The upper Cenomanian (Cretaceous) ammonite Neolobites vibrayeanus () in the Middle East: taxonomic and palaeoecologic remarks

In the Middle East and Africa, the Cenomanian ammonite genus Neolobites occurs, partly in great abundance, in shallow marine shelf settings. The genus includes several species but it has remained uncertain to what extent these species reflect biospecies, chronospecies or morphological variants. Based on material from Jordan and Egypt, the morphological variation of Neolobites vibrayeanus is described and discussed. From the several species of Neolobites described in the literature, only N. vibrayeanus, N. fourtaui and N. peroni appear to deserve specific separation. Sedimentological and lithological data, notably the common occurrence in strata that were possibly deposited above storm wave base, suggest that Neolobites was able to inhabit shallow marine settings. In these settings, it seems to form a distinct assemblage with the nautiloid Angulithes. Although N. vibrayeanus shows morphological variability between distinct populations, local N. vibrayeanus assemblages seem to develop morphologically stable populations that show only a little morphological overlap with those of other areas. This may be the reason for the earlier taxonomic splitting. The occurrence in habitats in which other stratigraphically significant ammonites are often missing may be the reason for the previous poor dating of Neolobites assemblages.     

Transient Leakance and Infiltration Characteristics during Lake Bank Filtration

Infiltration capacity of bank filtration systems depends on water extraction and hydraulic resistance of the bed sediments. Lakebed hydraulics may be especially affected by clogging, which is dependent on settlement of fine particles, redox potential, and other factors. In the field, most of these processes are difficult to quantify, and thus, when calculating response to pumping the water flux across the sediment surface is assumed to be linearly dependent on the hydraulic gradient. However, this assumption was not adequate to describe conditions at a bank filtration site located at Lake Tegel, Berlin, Germany. Hence, we first assumed the leakage coefficient (or leakance) is spatially distributed and also temporally variant. Furthermore, observations show that the leakance is considerably higher in shallow than in deeper areas; hence, leakance was assumed to be dependent on the existence and thickness of an unsaturated zone below the lake. The proposed explanation of spatial and temporal variability in leakance involves a hypothesis for redox dependent and reversible biogeochemical clogging, supported by geochemical observations in surface water and ground water. Four leakance approaches are implemented in the ground water flow code MODFLOW2000 and calibrated by inverse modeling using the parameter estimation software PEST. These concepts are evaluated by examining the fit to the hydraulic heads, to infiltration measurements, transport modeling results, and considering the degrees of freedom due to the number of calibration parameters. The leakage concept based on the assumption of the influence of an unsaturated zone on clogging processes best explains the field data.     

Alternative mission architectures for a gravity recovery satellite mission

Since its launch in 2002, the Gravity Recovery and Climate Experiment (GRACE) mission has been providing measurements of the time-varying Earth gravity field. The GRACE mission architecture includes two satellites in near-circular, near-polar orbits separated in the along-track direction by approximately 220 km (e.g. collinear). A microwave ranging instrument measures changes in the distance between the spacecraft, while accelerometers on each spacecraft are used to measure changes in distance due to non-gravitational forces. The fact that the satellites are in near-polar orbits coupled with the fact that the inter-satellite range measurements are directed in the along-track direction, contributes to longitudinal striping in the estimated gravity fields. This paper examines four candidate mission architectures for a future gravity recovery satellite mission to assess their potential in measuring the gravity field more accurately than GRACE. All satellites were assumed to have an improved measurement system, with an inter-satellite laser ranging instrument and a drag-free system for removal of non-gravitational accelerations. Four formations were studied: a two-satellite collinear pair similar to GRACE; a four-satellite architecture with two collinear pairs; a two-satellite cartwheel formation; and a four-satellite cartwheel formation. A cartwheel formation consists of satellites performing in-plane, relative elliptical motion about their geometric center, so that inter-satellite measurements are, at times, directed radially (e.g. parallel to the direction towards the center of the Earth) rather than along-track. Radial measurements, unlike along-track measurements, have equal sensitivity to mass distribution in all directions along the Earth’s surface and can lead to higher spatial resolution in the derived gravity field. The ability of each architecture to recover the gravity field was evaluated using numerical simulations performed with JPL’s GIPSY-OASIS software package. Thirty days of data were used to estimate gravity fields complete to degree and order 60. Evaluations were done for 250 and 400 km nominal orbit altitudes. The sensitivity of the recovered gravity field to under-sampled effects was assessed using simulated errors in atmospheric/ocean dealiasing (AOD) models. Results showed the gravity field errors associated with the four-satellite cartwheel formation were approximately one order of magnitude lower than the collinear satellite pair when only measurement system errors were included. When short-period AOD model errors were introduced, the gravity field errors for each formation were approximately the same. The cartwheel formations eliminated most of the longitudinal striping seen in the gravity field errors. A covariance analysis showed the error spectrum of the cartwheel formations to be lower and more isotropic than that of the collinear formations.     

