Low-temperature hydrothermal alteration of intra-caldera tuffs,Miocene Tejeda caldera,Gran Canaria,Canary Islands

The Miocene Tejeda caldera on Gran Canaria erupted ~ 20 rhyolite–trachyte ignimbrites (Mogán Group 14–13.3 Ma), followed by ~ 20 phonolitic lava flows and ignimbrites (Fataga Group 13–8.5 Ma). Upper-Mogán tuffs have been severely altered immediately within the caldera margin, whereas extra-caldera Mogán ignimbrites, and overlying Fataga units, are apparently unaltered. The altered intra-caldera samples contain minerals characteristic of secondary fluid–rock interaction (clays, zeolites, adularia), and relics of the primary mineral assemblage identified in unaltered ignimbrites (K-feldspar, plagioclase, pyroxene, amphibole, and groundmass quartz). Major and trace-element data indicate that Si, Na, K, Pb, Sr, and Rb, were strongly mobilized during fluid–rock interaction, whereas Ti, Zr, and Nb behaved in a more refractory manner, experiencing only minor mobilization. The δ¹⁸O values of the altered intra-caldera tuffs are significantly higher than in unaltered extra-caldera ignimbrites, consistent with an overall low-temperature alteration environment. Unaltered extra-caldera ignimbrites have δD values between − 110‰ and − 173‰, which may reflect Rayleigh-type magma degassing and/or post-depositional vapour release. The δD values of the altered intra-caldera tuffs range from − 52‰ to − 131‰, with ambient meteoric water at the alteration site estimated at ca. − 15‰. Interaction and equilibration of the intra-caldera tuffs with ambient meteoric water at low temperature can only account for whole-rock δD values of around − 45‰, given that ?D_clay–water is ca. − 30‰ at 100 °C, and decreases in magnitude at higher temperatures. All altered tuff samples have δD values that are substantially lower than − 45‰, indicating interaction with a meteoric water source with a δD value more negative than − 15‰, which may have been produced in low-temperature steam fumaroles. Supported by numerical modeling, our Gran Canaria data reflect the near-surface, epithermal part of a larger, fault-controlled hydrothermal system associated with the emplacement of the high-level Fataga magma chamber system. In this near-surface environment, fluid temperatures probably did not exceed 200–250 °C.     

Pedoarchaeology of Cactus Hill,a sandy Paleoindian site in southeastern Virginia,U.S.A.

Cactus Hill is located in the Virginia Coastal Plain on a terrace above the Nottoway River. The site has a record of occupation that spans the Holocene and also offers evidence of humans late in the Pleistocene before Clovis time. Soil investigations identified several deposit types, and demonstrated that multisequal eolian sands forming the site's primary core are arrayed in spatially and temporally discrete horizons. Resting atop an ancient paleosol, the earliest sand stratum (19,540 ± 70 ¹⁴C yr B.P.) is marked by a conspicuous but culturally sterile buried surface horizon. Eolian sand above this surface supports another sequum in which Clovis and underlying “Blade” artifacts are associated with a fainter surface horizon and pronounced subsoil lamellae. Early Archaic and successively younger artifacts occur above the Clovis level in a more weakly developed uppermost sequum. This soil and cultural stratigraphy, together with considerations of regional topography, demonstrate that the landscape has evolved incrementally since about the last glacial maximum. © 2004 Wiley Periodicals, Inc.     

The Extended Delaunay Method Applied to First Order Resonance

This paper is concerned with the extended Delaunay method as well as the method of integration of the equations, applied to first order resonance. The equations of the transformation of the extended Delaunay method are analyzed in the (p + 1)/p type resonance in order to build formal, analytical solutions for the resonant problem with more than one degree of freedom. With this it is possible to gain a better insight into the method, opening the possibility for more generalized applications. A first order resonance in the first approximation is carried out, giving a better comprehension of the method, including showing how to eliminate the ‘Poincaré singularity’ in the higher orders. This revised version was published online in July 2006 with corrections to the Cover Date.     

Laser combustion analysis of δS of sulfosalt minerals: determination of the fractionation systematics and some crystal-chemical considerations

