Aerosol characterization and optical thickness retrievalsusing GOME and METEOSAT satellite data

Summary ?Retrievals of atmospheric aerosol optical thickness are highly dependent on the choice of the class describing the aerosol properties leading to significant errors while using classes available in the literature. High spectral resolution measurements from GOME (Global Ozone Monitoring Experiment) between the ultraviolet and the near infrared can be used for an accurate characterization of the aerosol optical properties. The radiometer MVIRI (METEOSAT Visible and Infrared Imager) on board the geostationary satellite METEOSAT, while being equipped only with broadband VIS channel, ensures an adequate half-hourly monitoring of the atmospheric conditions over a large portion of the Earth. The present algorithm is based on a combination of data from both sensors for the retrieval of the aerosol optical thickness at the reference wavelength of 0.55 μm (AOT). A case of a desert dust outbreak from the African continent over the Atlantic Ocean is examined. AOT values obtained using a priori fixed classes taken from the literature are compared with those retrieved with this algorithm using the GOME-derived classes. Systematic differences of the order of a few tenths on average are found which remain significant also after considering the measurement errors. This represents a novelty introduced by the synergetic use of both sensors. Received March 13, 2002     

The Production of Methanol by Flowering Plants and the Global Cycle of Methanol

Methanol has been recognised as an important constituent of the background atmosphere, but little is known about its overall cycle in the biosphere/atmosphere system. A model is proposed for the production and emission to the atmosphere of methanol by flowering plants based on plant structure and metabolic properties, particularly the demethylation of pectin in the primary cell walls. This model provides a framework to extend seven sets of measurements of methanol emission rates to the global terrestrial biosphere. A global rate of release of methanol from plants to the atmosphere of 100 Tg y^–1 is calculated. A separate model of the global cycle of methanol is constructed involving emissions from plant growth and decay, atmospheric and oceanic chemical production, biomass burning and industrial production. Removal processes occur through hydroxyl radical attack in the atmosphere, in clouds and oceans, and wet and dry deposition. The model successfully reproduces the methanol concentrations in the continental boundary-layer and the free atmosphere, including the inter-hemispheric gradient in the free atmosphere. The model demonstrates a new concept in global biogeochemistry, the coupling of plant cell growth with the global atmospheric concentration of methanol. The model indicates that the ocean provides a storage reservoir capable of holding at least 66 times more methanol than the atmosphere. The ocean surface layer reservoir essentially buffers the atmospheric concentration of methanol, providing a physically based smoothing mechanism with a time constant of the order of one year.     

Particle size dependent response of aerosol counters

During an international workshop at the Institute for Experimental Physics of the University of Vienna, Austria, which was coordinated within the Committee on Nucleation and Atmospheric Aerosols (IAMAS-IUGG), 10 instruments for aerosol number concentration measurement were studied, covering a wide range of methods based on various different measuring principles. In order to investigate the detection limits of the instruments considered with respect to particle size, simultaneous number concentration measurements were performed for monodispersed aerosols with particle sizes ranging from 1.5 to 50 nm diameter and various compositions.The instruments considered show quite different response characteristics, apparently related to the different vapors used in the various counters to enlarge the particles to an optically detectable size. A strong dependence of the 50% cutoff diameter on the particle composition in correlation with the type of vapor used in the specific instrument was found. An enhanced detection efficiency for ultrafine hygroscopic sodium chloride aerosols was observed with water operated systems, an analogous trend was found for n-butanol operated systems with nonhygroscopic silver and tungsten oxide particles.     

Aerosol climatology for the planetary boundary layer derived from regular lidar measurements

Regular aerosol extinction and backscatter measurements using a UV Raman Lidar have been performed for almost 3 years in Hamburg in the frame of the German Lidar Network. A set of 92 aerosol extinction and 164 aerosol backscatter profiles has been used for statistical investigations. Mean values and variances of the aerosol extinction and backscatter in the boundary layer have been calculated. Large fluctuations during the whole year have been found. The measured aerosol extinction over Hamburg shows a seasonal cycle with highest values in early fall and a second less prominent peak in spring.An analysis of the data using back trajectories showed a dependence of the aerosol extinction on the origin of the air mass. The residence time of the air mass over industrialized areas was found to be an important parameter for the measured aerosol extinction at Hamburg. However, only a small part of the total variability could be explained by the air mass origin.For 75 cases of aerosol extinction measurements under cloud-free conditions, the aerosol backscatter profile and therefore, the lidar ratio as a function of altitude could be determined. Winter measurements of the lidar ratio are often close to model results for maritime aerosol, the summer measurements are close to the model results for urban or continental aerosols.The high quality of the data has been proven by intercomparisons with other lidar systems and with star photometer measurements of the aerosol optical depth during the Lindenberg Aerosol Characterization Experiment (LACE'98) field campaign.     