Arsenic in framboidal pyrite from recent sediments of a shallow water lagoon of the Baltic Sea

Arsenic is a redox‐sensitive element of environmental relevance and often enriched in iron sulphides. Because sediments from the Achterwasser lagoon, a part of the estuarine system of the river Oder, south‐west Baltic Sea, show unexpectedly high pyrite concentrations of up to 7·5 wt% they were used to investigate the influence of authigenic pyrite on the mobility and burial of As in the coastal environment. Micro‐X‐ray‐fluorescence measurements of 106 micrometre‐sized pyrite framboids from the anoxic sediments show highly variable As concentrations ranging from 6 to 1142 μg g^?1. Even within a 1 cm thick layer, the As concentration of different framboids varies greatly and no clear depth trend is visible throughout the 50 cm long sediment core. Pyrite can account for 9 to 55% (average 22%) of the total As budget of the sediments and the degree of trace metalloid pyritization for As ranges from 26 to 61%, indicating that authigenic pyrite formation is an important process in the geochemical cycling of As in coastal sediments. High‐resolution micro‐X‐ray fluorescence mapping of single pyrite grains shows that As is distributed inhomogeneously within larger framboids, suggesting changing pore water composition during pyrite growth. X‐ray absorption near edge structure spectra indicate that As is usually present as As(‐I) substituting S in the pyrite lattice. However, in samples close to the sediment/water interface a considerable part of As is in higher valence states (+III/+V). This can be explained by frequent re‐suspension of the surficial sediments to the oxic water column due to wave action and subsequent re‐deposition, leading to the adsorption of As oxyanions onto pyrite. Although reduced As(‐I) becomes more important in the deeper samples, reflecting decreasing redox potential and a longer time since deposition, the occurrence of oxidized As species (AsIII/AsV) in pyrite in the anoxic part of the sediment suggests formation under dysoxic conditions.     

Trends in the solid phase partitioning of metals in the Thames Estuary sediments during recent decades

A sequential extraction method was employed to extract the metals Al, Ag, Cd, Co, Cr, Cu, Pb, Fe, Li, Mn, Ni, and Zn from a 10-m sediment core taken from the Tilbury Basin on the Thames Estuary. Characteristics of the observed metal partitioning distributions were attributed primarily to the composition of the estuarine waters at the time of deposition. For some metals, a decrease in the bulk sediment metal concentrations from a depth of ?6.59 m ODN to the surface was also observed in one of the solid phases. This was the case for Cr, Cu, and Pb extracted from the organic phase and for Zn extracted from the carbonate phase. This decrease in sediment concentrations is thought to reflect reported improvements to water quality in this region of the Thames Estuary in the early 1960s, following updating of major sewage treatment works (STW) approximately 20 km upstream. These findings give an indication of the influence of estuarine inputs from STW on metal partitioning distributions. The order of mobility for the metals of environmental concern was Cd>Ag>Cr>Ni, Zn>Co, Cu, Pb. for Cd and Ag there was a tendency to partition towards the exchangeable phase, both at the surface and at depth, which indicates the potential for long-term leaching of these metals from the sediments.     

Comparison of DC sensitivity patterns for anisotropic and isotropic media

Many rocks possess electrical properties with a clearly expressed anisotropy. The anisotropic character of the rocks is often overlooked in forming the Fréchet derivatives or sensitivity functions for parameter updating during the inversion of DC resistivity data. In this study we have compared the sensitivity patterns for an isotropic, homogeneous model with that for a transversely isotropic (i.e. anisotropic) model having a tilted axis of symmetry using a pole–pole array. The sensitivity functions are expressed in terms of the derivatives of the electric potential U with respect to the average conductivity σ_m (geometric mean of the longitudinal and transverse conductivities) and the coefficient of anisotropy λ. Results are plotted in both cross-section form and plan view for various dip and strike angles of the axis of symmetry. The derivative dU/dλ decreases more rapidly than the isotropic value dU/dσ, and shows pronounced asymmetry and weakening of magnitude with increasing dip of the plane of symmetry. The derivative dU/dσ_m also exhibits the asymmetric pattern (except for vertical and horizontal dip cases). The positive region between the electrodes only extends to a small depth compared to the isotropic derivative, even in the case of a vertical axis of symmetry (VTI medium). The ratio of this anisotropic derivative to the isotropic derivative, when plotted as a function of position and depth shows prominent differences in both the sign and the magnitude of the sensitivities, especially for steep dips and for strongly anisotropic rocks. The plot highlights the dangers of an isotropic assumption. Even for mildly anisotropic rocks (λ < 1.2) the possibility for error in interpretation is considerable. Combined borehole and surface measurements are needed to diagnose anisotropy. Further work is needed to design optimal electrode configurations in anisotropic situations.     

