High‐resolution synchrotron X‐ray fluorescence investigation of calcite coralloid speleothems: Elemental incorporation and their potential as environmental archives

Synchrotron high‐resolution and micro‐X‐ray fluorescence elemental mapping of two coeval coralloid speleothems from Lamalunga Cave (Italy) are complemented with petrographic, morphological and microstratigraphic studies. The importance of these speleothems relies on their direct and indirect association with a complete Neanderthal skeleton (‘Altamura Man’) found inside the cave. The coralloids grew discontinuously between 64·6 ka and the Holocene and reveal exceptionally high concentrations of Mg, Sr and Si, particularly on convex surfaces, where evaporation is more intense. The incorporation of trace elements depends on several factors including location, shape and geometrical evolution during their growth, as well as climate and environmental parameters. This resulted in calcite precipitation with Sr compositions from 100 to 1200 ppm and an average concentration of 7000 ppm Mg. An unusually high Si content (up to 16%) is possibly derived from volcanic ash transported as particulate and in solution inside the cave. The most common fabrics observed consist of non‐fluorescent elongated columnar calcite forming clean isopachous bands and fluorescent fibre‐like crystals associated with laminated, lenticular bands high in Sr, Mg and Si. Variability in Sr, Mg and Si concentrations appears to induce fabric changes in the coralloids. Elongation and lattice distortion of the crystals was found to coincide with high Mg concentrations. The transition from compact elongated to open to fibre‐like, is here interpreted as due to high concentrations of Si and Sr, which are preferentially incorporated in the speleothem at crystal boundaries and intra‐laminae. It is here inferred that coralloid fabric changes and their elemental content potentially record local rainfall variations through time, with the clean compact calcite marking high infiltration and open fibre‐like and micrite fabrics recording dry periods.     

Using tracer tests and hydrological observations to evaluate effects of tunnel drainage on groundwater and surface waters in the Northern Apennines (Italy)

The impact of a railway tunnel on groundwater and surface waters in the Northern Apennines (Italy) was demonstrated and characterised by multi-tracer tests and hydrological observations. The 15-km-long Firenzuola tunnel crosses turbidite marls and sandstones previously not considered as aquifers. During the drilling, water inrushes occurred at fracture zones, and the tunnel still continues to drain the aquifer. The water table dropped below the level of the valleys, and gaining streams transformed into losing streams or ran completely dry, as did many springs, causing severe damage to the aquatic fauna and other elements of the ecosystem. Two multi-tracer tests, each using uranine and sulforhodamine G, were carried out in two impacted catchments in order to confirm and quantify the stream–aquifer–tunnel interrelations. The results proved connection between losing streams and numerous water inlets in the tunnel, with maximum linear distances of 1.4 km and velocities up to 135 m/d. Several of the demonstrated flowpaths pass under previous groundwater divides (mountain ridges), proving that the tunnel has completely modified the regional flow system. Water balance estimations demonstrate that the observed water losses cannot be explained by climate change but can largely be attributed to the tunnel drainage.     

Geophysical investigations of the plumbing system of Stromboli volcano (Aeolian Islands,Italy)

In this work, we report the results of an integrated approach using both seismological and geodetic data provided by the INGV-CT (Istituto Nazionale di Geofisica e Vulcanologia, Sezione di Catania) Stromboli volcano monitoring systems, in order to improve the knowledge of its plumbing system. In particular, we investigated the relationships between the June 1999 seismic swarm, occurring in the area of Stromboli, and the possible activation of the NE–SW oriented volcano-tectonic structure. We analyzed this seismic swarm proposing new locations and a morphological analysis of the waveforms. This approach allowed us to demonstrate that there are relationships between the tectonic activity near Stromboli and the rising of magma. This evidence supports the hypothesis that during the 1999 swarm an intrusive process started from a crustal level where earthquakes were located (about 10–15 km b.s.l.).     

