Mud Volcanoes, Their Distribution Regularities and Genesis: Communication 1. Mud Volcanic Provinces and Morphology of Mud Volcanoes

The article discusses regularities in the distribution of mud volcanoes and characterizes most important mud volcanic provinces of the world. A new morphogenetic classification of mud volcanoes substantiated by results of their study in the Crimean–Caucasian and West Turkmenian regions is proposed.     

Facies analysis of the Trypali carbonate unit (Upper Triassic) in central-western Crete (Greece): an evaporite formation transformed into solution-collapse breccias

The Trypali carbonate unit (Upper Triassic), which crops out mainly in central‐western Crete, occurs between the parautochthonous series (Plattenkalk or Talea Ori‐Ida series, e.g. metamorphic Ionian series) and the Tripolis nappe (comprising the Tripolis carbonate series and including a basal Phyllite–Quartzite unit). It consists of interbedded dolomitic layers, represented principally by algally laminated peloidal mudstones, foraminiferal, peloidal and ooidal grainstones, as well as by fine‐grained detrital carbonate layers, in which coarse baroque dolomite crystals and dolomite nodules are dispersed. Baroque dolomite is present as pseudomorphs after evaporite crystals (nodules and rosettes), which grew penecontemporaneously by displacement and/or replacement of the host sediments (sabkha diagenesis). However, portions of the evaporites show evidence of resedimentation. Pre‐existing evaporites predominantly consisted of skeletal halite crystals that formed from fragmentation of pyramidal‐shaped hoppers, as well as of anhydrite nodules and rosettes (salt crusts). All microfacies are characteristic of peritidal depositional environments, such as sabkhas, tidal flats, shallow hypersaline lagoons, tidal bars and/or tidal channels. Along most horizons, the Trypali unit is strongly brecciated. These breccias are of solution‐collapse origin, forming after the removal of evaporite beds. Evaporite‐related diagenetic fabrics show that there was extensive dissolution and replacement of pre‐existing evaporites, which resulted in solution‐collapse of the carbonate beds. Evaporite replacement fabrics, including calcitized and silicified evaporite crystals, are present in cements in the carbonate breccias. Brecciation was a multistage process; it started in the Triassic, but was most active in the Tertiary, in association with uplift and ground‐water flow (telogenetic alteration). During late diagenesis, in zones of intense evaporite leaching and brecciation, solution‐collapse breccias were transformed to rauhwackes. The Trypali carbonate breccias (Trypali unit) are lithologically and texturally similar to the Triassic solution‐collapse breccias of the Ionian zone (continental Greece). The evaporites probably represent a major diapiric injection along the base of the parautochthonous series (metamorphic Ionian series) and also along the overthrust surface separating the parautochthonous series from the Tripolis nappe (Phyllite–Quartzite and Tripolis series). The injected evaporites were subsequently transformed into solution‐collapse breccias.     

Quantitative analysis of variations in depositional sequence thickness from submarine channel levees

Abstract Thickness variations across‐levee and downchannel in acoustically defined depositional sequences from six submarine channel‐levee systems show consistent and quantifiable patterns. The thickness of depositional sequences perpendicular to the channel trend, i.e. across the levee, decreases exponentially, as characterized by a spatial decay constant, k. Similarly, the thickness of sediment at the levee crest decreases exponentially down the upper reaches of submarine channels and can be characterized by a second spatial decay constant, λ. The inverse of these decay constants has units of length and defines depositional length scales such that k^?1 is a measure of levee width and λ^?1 is a measure of levee length. Quantification of levee architecture in this way allowed investigation of relationships between levee architecture and channel dimensions. It was found that these measures of levee e‐folding width and levee e‐folding length are directly related to channel width and relief. The dimensions of channels and levees are thus intimately related, thereby limiting the range of potential channel‐levee morphologies, regardless of allocyclic forcing. A simple sediment budget model relates the product of the levee e‐folding width and e‐folding length to through‐channel volume discharge. A classification system based on the quantitative downchannel behaviour of levee architecture allows identification of a ‘mid‐channel’ reach, where sediment is passively transferred from the through‐channel flow to the levees as an overspilling flow. Downstream from this reach, the channel gradually looses its control on guiding turbidity currents, and the resulting flow can be considered as an unconfined or spreading flow.     

