Measuring low concentrations of Th in water and sediment

²³⁴Th/²³⁸U disequilibria have been used extensively in studies of particle dynamics and the fate and transport of particle-reactive matter in marine environments. Similar work in low salinity, estuarine, and freshwater systems has not occurred primarily because the lower concentrations of both parent and daughter nuclides that are typical of these systems often render established methods for the analysis of ²³⁴Th inadequate. The application of this radionuclide tracer technique to these systems, however, has great potential. To this end, we present a method for measuring low activities of ²³⁴Th in relatively small samples (<200 l) using low background gas-flow proportional counters, a ²²⁹Th yield monitor, and empirical corrections for the interferences from real and apparent betas that are emitted by other thorium isotopes and their progeny. For samples with low ²³⁴Th/²²⁸Th activity ratios, we improve upon current beta counting methodologies that rely on immediate sample counting, weak beta absorption, or multiple beta counts so that, using the analytical approach outlined here, it should be possible to measure ²³⁴Th activities (i) as low as 1.5 dpm/total sample, (ii) up to 2 weeks after radiochemical purification of thorium, and (iii) with only one sample count for alpha and beta activity.     

A phytoplankton class-specific primary production model applied to the Kerguelen Islands region (Southern Ocean)

As part of the KErguelen: compared study of the Ocean and the Plateau in Surface water (KEOPS) project in late summer 2005, we examine the phytoplankton community composition and associated primary production in the waters surrounding the Kerguelen Archipelago, with the emphasis on two contrasted environments: (i) the Kerguelen Plateau, where a large bloom occurs annually, and (ii) the high-nutrient low-chlorophyll (HNLC) offshore waters. A biomarker pigment approach was used to assess the community composition in terms of chlorophyll biomass of three phytoplankton size classes, namely micro-, nano-, and picophytoplankton. The second objective was to evaluate a global class-specific approach for estimating the contribution of the three pigment-based size classes to the primary production in the study area. To do so, primary production rates associated with each phytoplankton class were computed from the class-specific chlorophyll biomass coupled to a class-specific primary production model, and compared with in situ measurements of size-fractionated ¹³C-based primary production. The iron-enriched bloom region was dominated by microphytoplankton (diatoms), which contributed 80–90% to the total primary production (of ≈1 g C m^?2 d^?1). In the HNLC area, the primary production was about 0.30 g C m^?2 d^?1, mainly (65%) achieved by small diatoms and nanoflagellates. The model results show a good overall agreement between predicted and measured total primary production rates. In terms of size classes, agreements were higher for the bloom region than for the HNLC waters. Discrepancies in this complex iron-limited area may be explained essentially by the smaller size of diatoms, or a different set of photophysiological properties.     

Nutrient dynamics at the sediment-water interface in a Mediterranean lagoon (Thau, France): influence of biodeposition by shellfish farming activities

The Thau Lagoon, a French Mediterranean shallow lagoon, is a site where extensive shellfish farming occurs. The aim of the present work is to evaluate the role of this activity on nutrient exchange at the sediment-water interface in relation to organic matter (OM) sedimentation and degradation. Two stations inside (C5) and outside (C4) of the shellfish farming areas were sampled at three seasons. Porewater chemistry surveys and calculated diffusive fluxes were used to evaluate the trophic status of the Thau lagoon. Quantitative (Particulate Organic Carbon) as well as qualitative OM (Hydrogen Index, Carbohydrates) analyses were performed on sediments to assess OM characteristics. Results emphasized that surficial sediments at C5 are always more enriched in OM. Porewater nutrient concentrations are 10-20 times higher at C5 than at C4. In June 2003, the porewater profiles exhibit a sharp gradient at the bottom waters, indicating a hypereutrophic status, leading to an anoxic crisis.     

Hydroclimatic variations over the last two glacial/interglacial cycles at Lake Urmia,Iran

A coarse-resolution, absolutely dated isotope record spanning the last 180 ka was constructed from aragonite-rich fecal pellets in a sediment core from Lake Urmia, Iran. The isotope record is not continuous as a consequence of detrital calcite that contaminates the pellets at certain depths. An isotopic correction was applied to samples > 50% aragonite, using the δ¹⁸O values of calcite-only pellets. Absolute dates were derived from U-Th analyses on pellets > 80% aragonite. The resultant δ¹⁸O record and sediment lithofacies confirm that the Penultimate Glacial was cold and dry, with pronounced interstadials at ca. 150 and >175 ka. Deglaciation began at ca. 130 ka, but climate was unstable and supported a probable no-analog vegetation assemblage. The onset of true interglacial conditions occurred at ca. 126 ka. Peak moisture conditions lasted for 5–6 ka before the climate became drier, with the loss of some tree taxa towards the end of the Last Interglacial. A period of greater moisture occurred between 116 and 108 ka, overlapping in timing with interstadial conditions recorded in the Soreq Cave speleothem record. In general, stadial to interstadial transitions (OIS 5d-5c, 5b-5a) are marked by decreasing δ¹⁸O values and rising lake levels. The nature of the OIS 5 to OIS 4 transition cannot be resolved in this study because of the loss of 5 m of core and imprecise dates. According to the present chronology, δ¹⁸O values, and inferred lake levels, arid conditions began at 60 ka and persisted until Termination I. Episodic increases in moisture, characterized by layers of aragonite-rich pellets, ostracodes, and the pollen of trees and/or aquatic plants, occurred during the Last Glacial. Deglaciation associated with the Late-glacial Interstadial began at 14 ka but was interrupted by a marked Younger Dryas event that resulted in renewed aridity. The Holocene began at approximately 10 ka. Despite large errors in the chronology, the overall timing and pattern of effective moisture matches the record from Soreq Cave, Israel, suggesting that the two regions were climatically in-phase.     