Elemental particle size distributions. Measured and estimated dry deposition in Sfax region (Tunisia)

Mass size distribution of the crustal elements (Al, Ca, Fe, Mg, Si, Ti), anthropogenic elements (Zn, Mn, Cr, Cu, K, P, Pb) and sea elements (Na, Cl) were obtained from measurements carried out with an inertial cascade impactor in Sfax. A fitting procedure by data inversion was applied to those data. This procedure yields accurate size distributions of aerosols in the diameter range 0.1–25 μm in two different sites. In a coastal industrial site, the mass distribution of the aerosol showed a bimodal structure; and in urban area, the lower particle mode cannot be observed. The elemental dry deposition flux was calculated as a function of particle size. The element flux size distribution increased rapidly with particle size. The modelling results indicate that the majority of the crustal and anthropogenic elements flux (>90%) was due to particles larger than 3 μm in diameter.     

Mobility of Phosphorus during the Weathering of Volcanic Ashes

Data are presented on phosphorus mobility during the weathering of rhyolite–dacite tephra of the modern and ancient eruptions. Distal tephra cannot be considered a phosphorus source, since phosphorous has low mobility during weathering both in subaerial and subaqueous sedimentation conditions. However, volcanic ashes exert a fertilization effect, providing the supply of nutrient elements into the ecosystem of internal basins and coastal zones.     

Chemical composition of stars in the galactic halo

The chemical compositions of the atmospheres of six metal-poor stars are analyzed. Spectra with signal-to-noise ratios of no less than 100 and a resolution of R≈17 000 were obtained using the 6-m telescope of the Special Astrophysical Observatory of the Russian Academy of Sciences. The abundances of Li, O, α-process elements (Mg, Si, Ca, Ti), Na, K, Sc, iron-peak elements (Cr, Mn, Fe, Ni, Cu, Zn), and s-process elements (Y, Ba) are derived. The star G251-54 ([Fe/H]=?1.55, T _eff=5541 K, logg=3.58) is deficient in some elements compared to both stars with similar metallicities and the Sun. The atmosphere of G251-54 has the following elemental abundances relative to iron: [O/Fe]=+0.47, [α/Fe]≈?0.3, [Na/Fe]=?0.60, [Sc/Fe]=?0.57, [Cr, Ni, Fe]≈0, [Zn/Fe]=+0.16, [Cu/Fe]=?0.66, [Y/Fe]=?0.70, and [Ba/Fe]=?1.35. The remaining five stars have metallicities in the range ?1.6<[Fe/H]相似文献   

Variability of the photospheric radiation of active K-M dwarfs and their X-ray luminosities

Variability of the photospheric radiation of 40 (dKe-dMe) dwarfs in the solar neighborhood due to variations in the spottedness of their surfaces is analyzed based on the behavior of their mean annual brightnesses over long time intervals. The amplitudes and characteristic time scales of the variations of the mean annual brightness are taken to be indicators of photospheric activity and were used to infer the levels of photospheric activity in the stars studied. The influence of axial rotation on the development of cyclic activity in young red dwarfs and F-M main-sequence stars is analyzed. The durations and amplitudes of the photospheric variability of rapidly rotating (dK0e-dK5e) stars testifies to a higher level of photospheric activity among red dwarfs and solar-type stars. The X-ray luminosities of these stars grow with the amplitude of the variations of the mean annual brightness. However, this is not typical of rapidly rotating M dwarfs, for which the X-ray emission varies by more than two orders of magnitude, although their degrees of spottedness are all virtually the same. A linear relationship between the X-ray and bolometric luminosities is observed for young (dKe-dMe) stars, with their ratios log(L _x/L _bol) being about ?3. These properties can be used to determine whether a red dwarf is a young star or is already on the main sequence.