Silica phase transformations in the petroliferous sequences

The joint evolution of organic matter and silica in petroliferous sequences is considered in the terms of the laws of transformation of dispersion systems. The dispersion systems are transformed under conditions of low-temperature solid-phase processes accompanied by the silica phase transition and dehydration that favors the evolution of organic matter.     

Temporal characteristics of aerosol physical properties at Visakhapatnam on the east coast of India during ICARB — Signatures of transport onto Bay of Bengal

Realizing the importance of aerosol physical properties at the adjoining continental and coastal locations in the airmass pathways onto the oceanic region, extensive measurements of aerosol physical properties were made at Visakhapatnam (17.7°N, 83.3°E), an eastern coastal location in peninsular India during the ICARB period. The temporal variations of aerosol optical depth, near surface aerosol mass size distributions and BC mass concentrations show significantly higher aerosol optical depth and near surface mass concentrations during the first and last weeks of April 2007. The mean BC mass fraction in the fine mode aerosol was around 11%. The aerosol back scatter profiles derived from Micro Pulse Lidar indicate a clear airmass subsidence on the days with higher aerosol optical depths and near surface mass fraction. A comparison of the temporal variation of the aerosol properties at Visakhapatnam with the MODIS derived aerosol optical depth along the cruise locations indicates a resemblance in the temporal variation suggesting that the aerosol transport from the eastern coastal regions of peninsular India could significantly affect the aerosol optical properties at the near coastal oceanic regions and that the affect significantly reduced at the farther regions.     

Characteristics of spectral aerosol optical depths over India during ICARB

Spectral aerosol optical depth (AOD) measurements, carried out regularly from a network of observatories spread over the Indian mainland and adjoining islands in the Bay of Bengal and Arabian Sea, are used to examine the spatio-temporal and spectral variations during the period of ICARB (March to May 2006). The AODs and the derived Ångström parameters showed considerable variations across India during the above period. While at the southern peninsular stations the AODs decreased towards May after a peak in April, in the north Indian regions they increased continuously from March to May. The Ångström coefficients suggested enhanced coarse mode loading in the north Indian regions, compared to southern India. Nevertheless, as months progressed from March to May, the dominance of coarse mode aerosols increased in the columnar aerosol size spectrum over the entire Indian mainland, maintaining the regional distinctiveness. Compared to the above, the island stations showed considerably low AODs, so too the northeastern station Dibrugarh, indicating the prevalence of cleaner environment. Long-range transport of aerosols from tshe adjoining regions leads to remarkable changes in the magnitude of the AODs and their wavelength dependencies during March to May. HYSPLIT back-trajectory analysis shows that enhanced long-range transport of aerosols, particularly from the west Asia and northwest coastal India, contributed significantly to the enhancement of AOD and in the flattening of the spectra over entire regions; if it is the peninsular regions and the island Minicoy are more impacted in April, the north Indian regions including the Indo Gangetic Plain get affected the most during May, with the AODs soaring as high as 1.0 at 500 nm. Over the islands, the Ångström exponent (α) remained significantly lower (～1) over the Arabian Sea compared to Bay of Bengal (BoB) (～1.4) as revealed by the data respectively from Minicoy and Port Blair. Occurrences of higher values of α, showing dominance of accumulation mode aerosols, over BoB are associated well with the advection, above the boundary layer, of fine particles from the east Asian region during March and April. The change in the airmass to marine in May results in a rapid decrease in α over the BoB.     

Integrated approach for identification of potential groundwater zones in Seethanagaram Mandal of Vizianagaram District,Andhra Pradesh,India

Identifying a good site for groundwater exploration in hard rock terrain is a challenging task. In hard rocks, groundwater occurs in secondary porosity developed due to weathering, fracturing, faulting, etc., which is highly variable within short distance and contributing to near-surface inhomogeneity. In such situations topographic, hydrogeological and geomorphological features provide useful clues for the selection of suitable sites. Initially, based on satellite imagery, topographical, geomorphological and hydrogeological features, an area of about 149 km² was demarcated as a promising zone for groundwater exploration in the hard rock tract of Seethanagaram Mandal, Vizianagaram District, Andhra Pradesh, India. A total of 50 Vertical Electrical Soundings (VES) were carried out using Wenner electrode configuration. An interactive interpretation of the VES data sharpened the information inferred from geomorphological and hydrogeological reconnaissance. Ten sites were recommended for drilling. Drilling with Down-The-Hole Hammer (DTH) was carried out at the recommended sites down to 50 to 70 m depths. The interpreted VES results matched well with the drilled bore well lithologs. The yields of bore wells vary from 900 to 9000 liters per hour (lph).     

Gouging abrasion test for rock abrasiveness testing

Wear parts of many mineral processing and mining equipment are often subjected to high stress loads applied at high speeds and at varying angles of incidence, where the prevalent mode of wear is high-stress gouging/sliding impact abrasion. Examples include crusher liners, wear liners in hoppers and chutes, picks on roadheaders, discs on tunnel boring machines and ground engaging tools. Abrasion under these conditions is characterised by a high material removal rate and thus has a direct bearing on wear rates and service life of the equipment concerned. However, at present there appears to be no method for rock abrasiveness assessment under these conditions. This paper describes a new Gouging Abrasion method and apparatus for testing abrasivity of rocks under high-stress gouging/sliding impact wear. A Gouging Abrasion Index (Gi) is introduced, which can be used for prediction and assessment of component life expectancy and efficiency of mineral processing and materials handling equipment. Experimental data from Gouging Abrasion testing of numerous Australian rock types are presented. It is suggested that the results of Gi testing can be used for wear rate predictions for a variety of mineral processing and materials handling equipment working under high-stress gouging/sliding impact abrasion conditions.     