Offshore petroleum and commercial fishery interactions: The case of Long Point,Port Dover,Lake Erie

GeoJournal - From a human ecological perspective, research was undertaken on interactions between Lake Erie fisheries and offshore petroleum (gas) development from 1913 to summer, 1981. In an...     

Chemical characterization of porewaters in an intertidal mudflat of the Seine estuary: relationship to erosion-deposition cycles

A seasonal field study was carried out in the Seine estuary to determine the chemistry of sediment porewaters using the 'peeper' technique and changes in the elevation of the mudflats using the 'Altus' technique. This approach allowed us to evaluate the release of nutrients and to link these releases to the sediment hydrodynamics. Our results show that nutrient and organic matter cycling in a Seine estuary mudflat exhibits a seasonal behaviour, which is mainly influenced by variations in hydrodynamics. Sediments, rich organic matter, were input during floods and they were mineralized during summer and autumn, releasing nutrients and dissolved organic carbon into the sediment porewaters. The nutrient release, including ammonium, is mainly linked to the mineralization of organic matter, while the release of phosphate is delayed. The delay could be the result of phosphate association with organic matter and/or its co-precipitation with calcium and iron.     

Analyse isotopique de l'air piégé dans la glace pour quantifier les variations de température

Isotopic measurements in polar ice core have shown a succession of rapid warming periods during the last glacial period over Greenland. However, this method underestimates the surface temperature variations. A new method based on gas thermal diffusion in the firn manages to quantify surface temperature variations through associated isotopic fractionations. We developed a method to extract air from the ice and to perform isotopic measurements to reduce analytical uncertainties to 0.006 and 0.020$\text{‰}$ for δ¹⁵N and δ⁴⁰Ar. It led to a 16±1.5 °C surface temperature variation during a rapid warming ($\text{?70}\text{000}$ yr). To cite this article: A. Landais et al., C. R. Geoscience 336 (2004).     

Prévision des crues éclair

Flash-flood events resulting from paroxystic meteorological events concentrated in time and space are insufficiently documented as they produce destructive effects. They are hardly measurable and present single features that are not transposable to another event. In the South of France, the flash flood of November 1999 gives a perfect illustration of these characteristics. The physical complexity of the process and consequently the volume and the variety of the data to take into account are incompatible with the real time constraint allocated to the forecasters confronted to the occurrence of such phenomena. So, we have to make choices to afford acceptable simplifications to the complete mechanical model. MARINE (‘Modélisation de l'Anticipation du Ruissellement et des Inondations pour des évéNements Extrêmes’) is the operational and robust tool we developed for flash-flood forecasting. This model complies with the criterions of real-time simulation. It is a physically based distributed model composed of two parts: first the flood runoff process simulation in the upstream part of the basin modelled from a rainfall–runoff approach, then the flood propagation in the main rivers described by the Saint-Venant equations. It integrates remote sensed data – Digital Elevation Model, land-use map, hydrographic network for the observations from satellites and the rainfall evolution from meteorological radar. The main goal of MARINE is to supply real time pertinent information to the forecasters. Results obtained on the Orbieu River (Aude, France) show that this model is able to supply pertinent flood hydrograph with a sufficient precision for the forecasting service to take the appropriate safety decisions. Furthermore, MARINE has already been tested in the French National Flood Forecasting Service of Haute-Garonne in real conditions. To cite this article: V. Estupina Borrell et al., C. R. Geoscience 337 (2005).     

Cusp geometry in MHD simulations

The MHD simulations described here show that the latitude of the high-altitude cusp decreases as the IMF swings from North to South, that there is a pronounced dawn–dusk asymmetry at high-altitude associated with a dawn–dusk component of the IMF, and that at the same time there is also a pronounced dawn–dusk asymmetry at low-altitude. The simulations generate a feature that represents what has been called the cleft. It appears as a tail (when the IMF has a B_y component) attached to the cusp, extending either toward the dawn flank or the dusk flank depending on the dawn–dusk orientation of the IMF. This one-sided cleft connects the cusp to the magnetospheric sash. We compare cusp geometry predicted by MHD simulations against published observations based on Hawkeye and DMSP data. Regarding the high-altitude predictions, the comparisons are not definitive, mainly because the observations are incomplete or mutually inconsistent. Regarding the low-altitude prediction of a strong dawn–dusk asymmetry, the observations are unambiguous and are in good qualitative agreement with the prediction.