Upper Jurassic Rock Depositional Settings in the Baidar Valley and Evolution of the Crimean Carbonate Platform

The paper presents results of the lithological study of Upper Jurassic limestones, flyschoids and limestone breccias on the southern side of the Baidar Valley in the Crimean Mountains. Study of the microfacies revealed that the limestones are represented by deposits on lagoons, platform edge shoals, reefs, and forereef aprons on the carbonate platform slope. Flyschoids include deposits in the distributive turbidite channels and hemipelagic sediments in the deep-water part of the basin. Limestone breccias were formed by gravitation flows on the carbonate platform toe-of-slope and slope. The presence of gravitation deposits in the Upper Jurassic carbonate complexes of the Crimean Mountains can testify to the primary clinoform structure of this sedimentary sequence. Comparison of the obtained sedimentological data made it possible to reconstruct the facies model of the Crimean carbonate platform and main episodes of its formation. Development of the carbonate shelf was related to two transgressive-regressive cycles. A dome-shaped reef was formed away from the coast at the initial (Oxfordian) stage. The carbonate platform was formed at the early Kimmeridgian lowstand stage when sediments were deposited in the internal part of the platform adjacent to land. In the late Kimmeridgian and early Tithonian, configuration of the carbonate platform profile resembled a distally steepened ramp, and its active progradation and shelf expansion took place in the course of transgression. Regression in the late Tithonian–early Berriasian led to regressive transformation of the ramp into platform with a flattened shallow-water shelf. Tectonic deformations at the Jurassic/Cretaceous transition promoted the formation of megabreccias on the carbonate platform foreslope. The tectonically reworked rock sequence of the “extinct” carbonate platform was overlapped transgressively by the upper Berriasian or lower Valanginian, relatively deep-water deposits of the Cretaceous platform cover.     

Exploration rock geochemistry for gold, Parkes, New South Wales, Australia

The London-Victoria lode-type Au deposit near Parkes, New South Wales, was discovered in 1863 and became the subject of modern exploration in 1980 after about 75 years of little or no activity. The deposit lies within Palaeozoic tuffaceous, andesitic rocks. Soil geochemistry was the main technique used to define drill targets, and the deposit is now at an advanced state of assessment for probable development.Rock geochemistry is being investigated as an aid in drill-core interpretation in the search for extensions to the London-Victoria deposit and other similar deposits in the district.At an early stage of the rock-geochemical work it became clear that minor basemetal mineralization was also present in the structural hanging wall at between 30 and 70 m from the lode Au deposit. Interpretation of the geochemical signatures for major elements (Ca, Mg, Na, K, Fe) and trace elements (Cu, Pb, Zn, Mn) is confused by an overlap and merging of responses from the Au and base-metal mineralization. The measurement of bromine-soluble Sb, As, Bi, and Te, together with the more conventional major and trace elements, permits discrimination between geochemical halos related to the Au and those resulting from minor base metal mineralization.The results demonstrate the use of rock geochemistry for Au exploration, its usefulness in drawing attention to geological features, and the utility of bromine-soluble trace elements commonly associated with gold mineralization.     

Phosphorus removal in low alkalinity secondary effluent using alum

The alkalinity plays an important role in phosphorus removal using coagulant. The dosage of coagulant in the low alkalinity wastewater is limited due to rapid pH changes. In the present study, a series of jar test was conducted using low alkalinity wastewater (50 mg/L) to evaluate the optimum pH, dosage and performance parameters (slow mixing and settling time) for the common coagulant alum. From the experiment, it was found that the dosage of coagulant and removal of phosphorus depend upon the pH of the wastewater after adding coagulant. The final optimum pH for efficient P removal was found to be within the range of 5.7–5.9. This range acts as an indicator and it is the maximum tolerable pH range for phosphorus removal for low alkalinity wastewater. The optimum time for slow mix and settling was found to be 20 min. The optimum mole ratio of alum to remove one mole of phosphorous was found to be 2.3. The alum coagulation at pH 7 produced effluent with the total residual phosphorus and reactive phosphorus content of 0.3 and 0.9 mg/L, respectively.     

Geology and geochemistry of archaean felsic metavolcanic rocks of the Eastern Part of the Kolar greenstone belt, Dharwar craton, India: Implications for their petrogenesis and geodynamic setting