Evidence for compressionally induced high subsidence rates in the Kurile Basin (Okhotsk Sea)

A combined volcanological, geochemical, paleo-oceanological, geochronological and geophysical study was undertaken on the Kurile Basin, in order to constrain the origin and evolution of this basin. Very high rates of subsidence were determined for the northeastern floor and margin of the Kurile Basin. Dredged volcanic samples from the Geophysicist Seamount, which were formed under subaerial or shallow water conditions but are presently located at depths in excess of 2300 m, were dated at 0.84±0.06 and 1.07±0.04 Ma with the laser ⁴⁰Ar/³⁹Ar single crystal method, yielding a minimum average subsidence rate of 1.6 mm/year for the northeast basin floor in the Quaternary. Trace element and Sr–Nd–Pb isotope data from the volcanic rocks show evidence for contamination within lower continental crust and/or the subcontinental lithospheric mantle, indicating that the basement presently at 6-km depth is likely to represent thinned continental crust. Average subsidence rates of 0.5–2.0 mm/year were estimated for the northeastern slope of the Kurile Basin during the Pliocene and Quaternary through the determination of the age and paleo-environment (depth) of formation of sediments from a canyon wall. Taken together, the data from the northeastern part of the Kurile Basin indicate that subsidence began in or prior to the Early Pliocene and that subsidence rates have increased in the Quaternary. Similar rates of subsidence have been obtained from published studies on the Sakhalin Shelf and Slope and from volcanoes in the rear of the Kurile Arc. The recent stress field of the Kurile Basin is inferred from the analysis of seismic activity, focal mechanism solutions and from the structure of the sedimentary cover and of the Alaid back-arc volcano. Integration of these results suggests that compression is responsible for the rapid subsidence of the Kurile Basin and that subsidence may be an important step in the transition from basin formation to its destruction. The compression of the Kurile Basin results from squeezing of the Okhotsk Plate between four major plates: the Pacific, North American, Eurasian and Amur. We predict that continued compression could lead to subduction of the Kurile Basin floor beneath Hokkaido and the Kurile Arc in the future and thus to basin closure.     

Basement-controlled faulting of Paleozoic strata in southern Ontario, Canada: new evidence from geophysical lineament mapping

Basement fault reactivation is now recognized as an important control on sedimentation and fault propagation in intracratonic basins. In southern Ontario, the basement consists of complexly structured mid-Proterozoic (ca. 1.2 Ga) crystalline rocks and metasedimentary rocks that are overlain by up to 1500 m of Paleozoic sedimentary strata. Reactivation of basement structures is suspected to control the location of Paleozoic fault and fracture systems, but evaluation has been hindered by a limited understanding of the regional structural characteristics of the buried basement. New aeromagnetic- and gravimetric-lineament mapping presented in this paper better resolves the location of basement discontinuities and provides further evidence for basement controls on the distribution of Paleozoic fault and fracture systems. Lineament mapping was facilitated by reprocessing and digital image enhancement (micro-levelling, regional residual separation, derivative filtering) of existing regional gravity and aeromagnetic datasets. Reprocessed images identify new details of the structural fabric of the basement below southern Ontario and delineate several previously unrecognized aeromagnetic and gravity lineaments and linear zones. Linear zones parallel the projected trends of mid-Proterozoic terrane boundaries identified by field mapping on the exposed shield to the north of the study area, and are interpreted as zones of shearing and basement faulting. Mapped aeromagnetic and gravity lineaments show similar trends to Paleozoic faults and fracture networks and broad zones of seismicity in southern Ontario. These new data support an ‘inheritance model’ for Paleozoic faulting, involving repeated reactivation and upward propagation of basement faults and fractures into overlying cover strata.     

Some results obtained on the study of the chemical composition of Eurasian oils depending on the depth and age of the reservoir rock

The sulfur, paraffin, resin and asphaltene contents of some 6570 Cenozoic, Mesozoic and Paleozoic Eurasian oils were analysed statistically in terms of reservoir age and depth. The database includes all principal oil-bearing basins from 60 Eurasian countries. The results of the studies of the relationships between the distribution of oils with different sulfur, paraffin, resin and asphaltene contents and the reservoir age and depth are presented. Predictive trends are established allowing polynomial predictions of average properties.     

