Elimination of Carbamazepine,Diclofenac and Naproxen from Treated Wastewater by Nanofiltration

Most conventional wastewater treatment plants remove very small amounts of micropollutants, such as pharmaceuticals. Here, the ability of two different types of submerged nanofiltration flat sheet modules to remove pharmaceuticals from wastewater is analyzed. The two nanofiltration membranes were used at relatively low pressures of only 0.3 and 0.7 bar. At such low pressures, the membranes did not retain salts to a great extent. This is advantageous in wastewater treatment because no salt concentrate is produced. Carbamazepine was retained only slightly by the nanofiltration membranes, whereas approximately 60% of diclofenac and naproxen were retained by both membranes. This level of effectiveness might not be enough to justify the use of such a system as an additional treatment step in wastewater treatment plants.     

Diverse Range of Mineralization Induced by Phase Separation of Hydrothermal Fluid: Case Study of the Yonaguni Knoll IV Hydrothermal Field in the Okinawa Trough Back-Arc Basin

The Yonaguni Knoll IV hydrothermal vent field (24°51′N, 122°42′E) is located at water depths of 1370–1385 m near the western edge of the southern Okinawa Trough. During the YK03–05 and YK04–05 expeditions using the submersible Shinkai 6500, both hydrothermal precipitates (sulfide/sulfate/carbonate) and high temperature fluids (Tmax = 328°C) presently venting from chimney‐mound structures were extensively sampled. The collected venting fluids had a wide range of chemistry (Cl concentration 376–635 mmol kg^?1), which is considered as evidence for sub‐seafloor phase separation. While the Cl‐enriched smoky black fluids were venting from two adjacent chimney‐mound structures in the hydrothermal center, the clear transparent fluids sometimes containing CO₂ droplet were found in the peripheral area of the field. This distribution pattern could be explained by migration of the vapor‐rich hydrothermal fluid within a porous sediment layer after the sub‐seafloor phase separation. The collected hydrothermal precipitates demonstrated a diverse range of mineralization, which can be classified into five groups: (i) anhydrite‐rich chimneys, immature precipitates including sulfide disseminations in anhydrite; (ii) massive Zn‐Pb‐Cu sulfides, consisting of sphalerite, wurtzite, galena, chalcopyrite, pyrite, and marcasite; (iii) Ba‐As chimneys, composed of barite with sulfide disseminations, sometimes associated with realgar and orpiment overgrowth; (iv) Mn‐rich chimneys, consisting of carbonates (calcite and magnesite) and sulfides (sphalerite, galena, chalcopyrite, alabandite, and minor amount of tennantite and enargite); and (v) pavement, silicified sediment including abundant native sulfur or barite. Sulfide/sulfate mineralization (groups i–iii) was found in the chimney–mound structure associated with vapor‐loss (Cl‐enriched) fluid venting. In contrast, the sulfide/carbonate mineralization (group iv) was specifically found in the chimneys where vapor‐rich (Cl‐depleted) fluid venting is expected, and the pavement (group v) was associated with diffusive venting from the seafloor sediment. This correspondence strongly suggests that the subseafloor phase separation plays an important role in the diverse range of mineralization in the Yonaguni IV field. The observed sulfide mineral assemblage was consistent with the sulfur fugacity calculated from the FeS content in sphalerite/wurtzite and the fluid temperature for each site, which suggests that the shift of the sulfur fugacity due to participation of volatile species during phase separation is an important factor to induce diverse mineralization. In contrast, carbonate mineralization is attributed to the significant mixing of vapor‐rich hydrothermal fluid and seawater. A submarine hydrothermal system within a back‐arc basin in the continental margin may be considered as developed in a geologic setting favorable to a diverse range of mineralization, where relatively shallow water depth induces sub‐seafloor phase separation of hydrothermal fluid, and sediment accumulation could enhance migration of the vapor‐rich hydrothermal fluid.     

The young star cluster system of the Antennae galaxies

The study of young star cluster (YSC) systems, preferentially in starburst and merging galaxies, has seen great interest in the recent past, as it provides important input to models of star formation. However, even some basic properties (such as the luminosity function; LF) of YSC systems are still being debated. Here, we study the photometric properties of the YSC system in the nearest major merger system, the Antennae galaxies. We find evidence for the existence of a statistically significant turnover in the LF.     

