Metamorphic veining and mass transfer in a chemically closed system: a case study in Alpine metabauxites (western Vanoise)

In western Vanoise (French Alps), karstic pockets of Triassic‐to‐Jurassic metabauxites embedded in carbonate rocks and containing several generations of metamorphic veins were studied. During blueschist facies metamorphism, a cumulative amount of ～13 vol% of water is inferred to have been produced locally by successive dehydration reactions, and part of this fluid remained in the bauxitic lenses during most of the metamorphic cycle. Field and geochemical evidence show that these rocks have been isolated from large‐scale fluid flow (closed‐system behaviour). It is proposed that the internally derived fluid has promoted the opening of fluid‐filled open spaces (as attested by the euhedral habits of vein minerals) and served as medium for mass transfer from rock to vein. Indeed, the vein infill is obviously the result of chemical interactions, at the millimetre‐to‐centimetre scale, between the rock minerals and the locally produced aqueous fluid. Two vein types can be distinguished based on mineralogical and textural features: (i) some veins are filled with newly formed products of either prograde (chloritoid) or retrograde (chlorite) metamorphic reactions; in this case, fluid‐filled open spaces seem to offer energetically favourable nucleation/growth sites; (ii) the second vein type is infilled with cookeite or pyrophyllite, that were present in the host rock prior to the vein formation. In this closed chemical system, the components for the vein infill minerals have been transferred from rock to vein through the fluid, in a dissolution–transport–precipitation process, possibly stress‐assisted. These different vein generations all contain Al‐rich mineral infills, suggesting that Al was a mobile element (cm scale) during metamorphism. In these HP rocks, fluid flow may have been restricted, and if so mass transfer occurred by diffusion in an almost stagnant fluid. Metamorphic veins can be seen as witnesses of fluid and mass redistribution that partly accommodate the rock deformation (lateral segregation).     

U-Pb isotopic dating of zircons (SHRIMP-II) from granulites of the Ol’khon region of Western Baikal area

Doklady Earth Sciences -     

Non-linear model for the generation of baroclinic tides over extensive inhomogeneities of the seabed relief

A numerical model is developed for the generation of internal waves induced by a barotropic tidal wave travelling over large bottom features. Motion equations consider the non-linear terms, as well as the terms responsible for horizontal turbulent exchange. The fluid is assumed to be continuously stratified. In the framework of the developed model, a packet of short non-linear internal waves is shown to occur together with a long baroclinic tide. In the absence of non-linear terms in the equations of motion, the model data are qualitatively and quantitatively consistent with the data provided by known linear models.Translated by V. Puchkin.     

Exhumation of the Dayman dome metamorphic core complex, eastern Papua New Guinea

The ～750 km² Dayman dome of the Late Cretaceous Suckling‐Dayman massif, eastern Papua New Guinea, is a domed landform that rises to an elevation of 2850 m. The northern edge of the dome is a fault scarp >1000 m high that is now part of an active microplate boundary separating continental crust of the New Guinea highlands from continental and oceanic crust of the Woodlark microplate. Previous work has shown that a parallel belt of eclogite‐bearing core complexes north‐east of the Dayman dome were exhumed from up to 24–28 kbar in the last few millions of years. The remarkably fresh and lightly eroded scarp of the Dayman dome exposes shallowly‐dipping mylonitic (S1) metabasite rocks (500 m thick) on the northern flank of Mount Dayman. Field relationships near the base of this scarp show a cross cutting suite of ductile and brittle meso‐structures that includes: (i) rare ductile S2 folia with a shallowly ESE‐plunging mineral elongation lineation defined by sodic‐calcic blue amphibole; (ii) narrow steeply‐dipping ductile D2 shear zones; and (iii) semi‐brittle to brittle fault zones. Pumpellyite‐actinolite facies assemblages reported by previous workers to contain local aragonite, lawsonite and/or glaucophane are found in the core of the complex at elevations greater than 2000 m. These assemblages indicate peak metamorphic pressures of 6–9.5 kbar, demonstrating exhumation of the core of the Dayman dome from depths of 20–30 km. The S1 metamorphic mineral assemblage in metabasite includes actinolite‐chlorite‐epidote‐albite‐quartz‐calcite‐titanite, indicative of greenschist facies conditions for the main deformation. New mineral equilibria modelling suggests that this S1 assemblage evolved at 5.9–7.2 kbar at ～425 °C. Modelling variable Fe³⁺ indicates that the sodic‐calcic blue amphibole (D2) formed under a higher oxidation state compared with the S1 assemblage, probably at <4.5 kbar. A SE‐dipping, Mio‐Pliocene sedimentary sequence (Gwoira Conglomerate) forms a hangingwall block juxtaposed by low‐angle fault contact with the metabasite footwall. Prehnite‐bearing D3 brittle fault zones separate the two blocks and likely accommodated the final exhumation of the S1 greenschist facies assemblage in the footwall. These results indicate that the extensive Mt Dayman fault surface coincides with a domed S1 greenschist facies foliation that was last active at >20 km depth. Exhumation of this foliation must therefore be controlled by brittle faults of the active microplate boundary that are largely not observed in the study area. The structural record of the final exhumation of the Dayman dome to the surface was likely lost as a result of erosion, poor exposure or wide spacing of semi‐brittle to brittle fault zones.     

