P–T–fluid evolution in the Mahalapye Complex, Limpopo high-grade terrane, eastern Botswana

Metapelites, migmatites and granites from the c. 2 Ga Mahalapye Complex have been studied for determining the P–T–fluid influence on mineral assemblages and local equilibrium compositions in the rocks from the extreme southwestern part of the Central Zone of the Limpopo high‐grade terrane in Botswana. It was found that fluid infiltration played a leading role in the formation of the rocks. This conclusion is based on both well‐developed textures inferred to record metasomatic reactions, such as Bt ? And + Qtz + (K₂O) and Bt ± Qtz ? Sil + Kfs + Ms ± Pl, and zonation of Ms | Bt + Qtz | And + Qtz and Grt | Crd | Pl | Kfs + Qtz reflecting a perfect mobility (Korzhinskii terminology) of some chemical components. The conclusion is also supported by the results of a fluid inclusion study. CO₂ and H₂O ( = 0.6) are the major components of the fluid. The fluid has been trapped synchronously along the retrograde P–T path. The P–T path was derived using mineral thermobarometry and a combination of mineral thermometry and fluid inclusion density data. The Mahalapye Complex experienced low‐pressure granulite facies metamorphism with a retrograde evolution from 770 °C and 5.5 kbar to 560 °C and 2 kbar, presumably at c. 2 Ga.     

Contrasting morphodynamics in alluvial fans and fan deltas: effect of the downstream boundary

Alluvial fans and fan deltas can, in principle, have exactly the same upstream conditions, but fan deltas by definition have ponding water at their downstream boundary. This ponding creates effects on the autogenic behaviour of fan deltas, such as backwater adaptation, mouth bars and backward sedimentation, whereas alluvial fans may lack these effects. Hence the present authors hypothesize that morphodynamics on alluvial fans are determined primarily by upstream boundary conditions, whereas morphodynamics on fan deltas are determined by both the upstream and the downstream boundary condition and changes therein. To isolate the effects of the upstream and downstream boundaries, five new alluvial fan experiments are compared with the details of three fan deltas published earlier that were formed under very similar and simple conditions. Similar to the fan deltas, the alluvial fans build up by sheet flow, whilst quasi‐regular periods of incision cause temporary channelized flow. Incision is followed by channel backfilling, after which the fan returns to sheet flow. The channelization and backfilling in alluvial fans is markedly less pronounced and more prone to autogenic disturbance than in fan deltas. The difference is caused by morphodynamics at the downstream boundary. In a fan delta, the flow expansion of the channel causes deposition of all the sediment, which forms a mouth bar and causes strong backfilling. In an alluvial fan, on the other hand, the slope break at the fan perimeter causes some deposition, but transport is not reduced to zero. Consequently, the backfilling in alluvial fans is less pronounced than in fan deltas. Other published experiments support this trend: removal of the mouth bar by a river leads to permanent channelization, whilst pronounced mouth‐bar formation in highly channelized deltas promotes backward sedimentation. The experimental results for this study predict that, when alluvial fans prograde into lakes or deep rivers, they transition to fan deltas with increasingly deeper channels and thicker backfill deposits.     

Chemographic relationships of biotite and cordierite in the McGerrigle thermal aureole, Gaspé, Quebec

Abstract Biotite and cordierite occur in a 1-km wide zone of pelitic hornfelses around the McGerrigle pluton. These phases display systematic changes in X _Fe that can be attributed to continuous reactions involving chlorite or andalusite in the system KFMASH. Through much of the zone biotite and cordierite were products of the 'breakdown'of chlorite. Close to the pluton this continuous reaction was terminated by a discontinuous reaction that introduced andalusite. Pelites which interdigitate with apophyses of the intrusive at the pluton margin contain assemblages that record a continuous reaction between biotite, cordierite, andalusite, muscovite, and quartz or, alternatively, the discontinuous breakdown of muscovite and quartz to K-feldspar and andalusite.
The mole fraction of Fe in biotite and cordierite increased significantly with the progress of the first continuous reaction and apparently decreased during the second continuous reaction. The K _D of Fe-Mg between the minerals decreased and apparently increased, respectively, during the two reactions.
Biotite-cordierite-chlorite assemblages are interpreted to have been stable at temperatures between 525° C and 615° C and biotite-cordierite-andalusite assemblages stable at temperatures between 615° C and 635° C. The confining pressure was estimated to have been < 2 kbar.
The results of this study suggest that the K _D of Fe-Mg between biotite and cordierite is a function of temperature, the Fe-Mg exchange characteristics of the controlling continuous reaction and non-ideal mixing of Fe and Mg.     

