H2S Emissions from a Submerged Pilot‐Scale Fixed Bed Biofilm Reactor

A study was performed in two submerged, pilot‐scale biofilm bioreactors operated under different conditions to determine the relationship between the operating parameters and H₂S emission. H₂S was always detected in the exhaust air at concentrations varying from 1 to 353 ppm_v. The specific aeration rate was the most influencing parameter, with As < 30 kg COD (dissolved oxygen concentrations <4 mg L^?1) increasing noticeably the H₂S production. The periodical removal of the accumulated sludge reduced H₂S emissions by ～14%.     

Effects of slope angle and aspect on plant cover and species richness in a humid Mediterranean badland

Soil erosion is one of the most severe land degradation processes in the Mediterranean region. Although badlands occupy a relatively small fraction of the Mediterranean area, their erosion rates are very high. Many studies have investigated to what extent vegetation controls soil erosion rates. This study, however, deals with the impact of erosion on vegetation establishment. In semi‐arid badlands of the Mediterranean, soil water availability constitutes the main limiting factor for vegetation development. As a consequence, south‐facing slopes are typically less vegetated due to a very large water stress. However, these findings do not necessarily apply to humid badlands. The main objective of this paper is to determine the topographic thresholds for plant colonization in relation to slope aspect and to assess the spatial patterns of vegetation cover and species richness. We surveyed 179 plots on highly eroded badland slopes in the Central Pyrenees. We defined four aspect classes subdivided into slope angle classes. Colonization success was expressed in terms of vegetation cover and species richness. Slope angle thresholds for plant colonization were identified for each slope aspect class by means of binary logistic regressions. The results show that a critical slope angle exists below which plants colonize the badland slopes. Below this critical slope angle, plant cover and species richness increase with a decreasing slope angle. The largest critical slope angles in humid badlands are observed on south‐facing slopes, which contrasts with the results obtained in semi‐arid badlands. North‐facing slopes however are characterized by a reduced overall vegetation cover and species richness, and lower topographic threshold values. The possible underlying processes responsible for this slope‐aspect discrepancy in vegetation characteristics are discussed in terms of environmental variables that control regolith development, weathering and erosion processes. Moreover, possible restoration strategies through the use of vegetation in highly degraded environments are highlighted. Copyright © 2014 John Wiley & Sons, Ltd.     

Petrogenesis of diabase from accretionary prism in the southern Qiangtang terrane,central Tibet: Evidence from U–Pb geochronology,petrochemistry and Sr–Nd–Hf–O isotope characteristics

The Bangong–Nujiang suture (BNS) between the Lhasa and Qiangtang terranes is an important boundary and its petrogenesis is controversial. Diabase from the accretionary prism in the southern Qiangtang terrane yields a zircon U–Pb age of 181.3 ± 1.4 Ma. All the diabases show tholeiitic basalt compositions, gentle enrichment patters of light rare earth elements (REE), variable enrichment in incompatible element concentrations (e.g. Th and Rb), and no anomaly in high field strength elements (e.g. Nb and Ta), similar to that of enriched mid‐ocean ridge basalt (E‐MORB). They have relatively homogeneous whole rock Nd (εNd(t) = 7.3–9.1) and zircon Hf–O isotopic compositions (εHf(t) = 14.8–16.1, and δ¹⁸O = 4.57–6.12‰), possibly indicating melting of the depleted mantle and no significant crustal contamination during the petrogenesis. The element variations suggest that the diabases were formed by plume–ridge interaction at a mid‐ocean ridge within the Bangong–Nujiang ocean.     

Effect of natural restoration time of abandoned farmland on soil detachment by overland flow in the Loess Plateau of China

Vegetation restoration has significant effects on soil properties and vegetation cover and thus affects soil detachment by overland flow. Few studies have been conducted to evaluate this effect in the Loess Plateau where a Great Green Project was implemented in the past decade. This study was carried out to quantify the effects of age of abandoned farmland under natural vegetation restoration on soil detachment by overland flow and soil resistance to erosion as reflected by soil erodibility and critical shear stress. The undisturbed soil samples were collected from five abandoned farmlands with natural restoration age varying from 3 to 37 years. The samples were subjected to flow scouring in a 4.0 m long by 0.35 m wide hydraulic flume under six different shear stresses ranging from 5.60 to 18.15 Pa. The results showed that the measured soil detachment capacities in currently cultivated farmland were 24.1 to 35.4 times greater than those of the abandoned farmlands. For the abandoned farmlands, soil detachment capacities fluctuated greatly due to the complex effects of root density and biological crust thickness, and could be simulated well by flow shear stress and biological crust thickness with a power function (NSE = 0.851). Soil erodibility of abandoned farmlands decreased gradually with restoration age and reached a steady stage when restoration age was greater than 28 years. The critical shear stress of the natural abandoned farmlands declined when restoration age was less than 18 years and then increased due to the episodic influences of vegetation recovery and biological crust development. More studies in the Loess Plateau are necessary to quantify the relationship between soil detachment capacity and biological crust thickness for better understanding the mechanism of soil detachment under natural vegetation restoration. Copyright © 2013 John Wiley & Sons, Ltd.     

