Radiation Products in Processed Ices Relevant to Edgeworth-Kuiper-Belt Objects

Near the inner edge of the Edgeworth-Kuiper Belt (EKB) are Pluto and Charon, which are known to have N₂- and H₂O-dominated surface ices, respectively. Such non-polar and polar ices, and perhaps mixtures of them, also may be present on other trans-Neptunian objects. Pluto, Charon, and all EKB objects reside in a weak, but constant UV-photon and energetic ion radiation environment that drives chemical reactions in their surface ices. Effects of photon and ion processing include changes in ice composition, volatility, spectra, and albedo, and these have been studied in a number of laboratories. This paper focuses on ice processing by ion irradiation and is aimed at understanding the volatiles, ions, and residues that may exist on outer solar system objects. We summarize radiation chemical products of N₂-rich and H₂O-rich ices containing CO or CH₄, including possible volatiles such as alcohols, acids, and bases. Less-volatile products that could accumulate on EKB objects are observed to form in the laboratory from acid-base reactions, reactions promoted by warming, or reactions due to radiation processing of a relatively pure ice (e.g., CO → C₃O₂). New IR spectra are reported for the 1–5 mu;m region, along with band strengths for the stronger features of carbon suboxide, carbonic acid, the ammonium and cyanate ions, polyoxymethylene, and ethylene glycol. These six materials are possible contributors to EKB surfaces, and will be of interest to observers and future missions.     

Observations of High Resolution Spectra of Comet Hale-Bopp (C/1995 O1) at the SAO of the RAS

We present the results of the preliminary study of the comet Hale-Bopp spectrum obtained April 17, 1997 by K. Churyumov and F. Mussayev with the help of the 1-meter Zeiss reflector and the echelle spectrometer (spectral resolutionλ/Δ λ ≈ 50000), CCD and the long slit, oriented along the radius-vector(“Sun-comet direction”). Energy distributions for three selected regions including the C₃, C₂ (0-0) and CN(Δ ν = 0) molecules emissions of the comet Hale-Bopp spectrum were built. The rotational lines of the CN(Δ ν = 0) band were identified. The nature of the high emission peak near λ 4020 Å in the C₃ band is discussed. The presence of the cometary continuum of the nonsolar origin is assumed.     

A possible presence of HeH+ in white dwarfs

The equivalent width calculations for the fundamental vibration rotation band lines of HeH⁺ have been carried out for a non-DA white dwarf model with an effective temperature of 12 000 K. BothP andR branch lines with rotational quantum numbersJ=3 to 18 were included in the calculations. A search for these lines in helium rich white dwarfs is suggested.     

Die Entfernung von Cadmiumionen aus Spülwässern der galvanischen Industrie mittels Ionenaustausch

In laboratory investigations with model waters, the behaviour of selected cation-exchange resins (Amberlite 200 C, Duolite C-25, Lewatit S-100, Wofatit KPS and Wofatit KS-10) is tested. The usable volume capacity of the resins in the forms of H, Na and NH₄ as well as the water content and the total volume capacity after 25 cycles of loading/regeneration are determined. It is recommended to use Amberlite 200 C and Wofatit KS-10.     

Low-frequency electric field fluctuations excited by ring current protons

Energetic protons haying ring type distributions are shown to generate low-frequency electrostatic waves, propagating nearly transverse to the geomagnetic field lines, in the ring current region by exciting Mode 1 arid Mode 2 nonresonant instabilities and a resonant instability. Mode 1 nonresonant instability has frequencies around ~4 Hz with transverse wavelengths of ~(8–80) km, and it is likely to occur in the region L = (7–8). Mode 2 nonresonant instability can generate frequencies ~(850–1450) Hz with transverse wavelengths ~(2–20) km. The typical frequencies and transverse wavelengths associated with the resonant instability are (950–1250) Hz and (30–65) km. Both the Mode 2 nonresonant instability and the resonant instability can occur in the ring current region with L = (4–6). The low-frequency modes driven by energetic protons could attain maximum saturation electric field amplitude varying from 0.8 mV/m to 70 mV/m. It is suggested that the turbulence produced by the low-frequency modes may cause pitch angle scattering of ring current protons in the region outside the plasmapause resulting in the ring current decay.