Magnetic indicator of global paleoclimate cycles in Siberian loess–paleosol sequences

The loess–paleosol sequences of China, Siberia, Alaska and many other regions, along with lake sediments and glaciers, provide the only accurate paleoclimatic terrestrial records for intervals of thousands to hundreds of thousand years. The frequency dependence (FD) of magnetic susceptibility (MS) in such sequences has become the leading parameter for analyzing climatic change and Milankovitch (astronomical) periodicity in Siberian sequences; it is always higher in soil horizons than in loess. The enhanced FD parameter in soils is associated with ferromagnetic minerals, mostly magnetite, produced during pedogenesis. The MS and FD parameters of 670 samples from five sections in Siberia are reported here. Inter-section correlation is used to produce a combined FD time series for the studied sections. Chronological control is established by absolute dating and stratigraphic correlation. Spectral analysis of the FD time series reveals the presence of Milankovitch signals at ～100 kyr (eccentricity), ～40 kyr (obliquity) and ～23 kyr (precession) and demonstrates that Siberian loess–paleosol sequences are excellent continental recorders of long-term paleoclimatic changes. This suggests that the FD parameter can potentially be used more widely for evaluation of climate periodicity in loess/paleosol sequences in other parts of the world.     

Spatial patterning of water quality in Biscayne Bay, Florida as a function of land use and water management

An objective classification analysis was performed on a water quality data set from 25 sites collected monthly during 1994-2003. The water quality parameters measured included: TN, TON, DIN, NH4+, NO3-, NO2-, TP, SRP, TN:TP ratio, TOC, DO, CHL A, turbidity, salinity and temperature. Based on this spatial analysis, Biscayne Bay was divided into five zones having similar water quality characteristics. A robust nutrient gradient, driven mostly by dissolved inorganic nitrogen, from alongshore to offshore in the main Bay, was a large determinant in the spatial clustering. Two of these zones (Alongshore and Inshore) were heavily influenced by freshwater input from four canals which drain the South Dade agricultural area, Black Point Landfill, and sewage treatment plant. The North Bay zone, with high turbidity, phytoplankton biomass, total phosphorus, and low DO, was affected by runoff from five canals, the Munisport Landfill, and the urban landscape. The South Bay zone, an embayment surrounded by mangrove wetlands with little urban development, was high in dissolved organic constituents but low in inorganic nutrients. The Main Bay was the area most influenced by water exchange with the Atlantic Ocean and showed the lowest nutrient concentrations. The water quality in Biscayne Bay is therefore highly dependent of the land use and influence from the watershed.     

Architecture and recognition criteria of ancient shelf ridges; an example from Campanian Almond Formation in Hanna Basin,USA

Shelf ridges are sedimentary bodies formed on the continental shelf due to transgressive reworking (tidal or storm) of lowstand deposits. Common on modern shelves, they are under‐represented in the geological record due to a lack of recognition criteria and facies model. This article proposes a new facies and architectural model for shelf ridges, linked to their inception–evolution–abandonment cycle and the process regime of the basin. The model is mainly based on new outcrop data and interpretations from three sandstone bodies of the Almond Formation, an overall transgressive interval during the infill of the Campanian Western Interior Seaway. Building from the case study, and ancient and modern examples, six characteristics are proposed for the recognition of ancient shelf ridges. Shelf ridges: (i) are encased between thick marine mudstone intervals; (ii) have a basal unconformity that erodes into marine muds or into the remnants of a previous shoreline; (iii) have a non‐erosional upper boundary that transitions into marine muds; (iv) are characterized by clean and well‐sorted sandstones, often cross‐bedded; (v) contain fully marine ichnofauna; and (vi) present compound architectures with large accretion surfaces and lower order structures. Although shelf ridges have been described in previous studies as generated exclusively by either tidal or storm currents, it is clear, from modern examples and the case study, that these two processes can be recorded and preserved in a single shelf ridge. The stratigraphy of these sandstone bodies is therefore much more complex than previously recognized, bearing the signature of changing tidal and storm intensity through time. Because they are developed during transgressions, shelf ridges are commonly subject to strong changes in process regime as sea‐level changes can easily affect the oceanographic conditions and the morphology of the basin. For this reason, shelf ridges can provide the best record of shelf process variability during transgressions.     