Laser sulfur combustion in the presence of O₂ is the most commonly used method of in situ sulfur isotope analysis. Previous workers indicated that a small but reproducible fractionation of ³⁴S/³²S exists between the product SO₂ gas and the mineral. The magnitude of this fractionation varies with bond strength, as reflected in Gibbs free energy of formation at 298.15K. The correction factors are known for common sulfides and anhydrite but not, hitherto, for stibnite and the sulfosalt minerals, which are important constituents of many classes of ore deposits. We present the correction factors for the following chemically and crystallographically well-characterized minerals: stibnite (weighted mean = −1.2‰), bournonite (+0.6‰), tetrahedrite (+1.3‰), and boulangerite (+1.4‰). The Gibbs free energies of formation of these phases have been approximated by the sulfide summation method, and the correlation of ΔG₂₉₈⁰ with the correction factor for the sulfosalts fits well with the trend previously established for simple sulfides. There is an excellent correlation between the fractionation factor and mineral composition, a parameter that does result in bond strength variations (e.g., mol fraction of PbS in sulfosalts), allowing estimation of the correction factors for simple intermediate compositions. Finally, bond strength also varies with variation in interatomic distances, and we have, therefore, investigated the behaviour of stibnite, a strongly anisotropic mineral. Our results indicate that there is a significant variation in fractionation factor, depending on crystal orientation. The fractionation factor along the prismatic b-axis, which displays the strongest chemical bonds (as monitored by the shortest bond lengths), is more negative (−1.7‰) than along the other crystallographic directions (−0.7 to −1.0‰), which is in full agreement with theoretical predictions. We demonstrate the application of the technique in unravelling source- and process-related sulfur isotope systematics in two hydrothermal vein systems in the classic mining area of the NE Rhenish Massif, both studies requiring resolution beyond the scale of conventional sulfur isotope analysis.     

The structure of the polar ionosphere during exceptionally quiet periods

Knowledge of the structure of the polar ionosphere during exceptionally quiet periods is basic for studying complicated ionospheric behaviors during disturbances. On the basis of data from an airborne ionosonde as well as a meridian chain of ground-basedionosondes, the circumpolar structure of the E,-and F-regions is elucidated. There are two circumpolar zones of E-region ionization with differing characteristics. The first is an auroral E,-layer and/or retarded type sporadic E-band that has previously (Whalen et al., 1971) been found to be identical with the continuous aurora. The second is a zone of non-retarded type spora die E located poleward of the former band. In general, discrete auroras are co-located with the latter. The main trough, a prominent feature of the night sector F-region, is most pronounced in the early morning. The main trough is bounded on the poleward side by a well defined ‘wall’ of F-region ionization. The night sector poleward trough wall is located approximately three degrees of latitude equatorward of the auroral oval. A ‘plateau’ of F-region ionization extends from the poleward trough wall to the auroral oval.     

Observations of a post-flare radio burst in X-rays

More than six hours after the two-ribbon flare of 21 May 1980, the hard X-ray spectrometer aboard the SMM imaged an extensive arch above the flare region which proved to be the lowest part of a stationary post-flare noise storm recorded at the same time at Culgoora. The X-ray arch extended over 3 or more arc minutes to a projected distance of 95 000 km, and its real altitude was most probably between 110 000 and 180 000 km. The mean electron density in the cloud was close to 10⁹ cm^–3 and its temperature stayed for many hours at a fairly constant value of about 6.5 × 10⁶ K. The bent crystal spectrometer aboard the SMM confirms that the arch emission was basically thermal. Variations in brightness and energy spectrum at one of the supposed footpoints of the arch seem to correlate in time with radio brightness suggesting that suprathermal particles from the radio noise regions dumped in variable quantities into the low corona and transition layer; these particles may have contributed to the population of the arch, after being trapped and thermalized. The arch extended along the H = 0 line thus apparently hindering any upward movement of the upper loops reconnected in the flare process. There is evidence from Culgoora that this obstacle may have been present above the flare since 15–30 min after its onset.     

The High Altitude Observatory Coronagraph/Polarimeter on the Solar Maximum Mission

The High Altitude Observatory Coronagraph/Polarimeter, to be flown on the National Aeronautics and Space Administration's Solar Maximum Mission satellite, is designed to produce images of the solar corona in seven wavelength bands in the visible spectral range. The spectral bands have been chosen to specifically exclude or include chromospheric spectral lines, so as to allow discrimination between ejecta at high (coronal) and low (chromospheric) temperatures, respectively. In addition, the instrument features spectral filters designed to permit an accurate color separation of the F and K coronal components, and a narrow band (5.5 Å) filter to observe the radiance and polarization of the Fe xiv 5303 Å line. The effective system resolution is better than 10 arc sec and the instrument images a selected quadrant (or smaller field) on an SEC vidicon detector. The total height range that may be recorded encompasses 1.6 to more than 6.0R (from Sun center). The instrument is pointed independently of the SMM spacecraft, and its functions are controlled through the use of a program resident within the onboard spacecraft computer. Major experimental goals include: (a) Observation of the role of the corona in the flare process and of the ejecta from the flare site and the overlying corona; (b) the study of the direction of magnetic fields in stable coronal forms, and, perhaps, ejecta; and (c) examination of the evolution of the solar corona near the period of solar maximum activity.The National Center for Atmospheric Research is sponsored by the National Science Foundation.