SHRIMP zircon dating and Sm/Nd isotopic investigations of Neoproterozoic granitoids, Eastern Desert, Egypt

There is an increasing evidence for the involvement of pre-Neoproterozoic zircons in the Arabian–Nubian Shield, a Neoproterozoic crustal tract that is generally regarded to be juvenile. The source and significance of these xenocrystic zircons are not clear. In an effort to better understand this problem, older and younger granitoids from the Egyptian basement complex were analyzed for chemical composition, SHRIMP U–Pb zircon ages, and Sm–Nd isotopic compositions. Geochemically, the older granitoids are metaluminous and exhibit characteristics of I-type granites and most likely formed in a convergent margin (arc) tectonic environment. On the other hand, the younger granites are peraluminous and exhibit the characteristics of A-type granites; these are post-collisional granites. The U–Pb SHRIMP dating of zircons revealed the ages of magmatic crystallization as well as the presence of slightly older, presumably inherited zircon grains. The age determined for the older granodiorite is 652.5 ± 2.6 Ma, whereas the younger granitoids are 595–605 Ma. Xenocrystic zircons are found in most of the younger granitoid samples; the xenocrystic grains are all Neoproterozoic, but fall into three age ranges that correspond to the ages of other Eastern Desert igneous rocks, viz. 710–690, 675–650 and 635–610 Ma. The analyzed granitoids have (+3.8 to +6.5) and crystallization ages, which confirm previous indications that the Arabian–Nubian Shield is juvenile Neoproterozoic crust. These results nevertheless indicate that older Neoproterozoic crust contributed to the formation of especially the younger granite magmas.     

Extensional tectonic origin of gneissosity and related structures of the Feiran–Solaf metamorphic belt, Sinai, Egypt

The Feiran–Solaf metamorphic belt consists of low-P high-T amphibolite facies, partly migmatized gneisses, schists, amphibolites and minor calc-silicate rocks of metasedimentary origin. There are also thick concordant synkinematic sheets of diorite, tonalite and granodiorite orthogneiss and foliated granite and pegmatite dykelets. The gneissosity (or schistosity) is referred to as S₁, and is almost everywhere parallel to lithological layering, S₀. This parallelism is not due to transposition. The gneissosity formed during an extensional tectonic event (termed D1), before folding of S₀. S₁ formed by coaxial pure shear flattening strain (Z normal to S₀, i.e. vertical; with X and Y both extensional and lying in S₁). This strain also produced chocolate tablet boudinage of some layers and S₁-concordant sills and veins. S₁ has a strong stretching lineation L₁ with rodding characteristics. Within-plane plastic anisotropy (lower ductility along Y compared to along X) resulted in L₁-parallel extensional ductile shears and melt filled cracks. Continued shortening of these veins, and back-rotation of foliations on the shears produced intrafolial F₁ folds with hinges parallel to the stretching lineation. F₁ fold asymmetry variations do not support previous models involving macroscopic F₁ folds or syn-gneissosity compressional tectonics. The sedimentary protoliths of the Feiran–Solaf gneisses were probably deposited in a pre-800 Ma actively extending intracratonic rift characterizing an early stage of the break-up of Rodinia.     

Paleomagnetism and Detrital Zircon Geochronology of the Upper Vindhyan Sequence, Son Valley and Rajasthan, India: A ca. 1000 Ma Closure age for the Purana Basins?

The utility of paleomagnetic data gleaned from the Bhander and Rewa Groups of the “Purana-aged” Vindhyanchal Basin has been hampered by the poor age control associated with these units. Ages assigned to the Upper Vindhyan sequence range from Cambrian to the Mesoproterozoic and are derived from a variety of sources, including ⁸⁷Sr/⁸⁶Sr and δ ¹³C correlations with the global curves and Ediacara-like fossil finds in the Lakheri–Bhander limestone. New analyses of the available paleomagnetic data collected from this study and previous work on the 1073 Ma Majhgawan kimberlite, as well as detrital zircon geochronology of the Upper Bhander sandstone and sandstones from the Marwar SuperGroup suggest that the Upper Vindhyan sequence may be up to 500 Ma older than is commonly thought. Paleomagnetic analysis generated from the Bhander and Rewa Groups yields a paleomagnetic pole at 44°N, 214.0°E (A95 = 4.3°). This paleomagnetic pole closely resembles the VGP from the well-dated Majhgawan intrusion (36.8°N, 212.5°E, α₉₅ = 15.3°).Detrital zircon analysis of the Upper Bhander sandstone identifies a youngest age population at 1020 Ma. A comparison between the previously correlated Upper Bhander sandstone and the Marwar sandstone detrital suites shows virtually no similarities in the youngest detrital suite sampled. The main 840–920 Ma peak is absent in the Upper Bhander. This supports our assertion that the Upper Bhander is older than the 750–771 Ma Malani sequence, and is likely close to the age of the 1073 Ma Majhgawan kimberlite on the basis of the paleomagnetic similarities. By setting the age of the Upper Vindhyan at 1000–1070 Ma, several intriguing possibilities arise. The Bhander–Rewa paleomagnetic pole allows for a reconstruction of India at 1000–1070 Ma that overlaps with the 1073 ± 13.7 Majhgawan kimberlite VGP. Comparisons between the composite Upper Vindhyan pole (43.9°N, 210.2°E, α₉₅ = 12.2°) and the Australian 1071 ± 8 Ma Bangamall Basin sills and the 1070 Ma Alcurra dykes suggest that Australia and India were not adjacent at this time period.