Mineralogical alteration and associated permeability changes induced by a high-pH plume: Modeling of a granite core infiltration experiment

Within the framework of the HPF project (Hyperalkaline Plume in Fractured Rock) at the Grimsel Test Site (Switzerland), a small scale core infiltration experiment was performed at the University of Bern. A high-pH solution was continuously injected, under a constant pressure gradient, into a cylindrical core of granite containing a fracture. This high-pH solution was a synthetic version of solutions characteristic of early stages in the degradation of cement. The interaction between the rock and the solutions was reflected by significant changes in the composition of the injected solution and a decrease in the permeability of the rock. Changes in the mineralogy and porosity of the fault gouge filling the fracture were only minor. One-dimensional reactive transport modeling, using a modified version of the GIMRT code, was used to interpret the results of the experiment. Dispersive and advective solute transport, mineral reaction kinetics and a coupling between porosity and permeability changes were taken into account. In order to obtain a reasonable agreement between models and experimental results, reactive surface areas of the order of 10⁵ m²/m³ rock had to be used. These values are much smaller than the values measured for the fault gouge filling the fracture, which are in the order of 10⁶–10⁷ m²/m³ rock. However, the results could be improved by adding a small fraction of fine grained mineral, which could explain the high initial peaks in Al and Si concentration. With the inclusion of this fine grained fraction, the initial surface areas in the model were within the range of the measured specific surface areas of the fault gouge. The fact that the decrease in permeability was significant despite the minor changes in mineralogy, suggests that permeability may be controlled by changes in the structure of the rock (pore geometries) rather than by only the bulk volumetric (porosity) changes.     

Microanalysis of nitrogen isotope abundances: association of nitrogen with noble gas carriers in Allende

Current research efforts to explore and account for the distribution of nitrogen isotope abundances in the ancient and present-day solar wind and in meteorites often require measurement of nitrogen abundances and isotopic compositions in very small samples of rare extraterrestrial materials. Isotopic analysis of ～ 1 μg of N₂ is possible with modern techniques of dynamic mass spectrometry, but even this high sensitivity is a limiting factor for certain critical samples. We have utilized a statistically operated mass spectrometer coupled to an ultrahigh vacuum gas extraction and processing system to lower this limit by approximately four orders of magnitude. Quantities of N₂ ranging from ～ 100 ng to < 100 pg are measurable with permil to percent precision in isotope ratios. Nitrogen and all noble gases evolved during stepwise combustion of fine-grained matrix material separated from the Allende meteorite have been meausred simultaneously in a pilot experiment using this technique. Isotopically heavy H-Xe (CCF-Xe) and isotopically light N are co-sited in a carbonaceous carrier phase, supporting a nucleosynthetic origin for¹⁵N-depleted nitrogen in Allende. The great isotopic uniformity of trapped Ar in all carrier phases indicates that simple, physical mass fractionation in gravitational escape of volatiles from the primitive nebula cannot have played a significant role in generating the nitrogen compositions observed in solar system matter.     

Coalescing neutron stars as gamma ray bursters?

We investigate the dynamics and evolution of coalescing neutron stars. The three-dimensional Newtonian equations of hydrodynamics are integrated by the Piecewise Parabolic Method on an equidistant Cartesian grid. The code is purely Newtonian, but does include the emission of gravitational waves and their back-reaction. The properties of neutron star matter are described by the equation of state of Lattimer and Swesty (1991). Energy loss by all types of neutrinos and changes of the electron fraction due to the emission of electron neutrinos and antineutrinos are taken into account by an elaborate neutrino leakage scheme. We simulate the coalescence of two identical, cool neutron stars with a baryonic mass of 1.6M and a radius of 15 km and with an initial center-to-center distance of 42 km. The initial distributions of density and electron concentration are given from a model of a cold neutron star in hydrostatic equilibrium. We investigate three cases which differ by the initial velocity distribution in the neutron stars. The orbit decays due to gravitational-wave emission and after one revolution the stars are so close that dynamical instability sets in. Within 1 ms the neutron stars merge into a rapidly spinning (P 1 ms), high-density body ( 10¹⁴ g/cm³) with a surrounding thick disk of material with densities 10¹⁰ – 10¹² g/cm³ and orbital velocities of 0.3-0.5 c. The peak emission of gravitational waves has a maximum luminosity of a few times 10⁵⁵ erg/s and is reached for about 1 ms. The amplitudes of the gravitational waves are close to 3 10^–23 at a distance of 1 Gpc and the typical frequency is near the dynamical value of the orbital motion of the merging neutron stars of 2 KHz. In a post-processing step, the rate of neutrino-antineutrino annihilation is calculated from the neutrino luminosities generated during the hydrodynamical simulations. We find the integral annihilation rate to be a few 10⁵⁰ erg/s during the phase of strongest neutrino emission, which is too small to generate the observed bursts considering the fact that the merged object of about 3M will most likely collapse to a black hole within milliseconds.     

