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641.
A. E. Gledzer E. B. Gledzer F. V. Dolzhanskii V. M. Ponomarev 《Izvestiya Atmospheric and Oceanic Physics》2006,42(4):399-422
This paper analyzes the properties of solutions to the equations describing the motion of a stratified fluid in the class of velocity and temperature fields linear in coordinates. For an ideal fluid, these equations, on the one hand, are exact for the corresponding hydrodynamic problem and, on the other hand, are identical to the equations of motion for a heavy top. In a conservative case, the equations of motion of a top share common solutions with the equations of geophysical fluid dynamics and reproduce motions similar to those existing in the theory of the large-scale atmospheric circulation. This study considers the effects of viscosity and heat conduction in the fluid, which are, in a sense, similar to the effect of friction in the case of a top. The influence of deflections of the vectors of gravity and external rotation from their standard directions for a plane-parallel atmosphere is also considered. The regimes of motions that are described by the starting equations and approximations commonly used to model the atmospheric general circulation (the quasi-geostrophic approximation) are analyzed. It is shown that these equations correctly describe the Hadley and Rossby circulation regimes and transitions between them that are observed in numerical and laboratory experiments. Particular attention is given to the consistency between different regimes of the exact equations and their quasi-geostrophic approximations, which is manifested for small Rossby numbers and is generally absent for large Rossby numbers. The asymptotic behaviors of the curves of transition between the Hadley and Rossby regimes under the conditions of breaking the external symmetry of flows are obtained. These asymptotics explain the corresponding transition boundaries for the regimes observed in the known experiments in annuluses. 相似文献
642.
A method is proposed to study the transport of a passive additive in the atmospheric surface layer with the use of the atmospheric transfer function. This method makes it possible to estimate the spatial distribution of the concentration of a passive additive in the atmospheric surface layer from the additive’s surface source without experimentally determining the vertical profile of the transport coefficient or without resorting to various hypotheses for the character of its behavior. The transfer function, which contains the information on the wind-field structure, can be obtained from simple one-point measurements of surface-and air-temperature fluctuations and from subsequent spectral processing of the data. The effects of the wind-velocity profile and turbulence on the spatial distribution of additive concentration are assessed. This method allows one to simplify experiments during development and verification of the models of atmospheric diffusion. This method may also be useful in emergency situations to predict the propagation of hazardous additives. 相似文献
643.
The dependence of the variation in the depth of the upper mixed layer (MLD) on the governing parameters (the momentum flux, the buoyancy fluxes at the ocean surface, and the density gradient in the pycnocline) is considered. It is shown that, in the spring storm season, wind mixing dominates over convective mixing. In this case, the MLD is linearly correlated with the Ekman scale calculated from the friction velocity observed approximately 12 h before the measurement of the MLD. 相似文献
644.
I. Brandariz P. Castro M. Montes F. Penedo M.E. Sastre de Vicente 《Marine Chemistry》2006,102(3-4):291-299
Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl2 or CaCl2), with binary mixtures of MgCl2 and CaCl2, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl2, while it is increased by the other electrolytes used in this work. 相似文献
645.
We present the results of numerical experiments aimed at the simulation of the circulation of waters and transport of impurities
in the Balaklava Bay for typical wind conditions established on the basis of the analysis of the data of in-situ measurements. The currents are computed by using the nonlinear σ-coordinate model. The specific features of the integral
circulation and three-dimensional structure of the current field are investigated. The statistical characteristics of currents
are estimated on the basis of the in-situ data on winds and model calculations. Possible scenarios of propagation of impurities from the coastal sources are analyzed
for various hydrodynamic conditions. It is shown that the localized eddy structures in the current fields (in combination
with the zones of intense vertical motion) can result in a complex character of the transport of substances in the bay and
lead to the formation of local regions of maximum concentrations of impurities on the boundary of the north and central parts
of the bay.
__________
Translated from Morskoi Gidrofizicheskii Zhurnal, No. 4, pp. 43–58, July–August, 2005. 相似文献
646.
647.
This issue marks a change in the editorial team of the ICESJournal of Marine Science, in that we have bid farewell to ourformer Editor-in-Chief, Niels Daan, after six years of sterlingservice, and to our Elsevier Publishing Editor, Andrew Richford,after an even longer period of years. Both deserve credit fortheir energy and vision that has left us the legacy of a journalas widely read and cited as the ICES Journal now is, but theyleave a gap that will be a huge challenge for us to meet. However,in my new capacity as Editor-in-Chief and in Els Bosma's capacityas Elsevier's Publishing Editor, I 相似文献
648.
Ivanov V. A. Kubryakov A. I. Lyubartseva S. P. Mikhailova É. N. Shapiro N. B. 《Physical Oceanography》2004,14(2):67-83
In the present work, we generalize the results of our investigations in the field of simulation of hydrophysical and ecological processes in coastal regions of various seas and some closed basins. The developed and applied mathematical models and the results of numerical experiments are briefly analyzed. 相似文献
649.
Elizabeth B. Kujawinski Rossana Del Vecchio Neil V. Blough Geoffrey C. Klein Alan G. Marshall 《Marine Chemistry》2004,92(1-4):23
Molecular-level characterization of natural organic matter (NOM) has been elusive due to the inherent complexity of natural organic mixtures and to the fact that individual components are often polar and macromolecular. Electrospray ionization (ESI) is a “soft” ionization technique that ionizes polar compounds from aqueous solution prior to injection into a mass spectrometer. The highest resolution and mass accuracy of compounds within NOM have been achieved when ESI is combined with an ultrahigh-resolution mass spectrometer such as the Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS). With this technique, individual molecules within a variety of natural organic mixtures can be detected and their elemental composition can be determined. At low mass-to-charge (m/z) ratio, the resolution is high enough to assign exact molecular formulas allowing specific components of these mixtures to be identified. In addition to molecular identification, we can now use ESI FT-ICR MS to examine molecular-level changes in different organic mixtures as a function of relevant geo-processes, such as microbial alterations and photochemistry. Here we present the results from the application of ESI FT-ICR MS to two geochemical questions: (1) the effect of photoirradiation on the molecular composition of fulvic acids and (2) the role of protozoan grazers in the modification of DOM in aquatic systems. 相似文献
650.
There is a growing body of evidence to suggest that certain polycyclic aromatic hydrocarbons (PAHs) pose a greater hazard to aquatic organisms than previously demonstrated, due to their potential to cause photo-induced toxicity when exposed to ultraviolet (UV) radiation. The consequences of photo-induced toxicity are reported here for embryo-larval stages of the pacific oyster Crassostrea gigas, following exposure to pyrene and benzo[a]pyrene. During laboratory investigations, significant increases in toxicity were observed in the presence of environmentally attainable levels of UV-radiation, compared with embryos exposed to PAH alone, at levels previously deemed to have little acute biological effect. The phototoxicity of pyrene and benzo[a]pyrene completely inhibited the development to the D-shell larval stage when embryos were simultaneously exposed to 5 microg l(-1) PAH and ultraviolet light (UVB = 6.3 +/- 0.1 microW/cm2 and UVA = 456.2 +/- 55 microW/cm2). A linear relationship was also demonstrated for benzo[a]pyrene phototoxicity with decreasing UV light intensity. 相似文献