Interplay of S and As in Mekong Delta sediments during redox oscillations

The cumulative effects of periodic redox cycling on the mobility of As,Fe,and S from alluvial sediment to groundwater were investigated in bioreactor experiments.Two particular sediments from the alluvial floodplain of the Mekong Delta River were investigated:Matrix A(14 m deep)had a higher pyrite concentration than matrix B(7 m deep)sediments.Gypsum was present in matrix B but absent in matrix A.In the reactors,the sediment suspensions were supplemented with As(Ⅲ)and SO_4~(2-),and were subjected to three full-redox cycles entailing phases of nitrogen/CO_2,compressed air sparging,and cellobiose addition.Major differences in As concentration and speciation were observed upon redox cycling.Evidences support the fact that initial sediment composition is the main factor controlling arsenic release and its speciation during the redox cycles.Indeed,a high pyrite content associated with a low SO_4~(2-)content resulted in an increase in dissolved As concentrations,mainly in the form of As(Ⅲ),after anoxic half-cycles;whereas a decrease in As concentrations mainly in the form of As(Ⅴ),was instead observed after oxic half-cycles.In addition,oxic conditions were found to be responsible for pyrite and arsenian pyrite oxidation,increasing the As pool available for mobilization.The same processes seem to occur in sediment with the presence of gypsum,but,in this case,dissolved As were sequestered by biotic or abiotic redox reactions occurring in the Fe—S system,and by specific physico-chemical condition(e.g.pH).The contrasting results obtained for two sediments sampled from the same core show that many complexes and entangled factors are at work,and further refinement is needed to explain the spatial and temporal variability of As release to groundwater of the Mekong River Delta(Vietnam).     

Crack nucleation in saturated porous media

Crack nucleation has been the subject of important contributions in the last two last decades. However, it seems that few attention has been granted to the case of saturated porous media. This is the question addressed in the present paper which is devoted to nucleation in traction mode. From a physical point of view, nucleation is a sudden phenomenon, so that the material response is both adiabatic and undrained. In the spirit of the variational approach, the nucleated crack is viewed as the final state of a region of space in which the material undergoes a full damage process. In traction mode, the opening of a saturated crack in undrained condition induces a drop of fluid pressure. In case of low fluid compressibility, the presence of the fluid delays the brittle failure usually associated with nucleation, as long as the fluid pressure remains above the saturation vapor pressure. Nucleation is therefore possible only if a partial vaporization of the fluid takes place.     

The information system of the French Peatland Observation Service: Service National d'Observation Tourbières – A valuable tool to assess the impact of global changes on the hydrology and biogeochemistry of temperate peatlands through long term monitoring

Mitigating and adapting to global changes requires a better understanding of the response of the Biosphere to these environmental variations. Human disturbances and their effects act in the long term (decades to centuries) and consequently, a similar time frame is needed to fully understand the hydrological and biogeochemical functioning of a natural system. To this end, the ‘Centre National de la Recherche Scientifique’ (CNRS) promotes and certifies long-term monitoring tools called national observation services or ‘Service National d'Observation’ (SNO) in a large range of hydrological and biogeochemical systems (e.g., cryosphere, catchments, aquifers). The SNO investigating peatlands, the SNO ‘Tourbières’, was certified in 2011 ( https://www.sno-tourbieres.cnrs.fr/ ). Peatlands are mostly found in the high latitudes of the northern hemisphere and French peatlands are located in the southern part of this area. Thus, they are located in environmental conditions that will occur in northern peatlands in coming decades or centuries and can be considered as sentinels. The SNO Tourbières is composed of four peatlands: La Guette (lowland central France), Landemarais (lowland oceanic western France), Frasne (upland continental eastern France) and Bernadouze (upland southern France). Thirty target variables are monitored to study the hydrological and biogeochemical functioning of the sites. They are grouped into four datasets: hydrology, fluvial export of organic matter, greenhouse gas fluxes and meteorology/soil physics. The data from all sites follow a common processing chain from the sensors to the public repository. The raw data are stored on an FTP server. After operator or automatic processing, data are stored in a database, from which a web application extracts the data to make them available ( https://data-snot.cnrs.fr/data-access/ ). Each year at least, an archive of each dataset is stored in Zenodo, with a digital object identifier (DOI) attribution ( https://zenodo.org/communities/sno_tourbieres_data/ ).     