NUMERICAL MODELLING OF STANDARD AND CONTINUOUS VERTICAL ELECTRICAL SOUNDINGS1

Analytical solutions of vertical electrical soundings (VES) have mostly been applied to groundwater exploration and monitoring groundwater quality on terrains of fairly simple geology and geomorphology on which the electrode arrays are symmetrical (e.g. Schlumberger or Wenner configurations). The sounding interpretation assumes flat topography and horizontally stratified layers. Any deviations from these simple situations may be impossible to interpret analytically. The recently developed GEA-58 geoelectrical instrument can make continuous soundings along a profile with any colinear electrode configuration. This paper describes the use of finite-difference and finite-element methods to model complex earth resistivity distributions in 2D, in order to calculate apparent resistivity responses to any colinear current electrode distribution in terrains in which the earth resistivities do not vary along the strike. The numerical model results for simple situations are compared with the analytical solutions. In addition, a pseudo-depth section of apparent resistivities measured in the field with the GEA-58 is compared with the numerical solution of a real complex resistivity distribution along a cross-section. The model results show excellent agreement with the corresponding analytical and experimental data.     

Source and Differentiation of Deccan Trap Lavas: Implications of Geochemical and Mineral Chemical Variations

The basalt stratigraphy of the Deccan Trap between MahabaleshwarGhat and Belgaum over-steps the basement from north to south.Sr-isotope and Zr/Nb ratios, and Sr, Rb, and Ba concentrationscorrelate portions of the post-Poladpur stratigraphy over 250km along the Western Ghats, thereby confirming a southerly componentof dip of 0?06?. At the southwestern margin, the stratigraphyextends upwards from the compositionally uniform Ambenali Formation(Cox & Hawkesworth, 1984) into a sequence of grossly heterogeneousflow units which have been allocated to the Mahabaleshwar andPanhala Formations (Lightfoot & Hawkesworth, 1988). TheMahabaleshwar Formation is represented only by a sequence ofhighly fractionated flows (termed the Kolhapur unit) with similar⁸⁷Sr/⁸⁶Sr₀ to the Mahabaleshwar (0?7045), but with Sr<240ppm and TiO₂>2?25%. Succeeding the Kolhapur unit are a seriesof flows with high ⁸⁷Sr/⁸⁶Sr₀ (0?7045-0?705), Zr/Nb > 13,and low Sr (< 200 ppm), which have been allocated to thePanhala Formation, and a group of flows with high ⁸⁷Sr/⁸⁶Sr₀(0?707–0?708) and Sr (>230), but trace element concentrationssimilar to the Mahabaleshwar Formation; these have been allocatedto the Desur unit of the Panhala. Geochemical variations in flows overlying the Ambenali definetwo distinct trends: one is attributed to gabbro fractionation,and the other to variations in the compositions of the parentalmagmas, and arguably their source regions. There is little evidencefor significant crustal contamination in these flows, and thedegree of fractionation and the composition of the phase extractare shown to vary along strike within the Mahabaleshwar Formation.The high TiO₂ content of Kolhapur unit flows is shown to bethe result of shallow-level gabbro fractionation, rather thanthe presence of a primitive high-Ti magma. Mahabaleshwar Formationbasalts exhibit a broad negative correlation between the degreeof fractionation and Sr-isotopic composition. The endmemberwith lower ⁸⁷Sr/⁸⁶Sr₀ has different Zr/Y from the Ambenali basalts,and would appear to have been generated by lower degrees ofmelting of a similar source. The other endmember has more radiogenicSr, lower Zr/Nb, similar Zr/Y, but higher mg-number. The simplestinterpretation is that these magmas were more primitive andhence hotter and more able to interact with the lithosphereen route to the surface, and that they then mixed to producethe Mahabaleshwar array. The Panhala Formation basalts ploton the Sr-Nd array defined by the Mahabaleshwar Formation, andthe Desur unit basalts plot on an extension of this array; thissuggests that the source characteristics are also lithospheric.The absolute elemental abundances may then be a function ofmelting and fractionation. We are impressed by the apparentswitch from crustal lithospheric contributions to mantle lithosphericcontributions through the stratigraphy, and suggest that this,together with the more protracted fractionation of the magma,reflects a change in the availability of the lithospheric componentsaccompanying the southerly migration of the volcanic edifice. ^* Present address: Geoscience Laboratories, Ontario Geological Survey, 11th Floor, 77, Grenville Street, Toronto, Ontario, M7A 1W4, Canada     

