The investigation of fault-controlled groundwater recharge within a suburban area of Damascus,Syria

Al-Mazraa is a heavily populated suburb of Damascus (Syria) with agricultural activity. It is adjacent to the Cretaceous Qassioun Mountain Range, from which it is structurally separated by the Damascus fault. Al-Mazraa waterworks abstracts from a shallow Quaternary aquifer, whose recharge processes are unidentified. The functions of Qassioun Mountain, the Damascus fault, the agricultural activities, the ascending deeper groundwater, and the through-flowing Tora River are not well understood and they are, hence, subject to study. The application of hydrochemical parameters and ratios in combination with signatures of δD and δ¹⁸O revealed that recharge predominantly occurs in the outcropping Cretaceous rocks through subsurface passages rather than through influent conditions of the Tora River or through direct rainfall. Interestingly, high Na/Cl ratios indicate contact with volcanic rocks which exist within the Cretaceous anticline and also in the subsurface of the studied Quaternary aquifer. Evidence for deeper circulating groundwater is given, since replenishing waters are up to 4 °C warmer and have much lower nitrate concentrations than the groundwater in the study area. From these points, it is indicated that the Damascus fault is conductive in respect to groundwater, rather than being impermeable, as it is elsewhere.     

Improved time control on Cretaceous coastal deposits: new results from Sr isotope measurements using laser ablation

Sr-isotope measurements of unaltered oyster shell calcite using laser-ablation multi-collector ICPMS techniques represent a powerful tool capable of establishing a chronostratigraphic framework for fossil near-shore deposits. This approach is tested on two shoal-water successions from the Portuguese Algarve and Lusitanian basins covering Late Barremian to Albian strata. ⁸⁷Sr/⁸⁶Sr values derived from low-Mg calcite of oyster shells fluctuate between 0.70717 ± 0.00001 and 0.70746 ± 0.00002; absolute values as well as stratigraphic trends match well with the global open-marine seawater signal. The new Sr-isotope results in combination with existing bio- and chemostratigraphic records allow for identification of an Early Aptian biocalcification crisis at both studied localities and show that this event has severely affected coastal environments along the evolving Atlantic. Siliciclastic intervals in the Algarve section are interpreted as near-shore equivalents of enhanced detrital shedding into shelf and deep-sea environments as a consequence of increased chemical weathering rates during humid climate episodes.     

Distribution of brine in grain boundaries during static recrystallization in wet, synthetic halite: insight from broad ion beam sectioning and SEM observation at cryogenic temperature

We report observations from room temperature static recrystallization experiments (annealing times from minutes to year) of cold-pressed, synthetic, coarse-grained, wet sodium chloride, prepared by broad ion beam polishing and SEM observations at cryogenic temperature to observe directly the brine in grain boundaries. At all stages of annealing, the majority of the brine in the samples is connected in 2D sections along grain boundaries. Another part of the brine is in isolated brine inclusion arrays along grain boundaries and in brine inclusions left behind by migrating brine-filled grain boundaries. Most of these boundaries are mobile because the aggregate is coarsening. We interpret that the boundaries without observable brine films (<15 nm) and brine inclusion arrays are healed and immobile. Evolution of grain boundary structure involves three major processes. First, dissolution on one side of the grain boundary and precipitation on the other side, resulting in grain boundary migration. Second, the development of facets formed by low-index crystallographic planes of the grains bounding the grain boundary brine. When both sides of a grain boundary are able to develop low-index facets in a thick brine film, the resulting impingement boundary is interpreted to be immobile and may prevent the new grain from migrating into a deformed neighbor. When one side of a faceted boundary consists of low-index crystallographic planes and the other side passively follows this faceted shape along irrational surfaces, the boundary is mobile. Third, the healing of grain boundary brine films, producing solid–solid grain boundaries without resolvable brine films.     

Use of major and selected trace elements to describe mixing processes in a water reservoir

Data on temperature, major constituents and some trace elements, measured in the dissolved and particulate phases, were used to identify the hydrodynamics of a reservoir (the Bicaz reservoir, Romania). Results revealed that the reservoir experiences two thermal stratifications per year (summer and winter). However, the summer stratification is delayed by the high river inflow of June–July. Two layers were identified, a surface and a deep layer, whose location and impact vary with time. The surface layer originates from the river inflow (intrusion layer) and the deep current is produced by the outflow (velocity current). According to season, the river inflow either supplies the deep current or remains recordable up to the dam. Consequently, the structure of the water column, and thus the biogeochemical processes within it, are governed both by thermal stratification and by these layers.     

