Dissolved nutrient balance and net ecosystem metabolism in a Mediterranean-climate coastal lagoon: San Diego Bay

The temporal and spatial variability of dissolved inorganic phosphate (DIP), nitrogen (DIN), carbon (DIC) and dissolved organic carbon (DOC) were studied in order to determine the net ecosystem metabolism (NEM) of San Diego Bay (SDB), a Mediterranean-climate lagoon. A series of four sampling campaigns were carried out during the rainy (January 2000) and the dry (August 2000 and May and September 2001) seasons. During the dry season, temperature, salinity and DIP, DIC and DOC concentrations increased from oceanic values in the outer bay to higher values at the innermost end of the bay. DIP, DIC and DOC concentrations showed a clear offset from conservative mixing implying production of these dissolved materials inside the bay. During the rainy season, DIP and DOC increased to the head, whereas salinity decreased toward the mouth due to land runoff and river discharges. The distributions of DIP and DOC also showed a deviation from conservative mixing in this season, implying a net addition of these dissolved materials during estuarine mixing within the bay. Mass balance calculations showed that SDB consistently exported DIP (2.8–9.8 × 10³ mol P d⁻¹), DIC (263–352 × 10³ mol C d⁻¹) and DOC (198–1233 × 10³ mol C d⁻¹), whereas DIN (5.5–18.2 × 10³ mol N d⁻¹) was exported in all samplings except in May 2001 when it was imported (8.6 × 10³ mol N d⁻¹). The DIP, DIC and DOC export rates along with the strong relationship between DIP, DIC or DOC and salinity suggest that intense tidal mixing plays an important role in controlling their distributions and that SDB is a source of nutrients and DOC to the Southern California Bight. Furthermore, NEM ranged from −8.1 ± 1.8 mmol C m⁻² d⁻¹ in September to −13.5 ± 5.8 mmol C m⁻² d⁻¹ in January, highlighting the heterotrophic character of SDB. In order to explain the net heterotrophy of this system, we postulate that phytoplankton-derived particulate organic matter, stimulated by upwelling processes in the adjacent coastal waters, is transported into the bay, retained and then remineralized within the system. Our results were compared with those reported for the heterotrophic hypersaline coastal lagoons located in the semi-arid coast of California–Baja California, and with those autotrophic hypersaline systems found in the semi-arid areas of Australia. We point out that the balance between autotrophy and heterotrophy in inverse estuaries is dependent on net external inputs of either inorganic nutrients or organic matter as it has been indicated for positive estuaries.     

Sequence stratigraphic analysis and the origins of Tertiary brown coal lithotypes, Latrobe Valley, Gippsland Basin, Australia

The methods of sequence analysis have been applied to the onshore Gippsland Basin and in particular to the Latrobe Valley Group coal measures which include up to five coal seams each exceeding 100 m in thickness. The methods appear to provide new depositional concepts to the evolution of these seams, and the development of coal lithotypes. In the eastern half of the Latrobe Valley evidence for marine transgressions into the coal measures are recorded in most of the interseam sediment splits by the presence of contained foraminifera and dinoflagellates. To the west (inland) these splits pinch out into continuous coal. However, they can be followed westwards as enhanced organic sulphur levels along sharply defined boundaries between light coal lithotypes below and dark coal lithotypes above. The dark lithotype immediately overlying each of these boundaries contains the highest sulphur value and warmer climate pollen assemblages (Sluiter et al., 1995, this volume).Colorimeter and lithotype logging strongly supports an upwards lightening cyclicity to coal colour at 12–20 m intervals through the approx. 100 m thick seams, with cycle boundaries defined at sharp planar to undulating surfaces. The lightening upward lithotype cycles together with their unique boundary conditions (i.e. enhanced organic sulphur levels, warm climatic indicators and laterally equivalent marine clay splits) are interpreted as parasequences and parasequence boundaries respectively. Each major coal seam can comprise up to five parasequences and is interpreted to represent deposition during an outbuilding high stand systems tract at one of several maximum periods of Tertiary coastal onlap. The top of each major seam shows evidence of truncation (erosion?) on a regional scale and these surfaces are interpreted to represent the sequence boundaries. The major seams are usually conformably underlain by marine clays and extensive aquifer sands, being deposits of the late transgressive systems tracts. The low stands and early parts of the transgressive systems tracts appear not to be represented in the Latrobe Valley due to its (more) basin margin location, but are probably present down-dip in the equivalent marine facies of the Seaspray Group.Stratigraphic correlation of the sequence boundaries identified in the coal measures to the adjacent, internationally dated marine Seaspray Group, provides a basis for chronostratigraphic correlation of the coal successions to the coastal onlap charts of Haq et al. (Exon Mesozoic-Cenozoic chronostratigraphic chart, version January 1988, and August 1989). From this dating it appears that each major seam is confined to high stands of third order eustatic cycles. It therefore follows that the lithotype cycles (parasequences) that comprise each seam are related to fourth order eustatic cycles. By analogy all the coal cycles may have developed under subtropical conditions as ombrogenous forested peat swamps in a similar manner to the Holocene, though tropical, swamps of Indonesia.     

