Note on the seismicity of northeastern Italy (Friuli area)

The kinematics and mechanics of the seismicity of the Friuli area in northeastern Italy are discussed, especially the focal mechanism of the catastrophic earthquake of May 6, 1976. Alternative solutions are analyzed. A N-S section, down to 60 km below sea-level, across the Alps from the Bavarian foreland to the Adriatic Sea illustrates these possibilities.     

Characterisation of Soot Emitted by Domestic Heating,Aircraft and Cars Using Diesel or Biodiesel

The characterisation of aggregates, like soot, firstly requires the determination of the size distribution of the primary particles. The primary particle size of combustion generated aggregates depends upon the combustion environment and the formation conditions, such as temperature, pressure and fuel-to-air ratio, among others. Since the combustion characteristics are different in the different types of burners, the characterisation of primary particles may offer the possibility to distinguish soot from different sources. In this paper, we present the signature of the primary particles and the aggregates of soot emitted by cars using diesel or biodiesel, by domestic heating, and by aircraft exhausts, which can be considered as the major sources as derived from measurements on transmission electron micrographs. The size distributions of all aggregates types with different aerodynamic diameter were log-normal and quasi-monodisperse. The size distribution of the primary particles for soot emitted by different sources showed minor differences. However, a comparison between the diameter of the primary particles and those obtained using a standard method for carbon black revealed discrepancies. The median diameter of the primary particles was combined with the median number of primary particles in an aggregate to calculate the relative particle surface area available for adsorption. In a similar way, the relative specific surface area was determined. The surface area was measured using the Brunauer-Emmett-Teller (B.E.T.) nitrogen adsorption method and the relative surface area available for adsorption was calculated.     

Nighttime convection in the interior of a dense Douglas fir forest

Infrared radiative surface temperatures as observed over a dense Douglas fir forest during stable atmospheric conditions are analyzed. It is shown that the concept of a single surface temperature to describe both the thermal coupling and the radiative coupling between atmosphere and forest fails when longwave cooling is large and wind speeds are low. In such cases a decoupling of the radiative surface temperature from the air temperature aloft is observed. Conditions for decoupling are formulated in terms of an appropriate Richardson number. It is shown that a convective surface temperature comes into play that is coupled to the forest interior air temperature. Observed radiative surface temperature is then composed of this convective surface temperature and the aerodynamic surface temperature. Forest interior air temperature during nighttime is, in general, lower than air temperature above the canopy. A simple two-layer canopy model is used to explain this phenomenon in terms of the distribution of atmospheric sensible heat flux and storage heat flux over the two canopy layers.     

Zinc speciation in the Northeastern Atlantic Ocean

Measurements of zinc and zinc complexation by natural organic ligands in the northeastern part of the Atlantic Ocean were made using cathodic stripping voltammetry with ligand competition. Total zinc concentrations ranged from 0.3 nM in surface waters to 2 nM at 2000 m for open-ocean waters, whilst nearer the English coast, zinc concentrations reached 1.5 nM in the upper water column. In open-ocean waters zinc speciation was dominated by complexation to a natural organic ligand with conditional stability constant (log K_ZnL′) ranging between 10.0 and 10.5 and with ligand concentrations ranging between 0.4 and 2.5 nM. The ligand was found to be uniformly distributed throughout the water column even though zinc concentrations increased with depth. Organic ligand concentrations measured in this study are similar to those published for the North Pacific. However the log K_ZnL′ values for the North Atlantic are almost and order of magnitude lower than those reported by Bruland [Bruland, K.W., 1989. Complexation of zinc by natural organic-ligands in the central North Pacific. Limnol. Oceanogr., 34, 269–285.] using anodic stripping voltammetry for the North Pacific. Free zinc ion concentrations were low in open-ocean waters (6–20 pM) but are not low enough to limit growth of a typical oceanic species of phytoplankton.     