Chloride transfer in cement‐based materials. Part 1. Theoretical basis and modelling

In this first part of the work, we develop macroscopic models for migration and diffusion–migration of ionic species in saturated porous media, based on periodic homogenization. The prior application is chloride transport in cementitious materials. The dimensional analysis of Nernst–Planck equation lets appear to dimensionless numbers characterizing the ionic transfer in the porous medium. Using experimental data obtained from electrodiffusion tests on cement‐based materials (Part II), these dimensionless numbers are linked to the perturbation parameter ?. For a strong imposed electrical field, the asymptotic expansion of Nernst–Planck equation leads to a macroscopic model where the migration is predominant. For a weak imposed electrical field or in natural diffusion, we obtain a macroscopic model coupling diffusion and migration at the same order. In both models, the expression of the homogenized diffusion tensor is identical and only involves the geometric properties of the material microstructure. Copyright © 2012 John Wiley & Sons, Ltd.     

Submarine reworking of exhumed subcontinental mantle rocks: field evidence from the Lherz peridotites,French Pyrenees

In the Pyrenees, the lherzolites nowhere occur as continuous units. Rather, they always outcrop as restricted bodies, never more than 3 km wide, scattered across Mesozoic sedimentary units along the North Pyrenean Fault. We report the results of a detailed analysis of the geological setting of the Lherz massif (central Pyrenees), the type‐locality of lherzolites and one of the most studied occurrences of mantle rocks worldwide. The Lherz body is only 1.5 km long and belongs to a series of ultramafic bodies of restricted size (a few metres to some hundreds of metres), occurring within sedimentary formations composed mostly of carbonate breccias originating from the reworking of Mesozoic platform limestones and dolomites. The clastic formations also include numerous layers of polymictic breccias reworking lherzolitic clasts. These layers are found far from any lherzolitic body, implying that lherzolitic clasts cannot derive from the in situ fragmentation of an ultramafic body alone, but might also have been transported far away from their sources by sedimentary processes. A detailed analysis of the contacts between the Lherz ultramafic body and the surrounding limestones confirms that there is no fault contact and that sediments composed of ultramafic material have been emplaced into fissures within the brecciated carapace of the peridotites. These observations bear important constraints for the mode of emplacement of the lherzolite bodies. We infer that mantle exhumation may have occurred during Albian strike‐slip deformation linked to the rotation of Iberia along the proto‐North Pyrenean Fault.     

XMM‐Newton publication statistics

We assessed the scientific productivity of XMM‐Newton by examining XMM‐Newton publications and data usage statistics. We analyse 3272 refereed papers, published until the end of 2012, that directly use XMM‐Newton data. The SAO/NASA Astrophysics Data System (ADS) was used to provide additional information on each paper including the number of citations. For each paper, the XMM‐Newton observation identifiers and instruments used to provide the scientific results were determined. The identifiers were used to access the XMM‐Newton Science Archive (XSA) to provide detailed information on the observations themselves and on the original proposals. The information obtained from these sources was then combined to allow the scientific productivity of the mission to be assessed. Since around three years after the launch of XMM‐Newton there have been around 300 refereed papers per year that directly use XMM‐Newton data. After more than 13 years in operation, this rate shows no evidence that it is decreasing. Since 2002, around 100 scientists per year become lead authors for the first time on a refereed paper which directly uses XMM‐Newton data. Each refereed XMM‐Newton paper receives around four citations per year in the first few years with a long‐term citation rate of three citations per year, more than five years after publication. About half of the articles citing XMM‐Newton articles are not primarily X‐ray observational papers. The distribution of elapsed time between observations taken under the Guest Observer programme and first article peaks at 2 years with a possible second peak at 3.25 years. Observations taken under the Target of Opportunity programme are published significantly faster, after one year on average. The fraction of science time taken until the end of 2009 that has been used in at least one article is ∼90%. Most observations were used more than once, yielding on average a factor of two in usage on available observing time per year. About 20 % of all slew observations have been used in publications. The scientific productivity of XMM‐Newton measured by the publication rate, number of new authors and citation rate, remains extremely high with no evidence that it is decreasing after more than 13 years of operations.     

Note on the spatial distribution of old open clusters

Using the sample of 74 old open clusters compiled by Friel (1995) the increase of the mean distance from the galactic plane with cluster age has been determined. The result is in a qualitative agreement with the hypothesis of scattering of the clusters during encounters with massive molecular clouds and by spiral arms. (© 2003 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)