http://www.sciencedirect.com/science/article/pii/S1674987111001034

A comprehensive methodology that integrates Revised Universal Soil Loss Equation（RUSLE） model and Geographic Information System（GIS） techniques was adopted to determine the soil erosion vulnerability of a forested mountainous sub-watershed in Kerala,India.The spatial pattern of annual soil erosion rate was obtained by integrating geo-environmental variables in a raster based GIS method.GIS data layers including,rainfall erosivity（R）,soil erodability（K）,slope length and steepness（LS）,cover management （C） and conservation practice（P） factors were computed to determine their effects on average annual soil loss in the area.The resultant map of annual soil erosion shows a maximum soil loss of 17.73 t h^-1 y^-1 with a close relation to grass land areas,degraded forests and deciduous forests on the steep side-slopes（with high LS ）.The spatial erosion maps generated with RUSLE method and GIS can serve as effective inputs in deriving strategies for land planning and management in the environmentally sensitive mountainous areas.     

Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

A search for soft X-ray emission from stellar sources

With the soft X-ray detector (0.2–0.284 keV) aboard the Astronomical Netherlands Satellite (ANS) we have searched for X-ray emission from hot star coronae and peculiar stars. On Sirius ( CMa) and Capella ( Aur) X-ray emission has been measured at 6 and 5 level, respectively, above background. In all other cases the search revealed no evidence for soft X-ray emission. Upper limits to the luminosities of about 25 star coronae (main-sequence stars, (sub)giants, and supergiants) and of 4 peculiar stars ( Sco, Lyr, P Cyg, and Car) have been obtained.Paper presented at the COSPAR/IAU Symposium on Fast Transients in X-and Gamma-Rays, held at Varna, Bulgaria, 29–31 May, 1975.     

Geochemical characteristics of sphagnum brown coal — A possible oil-generating precursor

A preliminary study of newly discovered sphagnum brown coal from the Jingsuo Basin, Yunnan Province, China, which is quite rich in montan wax, indicates the predominance of highern-alkane homologues and aromatized triterpenoid components. Aromatic hydrocarbons are composed mainly of pentacyclic and tetracyclic di-, tri- and tetra-aromatic components, which are obviously diagenetically related to higher plant-derived triterpenoids naturally occurring in the biosphere. Because the sphagnum brown coal still remains in the highly immature stage, it seems that the progressive diagenetic aromatization of the higher plant-derived triterpenoids may start at a very early stage.     

Uranium (U) concentration and its genetic significance in the phosphorites of the Paleoproterozoic Bijawar Group of the Lalitpur district,Uttar Pradesh,India

