Sources and sinks of sea salt in a newfoundland blanket bog

Over an oceanic peatland, the concentration of Na in fog averaged 38.1 mgl^?1 compared with 1.8 mgl^?1 in rain, resulting in a significant flux of mineral elements to the surface. Between 16 May and 20 June 1990 the average mass flux of Na to the bog surface by fog, rain, and dry deposition was 21.9, 10.4 and 7.0 mg m^?2 d^?1. There was little long-term storage of Na within the peatland system, where Na losses measured in stream runoff averaged 34.8 mg m² d^?1, and deep groundwater losses 4 mg m^?2 d^?1. Calcium and Mg were preferentially retained in the organic soil, whereas K was relatively mobile. Potassium tended to become concentrated in the unsaturated zone. Stream runoff had a consistently higher pH than groundwater, corresponding to higher Ca and Mg concentrations, which may have been from mineral sources in the headwater ponds. Otherwise, the stream water chemistry was closely related to groundwater in the upper layers of the peat deposit.     

Surface Photometry of Comet Hale-Bopp Carbon Images

A very long series of photographic observations of the comet Hale-Bopp has been made during January–April 1997 at the double astrograph (400/2000) of the Main Astronomical Observatory (Kyiv, Ukraine). Some of the cometary photos were obtained with two wide-band filter combinations. One of these combinations isolates C₂ emission, another — the nearby dust continuum. The images were digitized by means of AMDPH-XY machine and then calibrated following the standard procedure. After subtraction of the dust continuum the distribution of surface brightness in the C₂ emission coma of comet Hale-Bopp was studied. We found an asymmetric brightness distribution both pre- and post-perihelion. On 21.77 April 1997 a secondary brightness peak is found at the distance of 1.03 × 10⁵ km from the nucleus. It is possible that this peak is related to the extended source of the C₂ molecules. This revised version was published online in July 2006 with corrections to the Cover Date.     

Main stages of evolution of matter in the universe. I

The problem of the equation of state of cosmic matter is discussed and the constants of integration in the Friedmann solutions are determined. Translated from Astrofizika, Vol. 40, No. 1, pp. 117–124, January–March, 1997.     

Comparison of results from several AOGCMs for global and regional sea-level change 1900–2100

 Sea-level rise is an important aspect of climate change because of its impact on society and ecosystems. Here we present an intercomparison of results from ten coupled atmosphere-ocean general circulation models (AOGCMs) for sea-level changes simulated for the twentieth century and projected to occur during the twenty first century in experiments following scenario IS92a for greenhouse gases and sulphate aerosols. The model results suggest that the rate of sea-level rise due to thermal expansion of sea water has increased during the twentieth century, but the small set of tide gauges with long records might not be adequate to detect this acceleration. The rate of sea-level rise due to thermal expansion continues to increase throughout the twenty first century, and the projected total is consequently larger than in the twentieth century; for 1990–2090 it amounts to 0.20–0.37 m. This wide range results from systematic uncertainty in modelling of climate change and of heat uptake by the ocean. The AOGCMs agree that sea-level rise is expected to be geographically non-uniform, with some regions experiencing as much as twice the global average, and others practically zero, but they do not agree about the geographical pattern. The lack of agreement indicates that we cannot currently have confidence in projections of local sea-level changes, and reveals a need for detailed analysis and intercomparison in order to understand and reduce the disagreements. Received: 1 September 2000 / Accepted: 20 April 2001     

A new pattern for the north–south asymmetry of sunspots

We study the solar cycle evolution during the last 8 solar cycles using a vectorial sunspot area called the LA (longitudinal asymmetry) parameter. This is a useful measure of solar activity in which the stochastic, longitudinally evenly distributed sunspot activity is reduced and which therefore emphasizes the more systematic, longitudinally asymmetric sunspot activity. Interesting differences are found between the LA parameter and the more conventional sunspot activity indices like the (scalar) sunspot area and the sunspot number. E.g., cycle 19 is not the highest cycle according to LA. We have calculated the separate LA parameters for the northern and southern hemisphere and found a systematic dipolar-type oscillation in the dominating hemisphere during high solar activity times which is reproduced from cycle to cycle. We have analyzed this oscillation during cycles 16–22 by a superposed epoch method using the date of magnetic reversal in the southern hemisphere as the zero epoch time. According to our analysis, the oscillation starts by an excess of the northern LA value in the ascending phase of the solar cycle which lasts for about 2.3 years. Soon after the maximum northern dominance, the southern hemisphere starts dominating, reaching its minimum some 1.2–1.7 years later. The period of southern dominance lasts for about 1.6 years and ends, on an average, slightly before the end of magnetic reversal.     

Observational Selection of Comet Discoveries

The distribution of perihelion distances of nearly periodic comets was studied using different assumptions about comet discovery probabilities. It was shown that the concentration of perihelia at small heliocentric distances cannot be explained solely by the influence of visibility conditions.     

Grain boundary diffusion in enstatite

We have investigated grain boundary diffusion rates in enstatite by heating single crystals of quartz packed in powdered San Carlos olivine (Mg_0.90Fe_0.10)₂SiO₄ at controlled oxygen fugacities in the range 10^?5.7 to 10^?8.7?atm and temperatures from 1350° to 1450?°C for times from 5 to 100?h at 1?atm total pressure. Following the experiments, the thickness of the coherent polycrystalline reaction rim of pyroxene that had formed between the quartz and olivine was measured using backscatter scanning imaging in the electron microprobe. Quantitative microprobe analysis indicated that the composition of this reaction phase is (Mg_0.92Fe_0.08)₂Si₂O₆. The rate of growth of the pyroxene increases with increasing temperature, is independent of the oxygen fugacity, and is consistent with a parabolic rate law, indicating that the growth rate is controlled by ionic diffusion through the pyroxene rim. Microstructural observations and platinum marker experiments suggest that the reaction phase is formed at the olivine-pyroxene interface, and is therefore controlled by the diffusion of silicon and oxygen. The parabolic rate constants determined from the experiments were analyzed in terms of the oxide activity gradient across the rim to yield mean effective diffusivities for the rate-limiting ionic species, assuming bulk transport through the pyroxene layer. These effective diffusivities are faster than the lattice diffusivities for the slowest species (silicon) calculated from creep experiments, but slower than measured lattice diffusivities for oxygen in enstatite. Thus, silicon grain boundary diffusion is most likely to be the rate-limiting process in the growth of the pyroxene rims. Also, as oxygen transport through the pyroxene rims must be faster than silicon transport, diffusion of oxygen along the grain boundaries must be faster than through the lattice. The grain boundary diffusivity for silicon in orthopyroxenite is then given by D¯gbSiδ=(3.3±3.0)×10^?9f0.0O₂e^?400±65/RT?m³s^?1, where the activation energy for diffusion is in kJ/mol, and δ is the grain boundary width in m. Calculated growth rates for enstatite under these conditions are significantly slower than predicted by an extrapolation from similar experiments performed at 1000?°C under high pressure (hydrous) conditions by Yund and Tullis (1992), perhaps due to water-enhancement of diffusion in their experiments.