Experimental investigation of shock metamorphic effects in a metapelitic granulite: The importance of shock impedance contrast between components

Shock recovery experiments were performed at 12.5, 25, 34, 40, and 56 GPa at 25 °C, and at 18 and 25 GPa at 400 °C, on a high‐grade, migmatitic, garnet‐cordierite metapelite from the Etivé aureole, Scotland. Objectives for this study were to (1) characterize shock effects in a complex polymineralic rock with a significant proportion of hydrous ferromagnesian minerals, both as a function of variable shock pressure and preshock temperature, and (2) to explore the effects of shock impedance contrast between component minerals on the respective abundances and distribution of these features. At any shock pressure, the order of decreasing intensity of shock metamorphic effects in component phases is: cordierite (Crd)→biotite (Bt)→plagioclase (Pl)→K‐feldspar (Kfs)→quartz (Qtz)→garnet (Grt)→orthopyroxene (Opx). Samples shocked to pressures below 40 GPa (25 °C) were typically characterized by marked heterogeneous distribution of shock effects on both intragranular and intergranular scales. Shock heterogeneity is mainly attributed to shock impedance contrast between contiguous phases, and manifests as shock amplification locally where shock impedance contrast is greatest, and shock suppression where impedance contrast is least. The heterogeneous distribution of shock metamorphic effects in both experiments and natural rocks is a signature of extreme disequilibrium at the submillimeter scale. The heterogeneous distribution of shock metamorphic effects mitigates against the use of shock effects in minerals exclusively as regional shock pressure barometers, and ought to be augmented by additional constraints on shock pressure from numerical models.     

Melt in the impact breccias from the Eyreville drill cores,Chesapeake Bay impact structure,USA

The center of the 35.3 Ma Chesapeake Bay impact structure (85 km diameter) was drilled during 2005/2006 in an ICDP–USGS drilling project. The Eyreville drill cores include polymict impact breccias and associated rocks (1397–1551 m depth). Tens of melt particles from these impactites were studied by optical and electron microscopy, electron microprobe, and microRaman spectroscopy, and classified into six groups: m1—clear or brownish melt, m2—brownish melt altered to phyllosilicates, m3—colorless silica melt, m4—melt with pyroxene and plagioclase crystallites, m5—dark brown melt, and m6—melt with globular texture. These melt types have partly overlapping major element abundances, and large compositional variations due to the presence of schlieren, poorly mixed melt phases, partly digested clasts, and variable crystallization and alteration. The different melt types also vary in their abundance with depth in the drill core. Based on the chemical data, mixing calculations were performed to determine possible precursors of these melt particles. The calculations suggest that most melt types formed mainly from the thick sedimentary section of the target sequence (mainly the Potomac Formation), but an additional crystalline basement (schist/gneiss) precursor is likely for the most abundant melt types m2 and m5. Sedimentary rocks with compositions similar to those of the melt particles are present among the Eyreville core samples. Therefore, sedimentary target rocks were the main precursor of the Eyreville melt particles. However, the composition of the melt particles is not only the result of the precursor composition but also the result of changes during melting and solidification, as well as postimpact alteration, which must also be considered. The variability of the melt particle compositions reflects the variety of target rocks and indicates that there was no uniform melt source. Original heterogeneities, resulting from melting of different target rocks, may be preserved in impactites of some large impact structures that formed in volatile‐rich targets, because no large melt body exists, in which homogenization would have taken place.     

Toward physical aspects affecting a possible leakage of geologically stored CO2 into the shallow subsurface

In geological formations, migration of CO₂ plume is very complex and irregular. To make CO₂ capture and storage technology feasible, it is important to quantify CO₂ amount associated with possible leakage through natural occurring faults and fractures in geologic medium. Present work examines the fracture aperture effect on CO₂ migration due to free convection. Numerical results reveal that fracture with larger-aperture intensify CO₂ leakage. Mathematical formulation and equations of state for the mixture are implemented within the object-oriented finite element code OpenGeoSys developed by the authors. The volume translated Peng–Robinson equation of state is used for material properties of CO₂ and water.     

Determination of major and trace elements in European bottled mineral water — Analytical methods

A total of 1785 European bottled water samples were analyzed using standard laboratory methods. The bottled water samples were purchased in 2008 at supermarkets throughout 40 European countries. The samples were analyzed for 71 chemical parameters (As, Al, As, B, Ba, Be, Bi, Ca, Cd, Ce, Co, Cr, Cs, Cu, Dy, Er, Eu, Fe, Ga, Gd, Ge, Hf, Hg, Ho, I, K, La, Li, Lu, Mg, Mn, Mo, Na, Nb, Nd, Ni, Pb, Pr, Rb, Sb, Sc, Se, Sm, Sn, Sr, Ta, Tb, Te, Th, Ti, Tl, Tm, U, V, W, Y, Yb, Zn, Zr, Br⁻, HCO₃⁻, Cl⁻, F⁻, NH₄⁺, NO₂⁻, NO₃⁻, PO₄³⁻, SO₄²⁻, SiO₂, pH, and EC) by quadrupole inductively coupled emission spectroscopy (ICP-QMS, trace elements), inductively coupled plasma atomic emission spectroscopy (ICP-AES, major elements), ion chromatography (IC, anions), atomic fluorescence spectrometry (AFS, Hg), titration (alkalinity), photometric methods (NH₄⁺), potentiometric methods (pH), and conductometric methods (specific electrical conductivity, EC). A very strict quality control procedure was followed by analysing blanks, international reference materials, an internal project standard, and duplicate analyses, as well as by analysing 23 elements by both ICP-QMS and ICP-AES. Analysis of marketed bottled water from springs, wells or boreholes, apart from the evaluation of its quality with respect to inorganic elements, it may provide a cheap alternative to obtain a first impression about groundwater chemistry at the European scale.