Drowning history of a Miocene carbonate platform (Zhujiang Formation, South China Sea)

The identification and interpretation of drowning events in the geologic record can aid significantly to the reconstruction of the depositional, tectonic and eustatic history of a study area and often improve reservoir and seal prediction in carbonate rocks. The differentiation between drowned platforms showing a record of continuous deepening and those with a record of exposure followed by rapid deepening remains, however, problematic. The Zhujiang carbonate platform (Liuhua 11-1 field, South China Sea) study shown here provides an example of an integrated approach combining high-resolution geochemistry, microfacies analyses and foraminiferal biostratigraphy in order to improve the reconstruction of environmental conditions prior, during and after platform demise and drowning. The Zhujiang carbonate platform displays the following vertical succession of four facies types i) skeletal grain facies with a miogypsinid/lepidocyclinid-dominated fauna deposited in a moderately deep (< 50 m), oligotrophic back-reef setting; ii) in situ corals in patch-reef facies in an oligotrophic lagoon (< 10 m); iii) rhodoid facies with in situ red algal crusts, dominated by Heterostegina sp. and spiroclypeids, possibly capped by a subaerial exposure surface. Well-rounded rhodoids representing a mesotrophic lagoon dominate the upper portions of the rhodoid facies; iv) pelagic marine shales of the Hanjiang Formation burying the carbonate platform after drowning. This facies succession, in combination with geochemical evidence suggests a deepening-upward trend. This trend might have been interrupted by transient subaerial exposure but no evidence for meteoric diagenesis was found at the drowning unconformity topping the carbonate platform. Instead, microfacies analyses suggest that platform demise may be related to progressive changes in environmental conditions, including increasing nutrient-levels and/or decreasing temperature up-core towards the drowning unconformity. These findings are of significance for those concerned with Miocene carbonate factories and, more specifically, the demise of carbonate platforms in general.     

Stochastic Modelling of Mineral Exploration Targets

Mathematical Geosciences - Mineral deposits are metal enrichment anomalies, occurring as local manifestations of the interplay between various geological processes that operate at a wide range of...     

The wetting ability of Si-bearing liquid Fe-alloys in a solid silicate matrix—percolation during core formation under reducing conditions?

The wetting characteristics of liquid Fe–Si alloys in a matrix of the respective predominating stable silicate mantle mineral (forsterite or silicate perovskite) at pressures of 2–5 and 25 GPa and temperatures of 1600–2000 °C were studied by determining the liquid metal–solid silicate contact angles. The median angle values from texturally equilibrated samples were found to be independent of pressure, temperature, silicate mineralogy and the Si content in the metal fraction and range between 130° and 140° which is far above the critical wetting boundary of 60°. This shows that within the studied range of conditions dissolved Si does not lower the surface energies between Fe-rich liquids and silicate mantle grains. As a consequence, under reducing conditions the presence of Si in the metal phase of planetary bodies would not have enhanced percolative flow as an effective metal–silicate separation process.     

The replacement of plagioclase feldspars by albite: observations from hydrothermal experiments

Oligoclase and labradorite crystals have been experimentally replaced by albite in an aqueous sodium silicate solution at 600°C and 2 kbars. The replacement is pseudomorphic and is characterised by a sharp chemical interface which progresses through the feldspar while preserving the crystallographic orientation. Reaction rims of albite, up to 50 μm thick, can be readily achieved within 14 days. Re-equilibration of plagioclase in an ¹⁸O-enriched sodium- and silica-bearing solution results in oxygen isotope redistribution within the feldspar framework structure. The observed characteristics of the reaction products are similar to naturally albitised plagioclase and are indicative of an interface-coupled dissolution–reprecipitation mechanism. Chemical analyses demonstrate that the albitisation is accompanied by the mobilisation of major, minor and trace elements also including elements such as Al and Ti which are commonly regarded as immobile during hydrothermal alteration. The results contribute to developing our understanding of the close association between large-scale albitisation and secondary ore mineralisation which is common in nature.     

Heterogeneous accretion,composition and core–mantle differentiation of the Earth

A model of core formation is presented that involves the Earth accreting heterogeneously through a series of impacts with smaller differentiated bodies. Each collision results in the impactor's metallic core reacting with a magma ocean before merging with the Earth's proto-core. The bulk compositions of accreting planetesimals are represented by average solar system abundances of non-volatile elements (i.e. CI-chondritic), with 22% enhancement of refractory elements and oxygen contents that are defined mainly by the Fe metal/FeO silicate ratio. Based on an anhydrous bulk chemistry, the compositions of coexisting core-forming metallic liquid and peridotitic silicate liquid are calculated by mass balance using experimentally-determined metal/silicate partition coefficients for the elements Fe, Si, O, Ni, Co, W, Nb, V, Ta and Cr. Oxygen fugacity is fixed by the partitioning of Fe between metal and silicate and depends on temperature, pressure and the oxygen content of the starting composition. Model parameters are determined by fitting the calculated mantle composition to the primitive mantle composition using least squares minimization. Models that involve homogeneous accretion or single-stage core formation do not provide acceptable fits. In the most successful models, involving 24 impacting bodies, the initial 60–70% (by mass) of the Earth accretes from highly-reduced material with the final 30–40% of accreted mass being more oxidised, which is consistent with results of dynamical accretion simulations. In order to obtain satisfactory fits for Ni, Co and W, it is required that the larger (and later) impactor cores fail to equilibrate completely before merging with the Earth's proto-core, as proposed previously on the basis of Hf-W isotopic studies. Estimated equilibration conditions may be consistent with magma oceans extending to the core–mantle boundary, thus making core formation extremely efficient. The model enables the compositional evolution of the Earth's mantle and core to be predicted throughout the course of accretion. The results are consistent with the late accretion of the Earth's water inventory, possibly with a late veneer after core formation was complete. Finally, the core is predicted to contain ~ 5 wt.% Ni, ~ 8 wt.% Si, ~ 2 wt.% S and ~ 0.5 wt.% O.