Landscape position,surface hydraulic gradients and erosion processes

Different hydraulic gradients, especially due to seepage or drainage, at different locations on a hillslope profile may have a profound effect on the dominant erosion processes. A laboratory study was designed to simulate hillslope processes and quantify effects of surface hydraulic gradients on erosion for a Glynwood clay loam soil (fine, illitic, mesic Aquic Hapludalf). A 5 m long, 1·2 m wide soil pan was used at 5 and 10 per cent slopes with an external watering tube to vary the soil bed's hydrological conditions. Different combinations of slope steepness with seepage or drainage gradients were used to simulate the hydrologic conditions on a 5 m segment of a hillslope profile. Runoff samples were taken during rainfall-only and rainfall with added inflow. Results showed that, under drainage conditions, interrill processes dominated and rilling was limited. The surface contained scattered crescent-shaped pits after the run. Under seepage conditions, rilling processes dominated and the inflow introduced at the top of the soil pan further accelerated the headward erosion of the rills. Erosion rates increased by as much as 60 times under seepage conditions representative of the lower backslope when compared to drainage conditions that generally occur at the upper backslope. This indicated that rills and gullies on backslopes and footslopes may be catalysed or enhanced by seepage conditions rather than form from flow hydraulic shear stress alone. An understanding of spatial and temporal changes that affect both hillslope hydrology and erosional processes is needed to develop accurate process-based erosion prediction models. This knowledge may lead to different management practices on landscape positions where seepage occurs. © 1998 John Wiley & Sons, Ltd.     

A multi-method approach for the identification and quantification of water balance components of two lentic small water bodies

The protection of the globally widespread lentic small water bodies (LSWB) must be based on detailed knowledge about their hydrological connectivity and water balance. The study aimed to identify and quantify water balance components as well as surface-groundwater interaction of two LSWB in a characteristic lowland region with a combination of different methods. This includes the collection of hydrological data and the use of bromide and water stable isotopes (δ²H and δ¹⁸O) as tracers. With their help, mixing models were established, and daily water balances were assessed. The results show a strong bidirectional interaction of both LSWB systems with shallow groundwater. Bromide and stable isotope tracers allowed for the identification of the most relevant in- and outflow sources and pathways. Thereby, isotope data revealed isotopic enrichment typical for open-water bodies and only minor precipitation inputs mainly relevant at the end of the dry season. Water balance calculations suggested accentuated seasonal dynamics that were strongly influenced by shallow groundwater, which represented large inputs into both LSWB. By that, different phases could be identified, with high inflow rates in winter and spring and decreasing fluxes in summer. In one LSWB, a drainage system was found to have a major impact next to the shallow groundwater interaction. The findings of this research provide detailed insights into the influence and importance of shallow groundwater for LSWB in lowland regions. This impacts the diffuse input of agricultural pollutants into these ecologically important landscape features.     

Al-Cu-Fe alloys in the solar system: Going inside a Khatyrka-like micrometeorite (KT01) from the Nubian Desert,Sudan

A recently described micrometeorite from the Nubian desert (Sudan) contains an exotic Al-Cu-Fe assemblage closely resembling that observed in the Khatyrka chondrite (Suttle et al., 2019; Science Reports 9:12426). We here extend previous investigations of the geochemical, mineralogical, and petrographic characteristics of the Sudan spherule by measuring oxygen isotope ratios in the silicate components and by nano-scale transmission electron microscopy study of a focused ion beam foil that samples the contact between Al-Cu alloys and silicates. O-isotope work indicates an affinity to either OC or CR chondrites, while ruling out a CO or CM precursor. When combined with petrographic evidence we conclude that a CR chondrite parentage is the most likely origin for this micrometeorite. SEM and TEM studies reveal that the Al-Cu alloys mainly consist of Al metal, stolperite (CuAl), and khatyrkite (CuAl₂) together with inclusions in stolperite of a new nanometric, still unknown Al-Cu phase with a likely nominal Cu₃Al₂ stoichiometry. At the interface between the alloy assemblage and the surrounding silicate, there is a thin layer (200 nm) of almost pure MgAl₂O₄ spinel along with well-defined and almost perfectly spherical metallic droplets, predominantly iron in composition. The study yields additional evidence that Al-Cu alloys, the likely precursors to quasicrystals in Khatyrka, occur naturally. Moreover, it implies the existence of multiple pathways leading to the association in reduced form of these two elements, one highly lithophile and the other strongly chalcophile.     

Chemically consistent evolutionary synthesis

To account for the range of stellar metallicities in local galaxies and for the increasing importance of low metallicities at higher redshift we present chemically consistent models for the spectral and chemical evolution of galaxies over cosmological timescales. We discuss advantages, limitations and future prospects of our approach. This revised version was published online in August 2006 with corrections to the Cover Date.     

Deriving Star Formation Histories: Evolutionary or Population Synthesis Codes versus Color-Magnitude Diagrams

The goal of this project is to analyze the integrated-light spectrum of a region in the LMC bar, for which HST images are already available yielding color-magnitude diagrams reaching the oldest main-sequence turnoff. Then, we can derive the star formation history in this field through evolutionary/population synthesis of the integrated light from 330 to 990 nm by a variety of independent methods and compare the results with the - in principle - more reliable results derived from the analysis of the color-magnitude diagram (CMD). This confrontation is the key ‘truth-test’ needed for the understanding of the abilities and the limitations of the evolutionary/population synthesis methods that must be applied of necessity to unresolved nearby and far-away galaxies. We report here on the observational part of the project. This revised version was published online in September 2006 with corrections to the Cover Date.