Nonlinear and 3D effects in leaky infragravity waves

In this paper, infragravity (IG) waves, forced by normally and obliquely incident wave groups, are studied using the quasi-3D (Q3D) nearshore circulation model SHORECIRC [Van Dongeren, A.R., I.A. Svendsen, 1997b. Quasi 3-D modeling of nearshore hydrodynamics. Research report CACR-97-04. Center for Applied Coastal Research, University of Delaware, Newark, 243 pp.], which includes the Q3D effects. The governing equations that form the basis of the model, as well as the numerical model and the boundary conditions, are described. The model is applied to the case of leaky IG waves. It is shown that the Q3D terms have a significant effect on the cross-shore variation of the surface elevation envelope, especially around the breakpoint and in the inner surf zone. The effect of wave groupiness on the temporal and spatial variation of all Q3D terms is shown after which their contribution to the momentum equations is analyzed. This reveals that only those Q3D coefficients, which appear in combination with the largest horizontal velocity shears make a significant contribution to the momentum equations. As a result of the calculation of the Q3D coefficients, the IG wave velocity profiles can be determined. This shows that in the surf zone, the velocity profiles exhibit a large curvature and time variation in the cross-shore direction, and a small — but essential — depth variation in the longshore direction.     

Stress state in the Cuu Long and Nam Con Son basins, offshore Vietnam

The results presented in this paper are the first published estimates of the complete stress tensor in the Cuu Long and Nam Con Son basins, offshore Vietnam. We analysed in situ stress and pore pressure fields in the sedimentary formations using data from petroleum exploration and production wells to evaluate the stress state in these basins. The data were obtained from the seafloor to 4300 m burial depth and include both hydrostatic and overpressured sections. Minimum horizontal stresses were obtained from extended leak-off tests and mini-fracture tests. Maximum horizontal stresses were estimated from drilling-induced fracture parameters and borehole breakout widths in twelve wells using rock properties measured in the laboratory or estimated empirically from wireline logs. Seven data points are located in sediments, and seventeen data points in igneous basement rocks at depths greater than 3000 m.The estimated magnitudes of σ_H are 70-110% of the σ_v magnitudes. Considering the errors in the stress magnitude estimates, their relative magnitudes suggest that a borderline normal/strike-slip stress regime presently exists in normally pressured sequences of the Nam Con Son and Cuu Long basins. Of the twenty-four data points, twenty have effective stress ratios at a critical stress state for faulting on the assumption that there are faults present that are optimally oriented for failure with friction coefficients of ∼0.5. The results suggest that the stress state in these basins is generally critical.     

An aromatase inhibitor and tamoxifen decrease plasma levels of o,p'-DDT and its metabolites in Nile tilapia (Oreochromis niloticus)

The objective of this study was to determine if tamoxifen or an aromatase inhibitor (4-hydroxyandrostenedione; 4-OHA) affected plasma concentrations of o,p' -DDT and its metabolites, o,p'-DDD and o,p'-DDE, in mature tilapia. Male and female tilapia were injected 6 times intraperitoneally with o,p'-DDT (40 mg/kg) alone or in combination with 4-OHA (2 mg/kg) over a 12 day period. An additional group of male fish was injected with tamoxifen (5 mg/kg) plus o,p'-DDT. At the end of the treatment period, plasma samples were extracted and analyzed by GC/ECD. Females injected only with o,p'-DDT had significantly higher levels of o,p'-DDT compared with males. Interestingly, females and males treated concomitantly with o,p'-DDT and 4-OHA or tamoxifen had significantly lower concentrations of plasma o,p'-DDT (about 50%) compared with fish treated with only o,p'-DDT. These initial results suggest that an interaction between endocrine-active compounds occurs in vivo in tilapia and may involve alterations in metabolism of o,p'-DDT.     