In the Kolar greenstone belt of the Dharwar craton, felsic metavolcanics are encountered prominently in its eastern region around Surapalli and Marikoppa. These felsic volcanic rocks are essentially homogeneous and their bulk mineralogy is almost the same. They consist of phenocrysts of quartz and feldspar, set in a fine-grained quartzo-feldspathic groundmass. They are calc-alkaline rhyolite in composition, and are characterized by high SiO₂ (av. 75.74 wt.%), moderate Al₂O₃ (av. 11.84 wt.%), Na₂O (av. 3.55 wt.%), K2O (av. 3.26 wt%) contents and low Mg# (av. 6.07), Cr (av. 8 ppm), Ni (av. 8 ppm), Sr (av. 331 ppm.), Y (av. 7 ppm), Yb (av. 0.87 ppm) and Nb/Ta (av. 6.40) values, suggesting Tonalite-Trondhjemite-Granodiorite (TTG) affinity for these felsic volcanics. They are strongly fractionated [(La/Yb)_N? = 14.41–48.70] with strong LREE enrichment [(La/Sm)_N = 2.50-3.59] and strong HREE depletion [(Gd/Yb)_N = 1.34–2.77] with positive Eu anomaly. The regional geological set-up, petrographic and geochemical characteristics suggest that these felsic volcanics probably were derived by partial melting of a subducting basalt slab at shallow depth without much involvement of mantle wedge in an island arc geodynamic setting.     

ENCORE: the effect of nutrient enrichment on coral reefs. Synthesis of results and conclusions

Coral reef degradation resulting from nutrient enrichment of coastal waters is of increasing global concern. Although effects of nutrients on coral reef organisms have been demonstrated in the laboratory, there is little direct evidence of nutrient effects on coral reef biota in situ. The ENCORE experiment investigated responses of coral reef organisms and processes to controlled additions of dissolved inorganic nitrogen (N) and/or phosphorus (P) on an offshore reef (One Tree Island) at the southern end of the Great Barrier Reef, Australia. A multi-disciplinary team assessed a variety of factors focusing on nutrient dynamics and biotic responses. A controlled and replicated experiment was conducted over two years using twelve small patch reefs ponded at low tide by a coral rim. Treatments included three control reefs (no nutrient addition) and three + N reefs (NH4Cl added), three + P reefs (KH2PO4 added), and three + N + P reefs. Nutrients were added as pulses at each low tide (ca twice per day) by remotely operated units. There were two phases of nutrient additions. During the initial, low-loading phase of the experiment nutrient pulses (mean dose = 11.5 microM NH4+; 2.3 microM PO4(-3)) rapidly declined, reaching near-background levels (mean = 0.9 microM NH4+; 0.5 microM PO4(-3)) within 2-3 h. A variety of biotic processes, assessed over a year during this initial nutrient loading phase, were not significantly affected, with the exception of coral reproduction, which was affected in all nutrient treatments. In Acropora longicyathus and A. aspera, fewer successfully developed embryos were formed, and in A. longicyathus fertilization rates and lipid levels decreased. In the second, high-loading, phase of ENCORE an increased nutrient dosage (mean dose = 36.2 microM NH4+; 5.1 microM PO4(-3)) declining to means of 11.3 microM NH4+ and 2.4 microM PO4(-3) at the end of low tide) was used for a further year, and a variety of significant biotic responses occurred. Encrusting algae incorporated virtually none of the added nutrients. Organisms containing endosymbiotic zooxanthellae (corals and giant clams) assimilated dissolved nutrients rapidly and were responsive to added nutrients. Coral mortality, not detected during the initial low-loading phase, became evident with increased nutrient dosage, particularly in Pocillopora damicornis. Nitrogen additions stunted coral growth, and phosphorus additions had a variable effect. Coral calcification rate and linear extension increased in the presence of added phosphorus but skeletal density was reduced, making corals more susceptible to breakage. Settlement of all coral larvae was reduced in nitrogen treatments, yet settlement of larvae from brooded species was enhanced in phosphorus treatments. Recruitment of stomatopods, benthic crustaceans living in coral rubble, was reduced in nitrogen and nitrogen plus phosphorus treatments. Grazing rates and reproductive effort of various fish species were not affected by the nutrient treatments. Microbial nitrogen transformations in sediments were responsive to nutrient loading with nitrogen fixation significantly increased in phosphorus treatments and denitrification increased in all treatments to which nitrogen had been added. Rates of bioerosion and grazing showed no significant effects of added nutrients. ENCORE has shown that reef organisms and processes investigated in situ were impacted by elevated nutrients. Impacts were dependent on dose level, whether nitrogen and/or phosphorus were elevated and were often species-specific. The impacts were generally sub-lethal and subtle and the treated reefs at the end of the experiment were visually similar to control reefs. Rapid nutrient uptake indicates that nutrient concentrations alone are not adequate to assess nutrient condition of reefs. Sensitive and quantifiable biological indicators need to be developed for coral reef ecosystems. The potential bioindicators identified in ENCORE should be tested in future research on coral reef/nutrient interactions. Synergistic and cumulative effects of elevated nutrients and other environmental parameters, comparative studies of intact vs. disturbed reefs, offshore vs. inshore reefs, or the ability of a nutrient-stressed reef to respond to natural disturbances require elucidation. An expanded understanding of coral reef responses to anthropogenic impacts is necessary, particularly regarding the subtle, sub-lethal effects detected in the ENCORE studies.     

