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951.
952.
The various assumptions implicit in the calculation of acid dissociation constants (based on ionic medium standard states) from potentiometric titrations using a cell with liquid junction (i.e. a pH measuring cell) have been examined. It was concluded that results can be obtained having an accuracy commensurate with the experimental precision. It has been shown that although the precise composition of the medium is a function of the hydrogen ion concentration (because of the protolytic nature of some of the ions in the media, e.g., sulphate and fluoride), the effect of such variations in the medium composition can be compensated for when defining the activity of hydrogen ion on an ionic medium standard state by defining the concentration of hydrogen ion as: where βHSO4 and βHF are the relevant association constants and ST and FT are the total concentrations of sulphate and fluoride, respectively.This approach was used to obtain values for the ionic product of water (KW) in artificial seawater media at various temperatures and ionic strengths. These were fitted to give the equation (molal concentration units): where I is the formal ionic strength of the artificial seawater medium and T is the absolute temperature. The values obtained are in reasonable agreement with those found by previous workers. 相似文献
953.
B.P. Mensink C.C. ten Hallers-Tjabbes J. Kralt I.L. Freriks J.P. Boon 《Marine environmental research》1996,41(4):315-325
Several cruises were carried out on the Eastern Scheldt between September 1992 and March 1995 to study the frequency and appearance of imposex in the common whelk, Buccinum undatum L. Incidences of imposex were always > 90%. For the first time several stages of imposex in Buccinum undatum are reported. The evolution of imposex in the whelk seems to follow a similar route as in Hinia reticulata belonging to the same superfamily (Buccinacea). Tissue organotin concentrations of animals collected in February 1995 showed the highest organotin concentrations in the digestive gland and lowest in the foot of the animals. Concentrations of phenyltin compounds (up to 625 ngSn/g DW) were much higher than those of butyltin compounds (up to 40 ngSn/g DW). 相似文献
954.
J.-G. Dessureault 《Ocean Engineering》1976,3(2):99-111
“Batfish” is a streamlined vehicle developed to house fast-responding oceanographic sensors. It is towed behind a ship or small vessel and its depth is controlled from the vessel by a manually or automatically produced command signal. Variable-angle wings permit the vehicle to be lowered and a novel control surface, which eliminates the need for heavy ballast, assures lateral stability. There are two models: the standard and the wide-wing Batfish. The standard Batfish has collected temperature and conductivity data at depths of up to 200 m when towed at 10–25 km/hr, and the wide-wing Batfish at depths to 400 m when towed at 10–16km/hr. 相似文献
955.
Measurements of underwater irradiance, transparency and Secchi disc depth were carried out in Liverpool Bay during 1974. The depth of the photic zone measured in the green portion of the spectrum ranged from 5 m to 50 m, depending on location and season. Inshore values of photic depth were smaller than those encountered offshore. By mid-summer the depth of the photic zone had reached or exceeded the depth of the sea bed over the whole study area.Consideration was given to the error terms associated with the optical measurements and to the problems of using standard optical relationships in coastal waters. The relationship between Secchi disc depth and the depth of the photic zone could not be taken as constant but was a function of the absorption and scattering properties of the water mass. 相似文献
956.
J. M. Auzende 《Marine Geophysical Researches》1971,1(2):162-177
Résumé Une série de profils de sismique réflexion effectués au large de la Tunisie et dans le détroit sardano-tunisien aboutissent à l'élaboration d'un schéma géologique interprétatif dans lequel nous replaçons le socle paléozoïque et sa couverture autochtone (Eocène et plio-quaternaire) et allochtone (nappe numidienne). Nous discutons ensuite des manifestations néotectoniques (bassins d'effondrements plio-quaternaires-mouvement de flexure-surrections locales-venues intrusives). Enfin la nature du substratum du détroit sardano-tunisien est discutée en liaison avec les hypothèses dynamiques et statiques relatives à la formation de la Méditerranée occidentale.
Serial seismic reflection profiles off Tunisia and between Sardinia and Tunisia are presented. Interpretation is given which includes paleozoïc basement and its autochtonous (Eocene and plioquaternary) and allochtonous (Numidian nappe) cover. Recent tectonic activity is discussed, (Plioquaternary foundered basins, flexure, local uplifts, intrusions). Then the nature of the basement of the Sardinia-Tunisia zone is discussed with respect to the various hypotheses on the region of the Western Mediterranean.相似文献
957.
958.
Experiments were conducted in an oscillatory water tunnel to investigate what effects temporal inertia has on the resistance of a granular medium. The flow law governing stationary porous media flow is reasonably well accepted and understood but the effects of unsteady flow have commonly been neglected. The present research was designed to assess the magnitude of the acceleration effects on media of uniformly packed spheres of equal diameter and on one sample of randomly placed stone.Oscillatory flow tests were made in a large oscillatory flume tunnel with periods varying from 3 to 12 seconds. The influence of properties of the medium (grain size and porosity) were tested by using spheres with two different diameters and packing each size sphere in different geometric arrangements. Tests made on a stone sample provided a qualitative assessment of the effects of more random material properties.For the experiments described in this paper, the Forchheimer unsteady-stationary flow law described the oscillatory measurements well when velocities and energy losses were maximum. Empirical coefficients determined from steady-stationary flow were generally found to apply to the unsteady flow, however some evidence of dependency on the period of oscillation was noted. 相似文献
959.
分析表观耗氧量、滴定碱度及总二氧化碳量等资料来研判红海及亚丁湾间之海水交换。结果显示,红海深层水的方解石及霰石饱和度均比亚丁湾和阿拉伯海深层水的饱和度高。红海全水柱之方解石和霰石都处於过饱和状态,亚丁湾和阿拉伯海中各深度之方解石亦呈过饱和状态,但霰石的饱和探度则大约在500m左右。分析深层水之生物体无机碳与有机碳的分解比值,可以发现此地区深层水中,大约有25%的总二氧化碳增加量是由无机碳酸钙溶解而来。 相似文献
960.
The results of research into the seasonal variability of hydrothermodynamic characteristics of the Black Sea are presented. These have been obtained using field data on the fields of temperature, salinity, and wind, and by mathematical modelling. The seasonal variability of the current and heat content fields and of the cold intermediate layer and other hydrophysical characteristics is discussed.Translated by Mikhail M. Trufanov. 相似文献