The paper presents the uranium (U) concentration and distribution pattern in the Paleoproterozoic phosphorites of Lalitpur district of Uttar Pradesh. The study of thin sections, SEM and XRD reveal that apatite is the essential phosphate mineral while quartz and feldspars are the dominant gangue in the phosphorites of the investigated area. The collophane is observed to be mostly oolitic in form and microspherulitic in texture. The major element geochemistry indicated that the phosphorite samples are rich in P₂O₅, CaO, SiO₂ and Fe₂O₃ whereas depletion of MgO, MnO, K₂O and Al₂O₃ was observed. The CaO/P₂O₅ ratio ranges from 1.13 to 1.46 which is slightly lower than that of cations and anions substituted francolite (1.621) and close to that of carbonate-fluorapatite (1.318). The trace element geochemistry indicates that the phosphorites of Lalitpur have the significant range of U concentration (1.67 to 129.67 μg/g) which is more than that of Th (0.69 to 0.09 μg/g) among the analysed trace elements in the phosphorite samples of the area. The positive correlation of U with P₂O₅, CaO and U/P₂O₅ indicates a close association of U with phosphate minerals like collophane (apatite), whereas negative correlation of U with SiO₂ and Fe₂O₃ may be due to mutual replacement. The antipathetic relationship of U with Ni may be an indication of high oxidizing conditions, whereas sympathetic relationship of U with K₂O points towards higher alkaline conditions of the basin of deposition during phosphatization. The variable concentration of U and its relationship with significant major and trace elements in most of the phosphorite samples lead one to believe that the deposition of these phosphorites might have taken place in highly alkaline medium during fairly oxidizing to weakly reducing environmental conditions of geosynclinal basin.     

Investigation of Failure Mechanisms and Migration of Organic Chemicals at Wilsonville, Illinois

Ground water contamination was discovered in 1981 in a monitoring well at the Earthline disposal facility near Wilsonville, Illinois. Organic chemicals had migrated at a rate 100 to 1000 times greater than predicted when the site received its permit to operate in 1978. Postulated failure mechanisms included migration through previously unmapped permeable zones, subsidence of an underground mine, organic-chemical and clay-mineral interactions, acid-mine drainage and clay interactions, trench-cover settlement, and erosion.
In this investigation, the Illinois State Geological Survey found the primary reason for the rapid migration: the presence of previously undetermined fractures and joints in glacial till. The inaccurate predictions of hydraulic conductivity were based on laboratory-determined values that did not adequately measure the effects of fractures and joints on the transit time calculations. Field-measured hydraulic conductivity values were generally 10 to 1000 times greater than their laboratory-measured counterparts, thus largely accounting for the discrepancy between predicted and actual migration rates in the transit time calculations. The problem was compounded, however, by the burial of liquid wastes and by trench covers that allowed excess surface runoff to enter the trenches. Organic-chemical and clay-mineral interactions may also have exacerbated the problem in areas where liquid organic wastes were buried.     

Estimating climate changes in the northern hemisphere in the 21st century under alternative scenarios of anthropogenic forcing

Possible changes in the climate characteristics of the Northern Hemisphere in the 21st century are estimated using a climate model (developed at the Obukhov Institute of Atmospheric Physics (OIAP), Russian Academy of Sciences) under different scenarios of variations in the atmospheric contents of greenhouse gases and aerosols, including those formed at the OIAP on the basis of SRES emission scenarios (group I) and scenarios (group II) developed at the Moscow Power Engineering Institute (MPEI). Over the 21st century, the global annual mean warming at the surface amounts to 1.2?C2.6°C under scenarios I and 0.9?C1.2°C under scenarios II. For all scenarios II, starting from the 2060s, a decrease is observed in the rate of increase in the global mean annual near-surface air temperature. The spatial structures of variations in the mean annual near-surface air temperature in the 21st century, which have been obtained for both groups of scenarios (with smaller absolute values for scenarios II), are similar. Under scenarios I, within the extratropical latitudes, the mean annual surface air temperature increases by 3?C7°C in North America and by 3?C5°C in Eurasia in the 21st century. Under scenarios II, the near-surface air temperature increases by 2?C4°C in North America and by 2?C3°C in Eurasia. An increase in the total amount of precipitation by the end of the 21st century is noted for both groups of scenarios; the most significant increase in the precipitation rate is noted for the land of the Northern Hemisphere. By the late 21st century, the total area of the near-surface permafrost soils of the land of the Northern Hemisphere decreases to 3.9?C9.5 10⁶ km² for scenarios I and 9.7?C11.0 × 10⁶ km² for scenarios II. The decrease in the area of near-surface permafrost soils by 2091?C2100 (as compared to 2001?C2010) amounts to approximately 65% for scenarios I and 40% for scenarios II. By the end of the 21st century, in regions of eastern Siberia, in which near-surface permafrost soils are preserved, the characteristic depths of seasonal thawing amount to 0.5?C2.5 m for scenarios I and 1?C2 m for scenarios II. In western Siberia, the depth of seasonal thawing amounts to 1?C2 m under both scenarios I and II.