On cumulus-scale transport of horizontal momentum in monsoon depression over India

A diagnostie method of cumulus parameterization is suggested in which vertical transport of horizontal momentum by cumulus-scale is derived by making use of large-scale vorticity as well as divergence budget equations. Data for composite monsoon depression over India available from our earlier studies used to test the method. As a first approximation, the results are obtained using only the vorticity budget equation.The results show that in the southwest sector of the monsoon depression, which is characterized by maximum cloudiness and precipitation, there is an excess of cyclonic vorticity in the lower troposphere and anticyclonic vorticity in the upper troposphere associated with the large-scale motion. The distribution of eddy vertical transport of horizontal momentum is such that anticyclonic vorticity is generated in the lower troposphere and cyclonic vorticity aloft. Cumulus-scale eddies thus work against the large-scale system and tend to off-set the large-scale imbalance in vorticity.     

Impact of increased vertical resolution on simulation of tropical climate

Summary The aim of this study is to describe the behaviour of tropical dynamics in the ECHAM4 model when increased vertical resolution around the tropopause and in the planetary boundary layer is used. In this work we perform experiments with the ECHAM4 model using T30 horizontal resolution and 19 and 42 vertical levels. The impact of the increased vertical resolution on the simulation of tropical clouds and precipitation has been investigated. Therefore, the dynamic fields related to tropical convection have been analyzed. The results suggest a beneficial effect of the increased number of vertical levels on the convective scheme performance and on the related dynamic fields over the Tropics. The improvement of the rainfall climatologies in the 42-level model has been explained via the impact of vertical resolution on the cloud structure. In the cloud spectrum of the L42 simulation, a third peak appears around 600 hPa, revealing that when using higher vertical resolution the convective parametrization starts to represent cumulus congestus clouds.     

U-Pb age and genetic significance of heterogeneous zircon populations in rocks from the Favourable Lake area,Northwestern Ontario

The study evaluates the relationships between measured U-Pb ages and zircon characteristics of five morphologically, texturally, and isotopically complex zircon populations and compares the zircon development stages to the orogenic evolution of the Favourable Lake area. Two distinct zircon types from a hornblendite xenolith in a granitoid batholith of the Sachigo subprovince of the Superior Province yield U-Pb ages of 2729.0±6.8 Ma and 2714.8 _–6.4 ^+7.4 Ma, which date specific metamorphic phases coinciding with major plutonic pulses in the batholith. Zircons from a metamorphosed felsic dike, crosscutting the hornblendite, consist of an old zircon component with a minimum age of 2788 Ma possibly reflecting igneous crystallization 2950 Ma ago, and a younger component with an inferred age of 2725±15 Ma, probably reflecting metamorphism during batholith emplacement.In the Berens River subprovince to the south, granodiorite forms both a late tectonic phase in a large batholith and a post-tectonic pluton intruded into the batholith, yet zircons from these granodiorites have identical ages of 2697.3±1.7 Ma and 2696.2±1.2 Ma, respectively. The late tectonic granodiorite also contains inherited zircons with a minimum age of 2767 Ma which are indirect evidence for the presence of old sialic crust in this subprovince. Zircons from a sheared monzonite near the boundary fault between the two subprovinces yield an upper intercept age of 2769 _–26 ⁺⁶³ Ma, which we interpret as the intrusion age of the monzonite. This rock is older than most dated units in the surrounding batholiths and suggests that the boundary is a long-lived Archean structure.A lower intercept age of about 1750 Ma for zircons of the hornblendite is the result of chemical alteration of the zircons. This, and a similar lower intercept age shown by the sheared monzonite zircons, are thought to reflect increased fluid activity and possibly shearing during the Early Proterozoic Hudsonian orogeny which occurred in the Churchill Province to the northwest. A later Pb-loss mainly from near-surface domains of the zircons is indicated by lower intercept ages of about 500–100 Ma.Publication approved by the Director, Ontario Geological Survey     

Problem of water in the upper mantle: Antigorite breakdown

Doklady Earth Sciences -     

Limestone weathering in Eastern Australia. Part 2: Surface micromorphology study

Results from long term microerosion meter (MEM) studies indicate that microenvironments are characterized by different erosion rates. A complementary study, carried out on the same sites, examines the microscale morphology in each environment. Optical and scanning electron microscopy were used to identify a range of features thought to reflect different processes. Under subaerial conditions micromorphology is dominated by biological weathering features owing to the presence of microflora. Sites permanently covered by soil or stream water have only dissolution etch features, though stream sites may exhibit microfractures. Sites with periodic exposure exhibit both dissolution and biological etch features. The natural environment is more accurately reflected by allowing some microflora colonization of MEM sites rather than preventing colonization by artificial means.