Geochronological constraints on the evolution of the Embu Complex, São Paulo, Brazil

Petrologic and geochronological work was carried out on a roadside outcrop of amphibolite facies orthogneisses near São Lourenço da Serra, about 50 km southwest of São Paulo City. These orthogneisses belong to the Embu Complex, within the Neoproterozoic Brasiliano Orogenic Cycle mobile belts of SE Brazil. The outcrop consists of predominantly foliated biotite tonalites and granodiorites, which were cut by granitic veins and pegmatites prior to final deformation. SHRIMP U/Pb measurements on zircons from one granodioritic–tonalitic gneiss indicate magmatic crystallization of the protolith at 811±13 Ma (MSWD=1.0). Zircons with dates of ca. 2000 and ca. 1000 Ma in this rock are interpreted as inherited from older crust. One zircon analyzed from the gneiss and three zircons from a discordant pegmatitic vein indicate an event at 650–700 Ma, perhaps related to the intrusion of the pegmatites. A regression of Rb–Sr whole rock data for four biotite gneisses yielded an imperfect isochron, giving an apparent age of 821±68 Ma and an elevated initial ⁸⁷Sr/⁸⁶Sr ratio of 0.719±0.005. The elevated initial ⁸⁷Sr/⁸⁶Sr ratio and the inherited zircons indicate involvement of older crust in the genesis of the gneisses. Rb–Sr feldspar and whole rock pairs yield ca. 560 Ma tielines, giving the time of final cooling below 300–350 °C, and the cessation of medium-grade metamorphism and ductile deformation. These results document a series of tectono-thermal events spanning 250 million years during the Brasiliano Orogenic Cycle. They relate to ca. 800 Ma magmatic arc activity and later allochthonous terrane assembly during closure of the Adamastor Ocean, resulting in the accretion of Western Gondwana.     

Late Quaternary Spring-Fed Deposits of the Grand Canyon and Their Implication for Deep Lava-Dammed Lakes

One of the most intriguing episodes in the Quaternary evolution of the Grand Canyon of the Colorado River, Arizona, was the development of vast lakes that are thought to have backed up behind lava erupted into the gorge. Stratigraphic evidence for these deep lava-dammed lakes is expectedly sparse. Possible lacustrine deposits at six areas in the eastern canyon yielded no compelling evidence for sediment deposited in a deep lake. At two of the sites the sediment was associated with late Quaternary spring-fed pools and marshes. Water-lain silt and sand at lower Havasu Creek was deposited 3000 cal yr ago. The deposit contains an ostracode assemblage similar to that living in the modern travertine-dammed pools adjacent to the outcrop. The second deposit, at Lees Ferry, formed in a spring-fed marsh 43,000 cal yr ago, as determined by ¹⁴C and amino acid geochronology. It contains abundant ostracode and mollusk fossils, the richest assemblages reported from the Grand Canyon to date. Our interpretation of these sediments as spring-fed deposits, and their relative youth, provides an alternative to the conventional view that deposits like these were formed in deep lava-dammed lakes that filled the Grand Canyon.     

Low-temperature thermodynamic properties of disordered zeolites of the natrolite group

 The heat capacity of paranatrolite and tetranatrolite with a disordered distribution of Al and Si atoms has been measured in the temperature range of 6–309 K using the adiabatic calorimetry technique. The composition of the samples is represented with the formula (Na_1.90K_0.22Ca_0.06)[Al_2.24Si_2.76O₁₀]·nH₂O, where n=3.10 for paranatrolite and n=2.31 for tetranatrolite. For both zeolites, thermodynamic functions (vibrational entropy, enthalpy, and free energy function) have been calculated. At T=298.15 K, the values of the heat capacity and entropy are 425.1 ± 0.8 and 419.1 ±0.8 J K⁻¹ mol⁻¹ for paranatrolite and 381.0 ± 0.7 and 383.2 ± 0.7 J K⁻¹ mol⁻¹ for tetranatrolite. Thermodynamic functions for tetranatrolite and paranatrolite with compositions corrected for the amount of extraframework cations and water molecules have also been calculated. The calculation for tetranatrolite with two water molecules and two extraframework cations per formula yields: C _p (298.15)=359.1 J K⁻¹ mol⁻¹, S(298.15) −S(0)=362.8 J K⁻¹ mol⁻¹. Comparing these values with the literature data for the (Al,Si)-ordered natrolite, we can conclude that the order in tetrahedral atoms does not affect the heat capacity. The analysis of derivatives dC/dT for natrolite, paranatrolite, and tetranatrolite has indicated that the water- cations subsystem within the highly hydrated zeolite may become unstable at temperatures above 200 K. Received: 30 July 2001 / Accepted: 15 November 2001