Magnitude of latent heat in thermally loaded clays

Temperature changes are known to induce specific couplings in clay, in particular, an anomalously high thermal pressurization in undrained conditions or a thermal compaction in drained conditions, both of which are potential threats for the mechanical stability and sealing capacity of the geomaterials. Thermodynamical analysis of those peculiar thermomechanical couplings points to a potentially important latent energy, which in turn could limit the temperature change upon heating or cooling. The direct measurement of latent energy developed during a laboratory geomechanical test is challenging. Instead, proper identification of thermal hardening in conventional experiments with temperature changes provides an alternative route to estimate latent energy. In this work, existing laboratory thermomechanical tests of clays are analyzed with a rigorous thermodynamic framework to quantify the magnitude of latent energy in thermomechanically loaded clays. A thermodynamically consistent constitutive model for fully saturated clays that combines two key features, (a) the temperature dependence of the blocked energy and (b) the framework of bounding plasticity, is proposed. The performance of the model is validated by reproducing results obtained in laboratory tests for Boom and Opalinus clays. The thermomechanical loads considered to validate the model performance were then used to estimate the percentage of work that remains latent in the clayey material during plastic yielding. We find that the magnitude of latent energy is quite significant, typically a few tens of percent of the total dissipated energy, and increases significantly with temperature. Accordingly, it is expected to play an important role in the thermomechanical response of clays.     

Catchment properties,function, and conceptual model representation: is there a correspondence?

This study investigates the possible correspondence between catchment structure, as represented by perceptual hydrological models developed from fieldwork investigations, and mathematical model structures, selected on the basis of reproducing observed catchment hydrographs. Three Luxembourgish headwater catchments are considered, where previous fieldwork suggested distinct flow‐generating mechanisms and hydrological dynamics. A set of lumped conceptual model structures are hypothesized and implemented using the SUPERFLEX framework. Following parameter calibration, the model performance is examined in terms of predictive accuracy, quantification of uncertainty, and the ability to reproduce the flow–duration curve signature. Our key research question is whether differences in the performance of the conceptual model structures can be interpreted based on the dominant catchment processes suggested from fieldwork investigations. For example, we propose that the permeable bedrock and the presence of multiple aquifers in the Huewelerbach catchment may explain the superior performance of model structures with storage elements connected in parallel. Conversely, model structures with serial connections perform better in the Weierbach and Wollefsbach catchments, which are characterized by impermeable bedrock and dominated by lateral flow. The presence of threshold dynamics in the Weierbach and Wollefsbach catchments may favour nonlinear models, while the smoother dynamics of the larger Huewelerbach catchment were suitably reproduced by linear models. It is also shown how hydrologically distinct processes can be effectively described by the same mathematical model components. Major research questions are reviewed, including the correspondence between hydrological processes at different levels of scale and how best to synthesize the experimentalist's and modeller's perspectives. Copyright © 2013 John Wiley & Sons, Ltd.     

Dark Matter in Wide Triple Systems of Galaxies

Numerical models for wide triplets of galaxies are developed, and a statistical estimate of the dark matter content in these systems is derived. In a typical system, the mass of dark matter proves to be (1.5 - 3) × 1012h-1 M.     

Analytical and empirical models for predicting the drift capacity of modern unreinforced masonry walls

Displacement‐based seismic assessment of buildings containing unreinforced masonry (URM) walls requires as input, among others, estimates of the in‐plane drift capacity at the considered limit states. Current codes assess the drift capacity of URM walls by means of empirical models with most codes relating the drift capacity to the failure mode and wall slenderness. Comparisons with experimental results show that such relationships result in large scatter and usually do not provide satisfactory predictions. The objective of this paper is to determine trends in drift capacities of modern URM walls from 61 experimental tests and to investigate whether analytical models could lead to more reliable estimates of the displacement capacity than the currently used empirical models. A recently developed analytical model for the prediction of the ultimate drift capacity for both shear and flexure controlled URM walls is introduced and simplified into an equation that is suitable for code implementation. The approach follows the idea of plastic hinge models for reinforced concrete or steel structures. It explicitly considers the influence of crushing due to flexural or shear failure in URM walls and takes into account the effect of kinematic and static boundary conditions on the drift capacity. Finally, the performance of the analytical model is benchmarked against the test data and other empirical formulations. It shows that it yields significantly better estimates than empirical models in current codes. The paper concludes with an investigation of the sensitivity of the ultimate drift capacity to the wall geometry, static, and kinematic boundary conditions.     