Growth, Production, and a Partial Energy Budget for the Amphipod, Talorchestia capensis (Crustacea; Talitridae) in the Eastern Cape, South Africa

Abstract. .A population of Talorchestia capensis was sampled in dune slacks over the period of one year. Two hatching periods, one in March and one in September, were observed. Growth was rapid, the amphipods reaching a size of 8.4 mm standard length in 18 months. Maximum growth occurred in spring and minimum growth in winter. Annual mortality rates for summer- and winter-hatched individuals were low, 0.22-y“¹ and 0.16-y”¹. Average production for the summer classes was 7.2g-y?‘ (dry mass) and for the winter classes 2.9-y“¹, with a P/B ratio of 2.25-y”’. Production values peaked during autumn and summer. Abundance and biomass estimates showed maxima during summer and minima in early spring. Reproductive output was low, 0.1 kJ ? m^-2 y“¹, indicating that 7 % of the total production is used for reproduction and 93 % for somatic production. The assimilated energy flow through the population was estimated to be 16.3 kJ m?² y?‘ and consumption about 81.6 kJ m^-2 y^_’.     

The effects of climate variability on discharge as dependent on catchment characteristics in the Upper Loire basin,France

Abstract

The effects of climatically deviating periods of at least four years on discharge were investigated employing flow duration curves in the Upper Loire basin, France. The periods were determined using the standardized cumulative yearly deviation from the mean precipitation for ten climate stations. Flow duration curves from 27 catchments were determined and parameterized for each period. Results show that the effect of precipitation on discharge is more pronounced than the effect of temperature. They also show that the parameter values that determine the flow duration curve differ significantly between dry and wet periods. Furthermore the effect of drought on discharge is larger than the effect of wetness. Catchments with a high variability of discharge are more sensitive to changes of precipitation than catchments with a low variability of discharge.     

Using estimated thermodynamic properties to model accessory phases: the case of tourmaline

Accessory phases and minor components in minerals are commonly ignored in thermodynamic modelling. Such an approach seems unwarranted, as accessory phases can represent a significant element reservoir and minor components can substantially change their host mineral's stability field. However, a lack of thermodynamic data prohibits assessment of these effects. In this contribution, the polyhedron method is used to estimate the thermodynamic properties of tourmaline, a common and widespread accessory phase, stable over a range of P–T–X conditions. The polyhedron method allows Δ H , S , V , C _P and V _m ( T , P ) properties to be estimated from a linear stoichiometric summation over the fractional properties of its polyhedron constituents. To allow for estimates of tourmaline, fractional thermodynamic properties for B^III and B^IV polyhedra were derived. Mixing contributions to molar volume were evaluated and symmetrical mixing parameters derived for Al-Mg, Al-Fe and Al-Li interaction on tourmaline's Y-site and T-site Al-Si interaction. Evaluation of the estimated properties using experimental and natural equilibria between tourmaline and melts, minerals and hydrothermal fluids, shows that reliable semi-quantitative results are obtained. The boron contents in fluids coexisting with tourmaline are calculated to within an order of magnitude of measured content, and where anchor-points are available, agreement improves to within a factor of 2. Including tourmaline in petrogenetic modelling of metamorphic rocks indicates that its presence leads to disappearance of staurolite and garnet, among others, and modifies the X _Mg of coexisting phases, in line with observations on natural rocks.