Groups of symmetries in the two‐body problem associated to Einstein's PN field

The two‐body problem associated to a spherical post‐Newtonian (PN) field with Einsteinian parameterization is revisited from the single standpoint of symmetries. The corresponding vector fields, in Hamiltonian and standard polar coordinates, or in collision‐blow‐up and infinity‐blow‐upMcGehee‐type coordinates, present symmetries that form diffeomorphic commutative groups endowed with a Boolean structure. The existence of such symmetries is of much help in understanding characteristics of the global flow, or in finding symmetric periodic orbits in more complex problems depending on a small parameter.     

Results of the solar constant experiment onboard Spacelab 1

A cavity type absolute radiometer was flown on Spacelab 1 in December 1983. We obtain a value of the solar constant of 1361.5 W m^–2 with an estimated accuracy of ±2.3 W m^–2 or 0.17%. When comparing this with other recent determinations, we find discrepancies which we consider indicative of metrological problems in present day absolute radiometry.     

The use of caesium‐137 to estimate agricultural erosion on steep slopes in a tropical watershed

The estimation of erosion and sediment delivery rates in tropical mountain watersheds is difficult and most of the methods widely used for estimating soil erosion over large areas have serious limitations. The ¹³⁷Cs approach has potential for quantifying soil erosion because it can provide retrospective estimates of long‐term (since 1963) net sediment redistribution relatively quickly. Despite its great potential, ¹³⁷Cs has not yet been used in an extensive, reconnaissance level survey of erosion in complex tropical mountain environments. The objective of this study was to examine the applicability of the ¹³⁷Cs method to estimate erosion on steep tropical agricultural lands (23 to 80% slopes) in the Nizao watershed, a humid, tropical mountain area of the Dominican Republic. In this study we (i) examine the variation of ¹³⁷Cs in ten reference sites—eight coffee groves and two forested sites—and (ii) estimate erosion from 14 cultivated fields. The soil pool of ¹³⁷Cs ranged from to 150 to 192 mBq cm⁻² on reference sites with minimal erosion. Variability among reference sites was less than expected for such complex mountain terrain. The variability within coffee and forested reference (average CV=28%) sites was similar to the variability found on grassland and forested reference sites in the temperate zone. The estimated annual soil loss from 14 sampled fields ranged from 6 to 61 t ha⁻¹ year⁻¹ with an overall mean of 26 t ha⁻¹ year⁻¹. Overall, the soil erosion estimates found using the ¹³⁷Cs method were much lower than those often assumed for such steep tropical hillsides. These erosion estimates account for soil loss since 1963 only and it seems likely that soil losses may have been much higher in earlier decades immediately after initial forest clearing earlier in the 20th century. Copyright © 2000 John Wiley & Sons, Ltd.     

Geochemical features of the utilization of buried wastes of the Tyrnyauz Tungsten–Molybdenum Plant using acid leaching

The decontamination of buried wastes of the Tyrnyauz Tungsten–Molybdenum Plant is complicated by the geochemical features of the waste composition: low sulfide and high carbonate content, polyelemental composition, and considerable amounts of technogenic admixtures (kerosene, oils, soda, and soluble glasses). These circumstances result in sufficient complication of the suggested technology of waste treatment, including the sulfuric-acid leaching and separate sorption recovery of hazardous and useful elements from the working solution.     

PGE distribution in deformed lherzolites of the Udachnaya kimberlite pipe (Yakutia)

The results of the first study of the PGE distribution in deformed lherzolites of the Udachnaya kimberlite pipe (Yakutia) are presented here. The complex character of evolution of the PGE composition in the Deformed lherzolites is assumed to be the result of silicate metasomatism. At the first stage, growth in the amount of clinopyroxene and garnet in the rock is accompanied by a decrease in the concentration of the compatible PGE (Os, Ir). During the final stage, the rock is enriched with incompatible PGE (Pt, Pd) and Re possible due to precipitation of submicron-sized particles of sulfides in the interstitial space of these mantle rocks.