Melt migration and melt-rock reaction in the Alpine-Apennine peridotites:Insights on mantle dynamics in extending lithosphere

The compositional variability of the lithospheric mantle at extensional settings is largely caused by the reactive percolation of uprising melts in the thermal boundary layer and in lithospheric environments.The Alpine-Apennine(A-A)ophiolites are predominantly constituted by mantle peridotites and are widely thought to represent analogs of the oceanic lithosphere formed at ocean/continent transition and slow-to ultraslow-spreading settings.Structural and geochemical studies on the A-A mantle peridotites have revealed that they preserve significant compositional and isotopic heterogeneity at variable scale,reflecting a long-lived multi-stage melt migration,intrusion and melt-rock interaction history,occurred at different lithospheric depths during progressive uplift.The A-A mantle peridotites thus constitute a unique window on mantle dynamics and lithosphere-asthenosphere interactions in very slow spreading environments.In this work,we review field,microstructural and chemical-isotopic evidence on the major stages of melt percolation and melt-rock interaction recorded by the A-A peridotites and discuss their consequences in creating chemical-isotopic heterogeneities at variable scales and enhancing weakening and deformation of the extending mantle.Focus will be on three most important stages:(i)old(pre-Jurassic)pyroxenite emplacement,and the significant isotopic modification induced in the host mantle by pyroxenite-derived melts,(ii)melt-peridotite interactions during Jurassic mantle exhumation,i.e.the open-system reactive porous flow at spinel facies depths causing bulk depletion(origin of reactive harzburgites and dunites),and the shallower melt impregnation which originated plagioclase-rich peridotites and an overall mantle refertilization.We infer that migrating melts largely originated as shallow,variably depleted,melt fractions,and acquired Si-rich composition by reactive dissolution of mantle pyroxenes during upward migration.Such melt-rock reaction processes share significant similarities with those documented in modern oceanic peridotites from slow-to ultraslow-spreading environments and track the progressive exhumation of large mantle sectors at shallow depths in oceanic settings where a thicker thermal boundary layer exists,as a consequence of slow-spreading rate.     

Provenance discrimination of fine sediments by mid-infrared spectroscopy: Calibration and application to fluvial palaeo-environmental reconstruction

Determining sediment provenance allows a better understanding of fluvial palaeo-dynamics, and identifying involved watersheds, at broad spatio-temporal scales. Conventional approaches for source identification are usually based on the physical, mineralogical, geochemical, magnetic or isotopic properties of sediments. Rapid, non-destructive and, in well-established contexts, highly accurate, mid-infrared spectroscopy is an alternative method for investigating sediment sources. The present research objectives are: (i) to use the mid-infrared spectroscopy method to discriminate the provenance of fine sediments, by applying discriminant analysis on a large set of reference samples from three different watersheds in the Upper Rhine area (associated with the Rhine, Ill and Vosges tributaries); (ii) to clarify whether the provenance spectra signatures are influenced by riverine depositional contexts (bars versus banks) and, to some extent, by grain size and/or high organic matter content; and (iii) to apply the mid-infrared spectroscopy – discriminant analysis method to a study of fluvial palaeo-dynamics and determine the provenance of palaeo-channel infillings. Three main sedimentary sources, divided into eight sub-categories, have been characterized by 196 modern reference samples from 78 collecting sites. Discriminant analysis displayed a strong separating power by classifying correctly the origin of samples without any inter-group overlap, independently from the geomorphological context (bar or bank) and associated slight changes in organic matter contents or grain size. Mid-infrared spectroscopy – discriminant analysis investigations of the palaeo-channel infill, complemented by radiocarbon dates and mineralogical data, allowed reconstructing general trends for the local morpho-sedimentary dynamics over the last ca 12 millennia.     

Beerkan multi-runs for characterizing water infiltration and spatial variability of soil hydraulic properties across scales

A method is presented for characterizing the spatial variability of water infiltration and soil hydraulic properties at the transect and field scales. The method involves monitoring a set of 10 Beerkan runs distributed over a 1-m length of soil, and running BEST (Beerkan estimation of soil transfer parameters) methods to derive hydraulic parameters. The Beerkan multi-runs (BMR) method provides a significant amount of data at the transect scale, allowing the determination of correlations between water infiltration variables and hydraulic parameters, and the detection of specific runs affected by preferential flow or water repellence. The realization of several BMRs at several transects on the same site allows comparison of the variation between locations (spatial variability at the field scale) and at the transect scale (spatial variability at the metre scale), using analysis of variance. From the results, we determined the spatial variability of water infiltration and hydraulic parameters as well as its characteristic scale (transect versus field).