C. maenas.