Upper temperature tolerances of exotic brackish-water mussel, Mytilopsis leucophaeata (Conrad): an experimental study

The dark false mussel, Mytilopsis leucophaeata is an important mussel colonising the brackish-water systems of temperate and subtropical regions. Of late it has earned notoriety as a biofouling species in industrial cooling water systems. However, there are no published data on the temperature tolerance of this species. This paper presents data on the upper temperature tolerance of this mussel from the view point of biofouling control using thermal methods. In addition to mortality, response of physiological activities such as oxygen consumption, filtration rate, foot activity and byssus thread production were also studied at temperatures varying from 5 to 35 degrees C. Experiments were also carried out to understand the effect of mussel size, breeding condition, nutritional status and acclimation conditions (temperature and salinity) on the mortality pattern. The physiological activities were significantly reduced at temperatures beyond 27.5 degrees C and ceased at 35 degrees C. In 20 mm size group mussels exposed to 37 degrees C, 50% mortality was observed after 85 min and 100% mortality after 113 min. The effect of mussel size on mortality at different temperatures was significant, with the larger size group mussels showing greater resistance. M. leucophaeata collected during the non-breeding season (December-April) were more tolerant to temperature than those collected during the breeding season (June-October). Nutritional status of the mussel had no significant influence on the thermal tolerance of the mussel: fed and starved (non-fed) mussels succumbed to temperature at comparable rates. The effect of acclimation temperature and acclimation salinity on M. leucophaeata mortality at different temperatures was significant. Survival time increased with increasing acclimation temperature and decreased with increasing salinity. In comparison with other co-occurring species such as Mytilus edulis and Dreissena polymorpha, M. leucophaeata appears to be more tolerant to high temperature stress.     

The Potential for Environmentally Sound Development of Marine Deposits of Potassic and Phosphatic Minerals Offshore, Southern Africa

Extensive potassium and phosphorous-rich mineralization occurs on the outer continental shelf of the southern and west coasts of South Africa and Nambia. This article reviews the potential of exploiting these deposits in an environmentally sound manner for the manufacture of fertilizer. At present, reserves of potash and phosphate fertilizer are exploited from terresterial deposits, the majority being surface mined. The use of fertilizer in South Africa has shown no growth in the past 13 years, and, in some years, usage has even declined. On average, over the last decade, South Africa has consumed 2 million Mt of fertilizer (including nitrogen) per annum, the vast majority of phosphate fertilizer being produced by FOSKOR from the Phalaborwa Igneous Complex. Potash fertilizer is imported into South Africa. Although fertilizer consumption is expected to decrease in the short-term, there are good future prospects for the domestic and international fertilizer market. Considerable research into both glauconitic (containing K 2 O) and phosphatic deposits along the southern African continental shelf indicate that these sedimentary deposits have a complex genesis and mineralization. Of the total K 2 O reserves of 1300 million Mt on the southern African margin, 1000 million Mt is located off the southern African west coast, and the remainder situated on the Agulhas Bank. The largest glauconite concentration ( ±300 million Mt K 2 O) off southern Africa lies west of Saldanha Bay, South Africa. The distribution of P 2 O 5 off southern Africa is dominated by the vast deposit between Walvis Bay and Luderitz, Nambia. This reserve is estimated to contain 1000 million Mt of greater than 5% P 2 O 5 in a relatively small area of about 10000 km2. The phosphorite deposit south of Saldanha Bay constitutes a reserve of ±3500 million Mt of apatite and the deposit on the Agulhas Bank comprises 5500 million Mt. The phosphate deposit off Saldanha Bay occurs as an extensive, low to medium grade deposit. Although vast resources of potash and phosphatic minerals occur along the southern African outer continental shelf the expensive nature of marine exploitation may render most of these deposits, especially the phosphates, subeconomic. The low price of fertilizer andextensive natureontheonland deposits, although confined to asmallnumber of countries, mean that it will not be financially viable to extract these deposits. Assuming high grade glauconitic sand with the right composition can be located, the high market price indicates good future prospects for these potash deposits.