Kinetic studies of lead(II) uptake by the seagrass Zostera muelleri in water by radiotracing,atomic absorption spectrometry and electrochemical techniques

Evidence was found that uptake of lead from seawater in both model and natural systems by the leaves of the seagrass Zostera muelleri does occur for live, dead and scraped leaves at all the lead concentrations tested. Positive uptake of lead was measured using the three analytical techniques of radio-tracer, differential pulse anodic stripping voltammetry and atomic absorption spectrometry; similar uptake profiles were obtained for each technique. Profiles always showed an initial rapid uptake phase followed by a gradual transition to a plateau phase at which an approximate equilibrium between lead attached to seagrass and free ionic lead in seawater was reached. The presence of active lead uptake processes was indicated in experiments which attempted to remove lead from leaves by a chelating agent.     

Umbral Three-Minute Oscillations and Running Penumbral Waves

We present results of investigations into chromospheric velocity oscillations in sunspots, carried out at the Sayan Solar Observatory. It is shown that the “chevron” structures in the space-time diagrams demonstrate wavetrain properties. Such structures are indicators of a propagating wave process and they are typical of many sunspots. In the authors’ opinion, three-minute umbral oscillations are not the source of running penumbral waves (RPW). It is very likely that umbral oscillations and RPW initially propagate along different magnetic field lines. We explain the decrease in RPW propagation velocity and frequency in the outer penumbra, as compared with the inner, by the combined action of different frequency modes. To better reveal the properties of these modes, frequency filtering was used. Our measurements of the RPW (five-minute mode) wavelength and RPW propagation velocity in different sunspots vary from 12^″ to 30^″ and from 28 to 60 – 70 km s⁻¹ correspondingly.     

Petrology and origin of amoeboid olivine aggregates in CR chondrites

Abstract— Amoeboid olivine aggregates (AOAs) are irregularly shaped, fine‐grained aggregates of olivine and Ca, Al‐rich minerals and are important primitive components of CR chondrites. The AOAs in CR chondrites contain FeNi metal, and some AOAs contain Mn‐rich forsterite with up to 0.7 MnO and Mn:Fe ratios greater than one. Additionally, AOAs in the CR chondrites do not contain secondary phases (nepheline and fayalitic olivine) that are found in AOAs in some CV chondrites. The AOAs in CR chondrites record a complex petrogenetic history that included nebular gas‐solid condensation, reaction of minerals with the nebular gas, small degrees of melting, and sintering of the assemblage. A condensation origin for the Mn‐rich forsterite is proposed. The Mn‐rich forsterite found in IDPs, unequilibrated ordinary chondrite matrix, and AOAs in CR chondrites may have had a similar origin. A type A calcium, aluminum‐rich inclusion (CAI) with an AOA attached to its Wark‐Lovering rim is also described. This discovery reveals a temporal relationship between AOAs and type A inclusions. Additionally, a thin layer of forsterite is present as part of the Wark‐Lovering rim, revealing the crystallization of olivine at the end stages of Wark‐Lovering rim formation. The Ca, Al‐rich nodules in the AOAs may be petrogenetically related to the Ca, Al‐rich minerals in Wark‐Lovering rims on type A CAIs. AOAs are chondrite components that condensed during the final stage of Wark‐Lovering rim formation but, in general, were temporally, spatially, or kinetically isolated from reacting with the nebula vapor during condensation of the lower temperature minerals that were commonly present as chondrule precursors.     

Massless scalar field in Robertson-Walker space-time

Recently, exact spatially-homogeneous solutions have been found for a conformally invariant massless scalar fieldS(t) coupled to a Robertson-Walker geometry. We investigate extending these solutions to inhomogeneous scalar fieldsS(t, x ^l ). For an isotropic scalar fieldS(t, r) we find a solution satisfying three of the five field equations. If we use REDUCE, we show that the remaining equations forceS=S(t).     

Weathering process at the natural fission reactor of Bangombé

 The uranium deposits in the basin of Franceville (Gabon) host the only natural fission reactors known in the world. Unique geological conditions favoured a natural fission reaction 2 Ga ago. This was detected by anomalous isotopic compositions of uranium and rare earth elements (REE), which are produced by the fission reaction. In total, 16 reactor zones were found. Most of them are mined out. The reactor zone of Bangombé, is only 10–11 m below the surface. This site has been influenced by surface weathering processes. Six drill cores have been sampled at the site of the reactor zone of Bangombé during the course of the study and only one drill core (BAX 08) hit the core of the reactor. From these data and previous drilling campaigns, the reactor size is estimated to be 10 cm thick, 2–3 m wide and 4–6 m long. The migration of fission products can be traced by the anomalous isotope ratios of REE because of the fission process. The ¹⁴⁹Sm/¹⁴⁷Sm ratio close to the reactor zone is only 0.28 (normal: 0.92) because of the intense neutron capture of ¹⁴⁹Sm and subsequent transmutation, whereas ¹⁴⁷Sm is enriched by the fission reaction. Similar changes in isotopic patterns are detectable on other REE. The isotope ratios of Sm and Nd of whole rock and fracture samples surrounding the reactor indicate that fission-genic REE migrated only a few decimetres above and mainly below the reactor zone. Organic matter (bitumen) seems to act as a trap for fission-genic REE. Additional REE-patterns show less intense weathering with increasing depth in the log profile and support a simple weathering model. Received: 26 November 1999 · Accepted: 2 May 2000     

Relationships between Campi Flegrei and Mt. Somma volcanism: evidence from melt inclusions in clinopyroxene phenocrysts from volcanic breccia xenoliths

Summary We present compositions of reheated melt inclusions in clinopyroxene phenocrysts from three mafic xenoliths in Breccia Museo, Campi Flegrei, Italy. Melt inclusion compositions are remarkably different from the compositions of known contemporary Campi Flegrei lavas, being significantly enriched in K₂O and depleted in Na₂O. Some differences are also evident in FeO^* (total Fe as FeO) and TiO₂ contents. The clinopyroxene phenocrysts could not have crystallised from Campi Flegrei magmas. We suggest that they originated from a volcanic system genetically very similar to, and possibly linked with, the >14 ka volcanic system of Mt. Somma, another Campanian volcano ∼ 30 km east from Campi Flegrei, from which Vesuvius subsequently developed. This result indicates a close relationship (or link) between the two volcanic systems which have until now been considered separate. We speculate that the link was established prior to eruption of the Neapolitan Yellow Tuff (NYT) (∼ 12 ka). The xenoliths were derived from a volcanic system older than the host breccias themselves. We suggest that this older volcanism had close similarities with the volcanism of the older products of Mt. Somma (∼25 ka). Received March 20, 2000; accepted November 2, 2000     

Microboudin structures of piemontite along the Sambagawa metamorphic belt, Japan: implications for lateral variation of differential stress during regional metamorphism

Evidence is presented of a lateral variation in differential stress during metamorphism along a regional metamorphic belt on the basis of the proportion of microboudinaged piemontite grains (p) in a quartz matrix in metacherts. It is proposed that p is a practical indicator of relative differential stress. Analysis of 123 metacherts from the 800 km long Sambagawa metamorphic belt, Japan, reveals that p‐values range from < 0.01 to 0.7 in this region. Most samples from Wakayama in the mid‐belt area have p‐values of 0.4–0.6, whereas those from western Shikoku have p‐values of < 0.1. This difference cannot be explained by variations in metamorphic temperature, and is instead attributed to a regional, lateral variation in differential stress during metamorphism.