Tripartite climate reversal in Central Europe 5600-5300 years ago

The history of variations in water level of Lake Constance, as reconstructed from sediment and pollen analysis of a sediment sequence from the archaeological site of Arbon-Bleiche 3, shows an abrupt rise in lake level dendrochronologically dated to 5375 yr ago (5320 yr relative to AD 1950). This event, paralleled by the destruction of the Neolithic village by fire, provoked the abandonment of this prehistoric lake-shore location established in the former shallow bay of Arbon-Bleiche, and was the last of a series of three episodes of successively higher lake level, the first occurring at 5600-5500 cal yr B.P. The dendrochronologically dated rise event was synchronous with an abrupt increase in atmospheric ¹⁴C. This supports the hypothesis of an abrupt climate change forced by varying solar activity. Moreover, the three successive episodes of higher lake level between 5600 and 5300 cal yr B.P. at Arbon-Bleiche 3 coincided with climatic cooling and/or changes in moisture conditions in various regions of both hemispheres. This period corresponds to the mid-Holocene climate transition (onset of the Neoglaciation) and suggests inter-hemispheric linkages for the climate variations recorded at Arbon-Bleiche 3. This mid-Holocene climate reversal may have resulted from complex interactions between changes in orbital forcing, ocean circulation and solar activity. Finally, despite different seasonal hydrological regimes, the similarities between lake-level records from Lake Constance and from Jurassian lakes over the mid-Holocene period point to time scale as a crucial factor in considering the possible impact of climate change on environments.     

Analysis of COMPTEL gamma-ray burst locations and spectra

In its first three years of operation, the COMPTEL instrument on theCompton Gamma-Ray Observatory has measured the locations (mean accuracy 1°) and spectra (0.75-30 MeV) of 18 gamma-ray bursts and continues to observe new events at a rate of 1/month. With good angular resolution and sensitivity at MeV energies, the growing COMPTEL burst catalog is an important new piece of evidence in the on-going GRB mystery. The COMPTEL burst locations are consistent with an isotropic distribution of sources, yet the spatial coincidence of two of the bursts indicates the possibility of repetition. The COMPTEL burst spectra are in most cases consistent with a single power law model with spectral index in the range 2–3. However, two bursts show evidence of a spectral break in the MeV range. Measurement of rapid variability at MeV energies in the stronger bursts provides evidence that either the sources are nearby (within the Galaxy) or the gamma-ray emission is relativistically beamed. We present an overview of analysis results obtained from the COMPTEL burst catalog concentrating on the search for burst repetition and the implications of highly variable MeV emission.     

High resolution regional climate model simulations for Germany: Part II—projected climate changes

The projected climate change signals of a five-member high resolution ensemble, based on two global climate models (GCMs: ECHAM5 and CCCma3) and two regional climate models (RCMs: CLM and WRF) are analysed in this paper (Part II of a two part paper). In Part I the performance of the models for the control period are presented. The RCMs use a two nest procedure over Europe and Germany with a final spatial resolution of 7 km to downscale the GCM simulations for the present (1971–2000) and future A1B scenario (2021–2050) time periods. The ensemble was extended by earlier simulations with the RCM REMO (driven by ECHAM5, two realisations) at a slightly coarser resolution. The climate change signals are evaluated and tested for significance for mean values and the seasonal cycles of temperature and precipitation, as well as for the intensity distribution of precipitation and the numbers of dry days and dry periods. All GCMs project a significant warming over Europe on seasonal and annual scales and the projected warming of the GCMs is retained in both nests of the RCMs, however, with added small variations. The mean warming over Germany of all ensemble members for the fine nest is in the range of 0.8 and 1.3 K with an average of 1.1 K. For mean annual precipitation the climate change signal varies in the range of ?2 to 9 % over Germany within the ensemble. Changes in the number of wet days are projected in the range of ±4 % on the annual scale for the future time period. For the probability distribution of precipitation intensity, a decrease of lower intensities and an increase of moderate and higher intensities is projected by most ensemble members. For the mean values, the results indicate that the projected temperature change signal is caused mainly by the GCM and its initial condition (realisation), with little impact from the RCM. For precipitation, in addition, the RCM affects the climate change signal significantly.