Facies system of the Eastern Barents Sea since the last glaciation to present

Twenty-two sediment cores raised from the central and eastern parts of the Barents Sea have been studied to reconstruct the evolution of the facies system since the Late Weichselian glaciation. Multiproxy records reveal four lithostratigraphic units, which reflect major development stages of paleoenvironments. Age control is provided by 23 AMS ¹⁴C dates for Holocene sections of four cores. Continental moraine deposits of the last glaciation are overlain by proximal glaciomarine facies of the initial deglaciation phase. During this phase, the Barents Sea ice sheet detached from the ground resulting in seawater penetration into troughs, iceberg calving, deposition of IRD and fine-grained glacier meltwater load in newly formed marine basins. The main deglaciation phase is characterized by pulsed sedimentation from various gravity flows resulting in accumulation of distal glaciomarine facies comprising laminated clay and sand sequences with minor IRD. Redistribution of fine-grained suspended matter by bottom currents and brine-induced nepheloid flows combined with biogenic processes and minor ice rafting caused facies diversity of the Holocene marine sediments. The Holocene facies of shelf depressions reflect rather high, but variable productivity responding to climate changes and variations of Atlantic water inflow into the Barents Sea.     

Interaction between shallow and deep aquifers in the Tivoli Plain (Central Italy) enhanced by groundwater extraction: A multi-isotope approach and geochemical modeling

In the Tivoli Plain (Rome, Central Italy) the interaction between shallow and deep groundwater flow systems enhanced by groundwater extraction has been investigated using isotopic and chemical tracers. A conceptual model of the groundwater flowpaths has been developed and verified by geochemical modeling. A combined hydrogeochemical and isotopic investigation using ion relationships such as DIC/Cl⁻, Ca/(Ca + Mg)/SO₄/(SO₄ + HCO₃), and environmental isotopes (δ¹⁸O, δ²H, ⁸⁷Sr/⁸⁶Sr, δ³⁴S and δ¹³C) was carried out in order to determine the sources of recharge of the aquifer, the origin of solutes and the mixing processes in groundwater of Tivoli Plain. Multivariate statistical methods such as principal component analysis and Cluster analyses have confirmed the existence of different geochemical facies and the role of mixing in the chemical composition of the groundwater.     

Biogeochemical effects of disturbance in shallow water sediment by macroalgae harvesting boats

In the shallow water of Orbetello lagoon, macroalgae harvesting boats produce sediment disturbance. To evaluate the effect of this, during 2001-2002, a trial study was carried out in the lagoon in order to: verify seasonal and diurnal trends in nutrients and estimate the quantity of resuspended organic sediment. An unbalanced and balanced ANOVA (one and two way) analysis was applied. The disturbance did not produce strong and lasting eutrophication effects. In the seasonal survey, dissolved inorganic nitrogen (DIN) and soluble reactive phosphorus (SRP) showed significant decreases in disturbed areas at the end of the trial, while the control area showed a constant, significant increase. Dissolved organic nitrogen (DON) and phosphorus (DOP) significantly increased everywhere. In disturbed areas, sediment redox (Eh((NHE))) increased and porosity values decreased, contrary to the control area. Total organic carbon (TOC) remained unchanged in disturbed areas, but increased in the control area, where the C:P ration increased. The fall-out of sedimentary material resuspended by boat action for as far as 50 m from the boat route, was 189 g(dw)m(-2) made up mainly of organic matter. This disturbance could be the cause of change in vegetation in the lagoon.     

Monitoring a Marine Coastal Area: Use of Mytilus galloprovincialis and Mullus barbatus as Bioindicators

Abstract. Samples of Mytilus galloprovincialis and Mullus barbatus were collected in eight coastal sites along the South Adriatic and Ionic coasts of Italy in spring 2000 for a survey of coastal pollution in the Mediterranean basin. Specimens were analysed using an integrated approach based on residue analysis of common aquatic pollutants like organochlorines such as hexachlorobenzene (HCB), DDTs and polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), heavy metals and nonylphenols (NPnE) and biomarker responses such as acetylcholinesterase (AChE) activity, and the two specific P450 activities benzo(a)pyrene monooxygenase (BPMO) and 7-ethoxyre-sorufin-(9-deethylase (EROD). Biological and morphological parameters like somatic liver index (SLI), gonadosomatic index (GSI) and gonadal and gamete histology (eggs and sperms) were also evaluated in red mullet samples. A contamination gradient in which several hot spots occur were revealed in this study. The hot spots account for high levels of organochlorines in both species near incinerators and of PAHs in harbour areas. Levels of both NPnE and AChE activity were highest in two protected marine areas and were within detectable limits in others. This finding was confirmed by P450 activities, in which maximum levels were detected in harbours and protected marine areas. No morphological alterations of male and female gonads were observed on the histological level.