Influence of Hematite Coating on the Activation of the Swelling Potential of Smectite-Bearing Rocks

The fraction of swelling-type clay minerals (smectites) is a first measure to estimate the swelling potential of natural rocks. This swelling potential is only activated if water can be incorporated in the sheet silicates. The samples studied in this work are volcanic rocks from the Southern Andes. According to the petrographic and mineralogical studies, the rocks are characterized as vulcanite with high content of smectite. Undisturbed samples showed minor swelling behaviour in conventional swelling tests, although X-ray diffraction and differential thermal analysis revealed swelling clay contents of more than 70 % in some samples. Powder swelling tests were performed on ground and recompacted rock samples. The results of these tests show a better agreement with those expected according to the mineralogical composition of the samples. The reason for the non-activation of the swelling potential in undisturbed samples was suspected to be the influence of the iron-oxide/hydroxide content, which was on average around 11 %. Scanning electron microscope images showed that the edge terminations of the clay particles are coated with hematite. The hydrophobic properties of hematite impede the access of water between the interlayers of the clay minerals and, in addition, hematite cementation prevents the expansion. In a further series of swelling tests water was replaced by a reducing solution (0.1 molar hydroxylammonium chloride) which removes the Fe-oxide coating. It can be shown that thus the swelling potential of the clay minerals in such undisturbed rocks can be activated.     

The extent of chronic marine oil pollution in southeastern Newfoundland waters assessed through beached bird surveys 1984-1999

The Grand Banks south of Newfoundland provide year-round feeding habitat for tens of millions of seabirds of numerous species, an abundance and diversity unparalleled in the North Atlantic. Dense ship traffic routes traverse this productive environment as vessels travel the Great Circle Route between Europe and North America. Oiled seabirds have washed up on beaches in Newfoundland for many decades. Most oil on their feathers is heavy fuel oil mixed with lubricants, the mixture found in bilges of large vessels. Beached bird surveys conducted between 1984 and 1999 indicate that chronic oil pollution along the southeast coast of Newfoundland is among the highest in world. Sixty two percent of all dead birds found over the 16-year period had oil on their feathers; 74% during the last five years. Auks, especially Thick-billed Murres (Uria lomvia), are the most affected. The mean number of oiled birds per kilometer was 0.77 and thus higher than in other regions of the world during a comparable time period (0.02-0.33). Oiling rates correlated with weather patterns and degree of the regional murre hunt, indicate that illegal dumping of oil may occur year round, and point out that it is critical to assess all possible environmental and anthropogenic factors influencing the number of clean and oiled dead birds found on beaches before inferring trends in oiling rates over time.     

Geomagnetische Tiefentellurik Tell I: Die elektrische Leitfähigkeit der Erdkruste und des oberen Erdmantels

Zusammenfassung Die magneto-tellurischen Verhältnisse in Niemegk und Ückermünde wurden für einen Periodenbereich von 10 bzw. 50 sec bis 86 400 sec ausgewertet. Der scheinbare Widerstand ist abhängig von der Richtung und von der Periode. Aus den magnetischen Variationen läßt sich angenähert die Richtung der Induktionsströme bei inhomogenem Untergrund feststellen. Durch Vergleich mit Ergebnissen an anderen Orten zeigt sich, daß der elektrische Widerstand der Kruste und des Mantels in horizontaler Richtung sehr unterschiedlich ist. Die Widerstände sind kleiner als man bisher angenommen hat und keinesfalls in der Größe von 10 000 m.

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Summary The apparent resistivity as a function of period (10–86400 sec) was deduced from magnetic and telluric registrations for the stations Niemegk and Ückermünde. The amount of apparent resistivity depends on direction and the period of the variation. It is possible to determine the direction of the induced currents in case of regional electrical inhomogeneities from magnetic registrations alone. In comparing these results with those of other stations it is seen that the resistivity in horizontal directions differs very much from place to place for the earthcrust and the upper mantle. The specific resistivities are much smaller than thougt before, they amount hardly 10⁴ m locally and never for the whole earth.

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Mitteilung Nr. 114 des Geomagnetischen Instituts Potsdam.