Long term and seasonal ground deformation monitoring of Larissa Plain (Central Greece) by persistent scattering interferometry

The land subsidence which occurs at the Larissa Basin (Thessaly Plain, Central Greece) is due to various causes including aquifer system compaction. Deformation maps of high spatial resolution deduced by the Persistent Scattering Interferometry (PSI) technique (using radar scenes from ERS and ENVISAT satellites) for the period 1992–2006 were produced to study the spatial and temporal ground deformation. A developed GIS database (including geological, tectonic, morphological, hydrological, meteorological and watertable variation from wells in the area) offered the possibility of studying in detail the intense subsidence. The PSI based average deformation image clearly shows that subsidence generally takes place inside the Larissa Plain ranging from 5–250 mm. The largest amplitude rates (?25 mm/yr) are observed around the urban area of Larissa City (especially at Gianouli and Nikea villages), while the Larissa City center appears to be relatively stable with a tendency to subside. The rest of the plain regions seem to subside at moderate rates (about 5–10 mm/yr). The surrounding mountainous area is stable, or has slightly been uplifted with respect to the NE located reference point. It was found that there is a correlation between the seasonal water-table variation (deduced from wells data), the seasonal water demand for irrigation associated with specific types of cultivation (cotton fields), the monthly rainfall, and the observed subsidence rate in the rural regions of the Thessaly Plain.     

Depth-profiles and surface enrichment of the halogens in four Antarctic H5 chondrites and in two non-Antarctic chondrites

Abstract— Depth-profiles of F, Cl, Br and I concentrations were determined in four different Antarctic H5 chondrites from the Allan Hills and in the two chondrites Allende (C3) and Holbrook (L6). Pieces of the meteorites were studied by analysis of stepwise removed layers of 0.5–1.0 mm thickness up to a depth of 9 mm. Neutron activation analysis and ion-selective potentiometry were used for the determination of Cl, Br, I and for F, respectively. The Antarctic meteorites show higher concentrations of the halogens at the surface compared to the interior. The highest enrichment factors are found for I and Cl and the lowest for Br. In contrast, F shows the steepest concentration gradient and is only enriched in the first 2.5 mm below the surface. The other halogens have penetrated deeper into the meteorites. The measured enrichments at the surfaces are not correlated to the visible degree of weathering. The analysed non-Antarctic meteorites, which were recovered shortly after their observed fall, demonstrate similar halogen concentrations at the surface, including the fusion crust, as in the interior. Based on these results we present a model to estimate the degree of contamination and the relation to the duration of exposure at the surface of the Antarctic ice.     

Weathering of ordinary chondrites from Oman: Correlation of weathering parameters with 14C terrestrial ages and a refined weathering scale

We have investigated 128 ¹⁴C‐dated ordinary chondrites from Oman for macroscopically visible weathering parameters, for thin section‐based weathering degrees, and for chemical weathering parameters as analyzed with handheld X‐ray fluorescence. These 128 ¹⁴C‐dated meteorites show an abundance maximum of terrestrial age at 19.9 ka, with a mean of 21.0 ka and a pronounced lack of samples between 0 and 10 ka. The weathering degree is evaluated in thin section using a refined weathering scale based on the current W0 to W6 classification of Wlotzka (1993), with five newly included intermediate steps resulting in a total of nine (formerly six) steps. We find significant correlations between terrestrial ages and several macroscopic weathering parameters. The correlation of various chemical parameters including Sr and Ba with terrestrial age is not very pronounced. The microscopic weathering degree of metal and sulfides with newly added intermediate steps shows the best correlation with ¹⁴C terrestrial ages, demonstrating the significance of the newly defined weathering steps. We demonstrate that the observed ¹⁴C terrestrial age distribution can be modeled from the abundance of meteorites with different weathering degrees, allowing the evaluation of an age‐frequency distribution for the whole meteorite population.     

格陵兰冰心中的矿物粉尘记录

矿物粉尘在当今气候研究中发挥着重要的作用。矿物粉尘气溶胶具有的发射性质使其直接影响着大气圈的辐射平衡。矿物粉尘也以多种间接方式积极参与了气候活动,其中包括成为云层凝聚中心来决定云盖层的规模和特征以及可能控制着遥远的营养贫瘠的大洋与大陆地区的原始生物生产力。     

Impact melt dikes in the Sudbury multi-ring basin (Canada): Implications from uranium-lead geochronology on the Foy Offset Dike

Abstract To investigate the origin of Offset Dikes and their age relationships to major impact generated lithologies in the Sudbury multi-ring impact structure, such as the Main Mass of the Sudbury “Igneous” Complex, zircon and baddeleyite were dated by the U-Pb chronometer. The rocks analysed are one diorite and two quartz diorites from inside the Foy Offset, one quartz diorite from the contact zone, and two country rock samples collected at 10 and 30 m distances from the contact within the Levack Gneiss Complex. The 21 analysed zircon and baddeleyite fractions yield a crystallization age of 1852 +4/-3 (2σ) Ma for the accessory minerals in the Foy Offset Dike and an age of 2635 ± 5 Ma for the shocked Levack country rock, in which zircons show significant shock effects (multiple sets of planar fractures), in contrast to the totally unshocked zircons of the Offset Dike. Within given errors, the new age of 1852 Ma is identical to the pooled 1850 ± 1 Ma U-Pb age determined by Krogh et al. (1984) as the crystallization age of accessory phases in different lithologies of the Sudbury “Igneous” Complex, which has been interpreted to represent the coherent impact melt sheet of the Sudbury Structure. This excellent agreement of the ages substantiates that emplacement of the Offset Dikes occurred coevally with the formation of the impact melt sheet. Total absence of inherited zircons in the central part of the Foy Offset indicates melting of the precursor material at temperatures well above 1700 °C, which emphasizes the origin of the dike lithologies by impact melting.     

Dating terrestrial impact events

Abstract— Systematic examination of dating results from various craters indicates that about 90% of the rocks affected by an impact preserve their pre-shock ages because shock and post-shock conditions are not sufficient to disturb isotopic dating systems. In the other 10% of target lithologies, various geochronometers show significant shock-induced effects. Major problems in dating impactites are caused by their non-equlibrated character. They often display complex textures, where differently shocked and unshocked phases interfinger on the sub-mm scale. Due to this, dating on whole rock samples or insufficiently pure mineral fractions often yielded ambiguous results that set broad age limits but are not sufficient to answer reliably questions such as a possible periodicity in cratering on Earth, or correlation of impact events with mass extinctions. Dating results from shock recovery experiments indicate that post-shock annealing plays the most important role in resetting isotopic clocks. Therefore, the major criterion for sample selection in and around craters is the post-shock thermal regime. Based on their different thermal evolution, the following geological impact formations can be distinguished: (1) the coherent impact melt layer, (2) allochthonous breccia deposits, (3) the crater basement, and (4) distant ejecta deposits. Samples of the coherent impact melt layer are the most suitable candidates for dating. Excellent ages of high precision can be obtained by internal Rb-Sr, and Sm-Nd isochrons, U-Pb analyses on newly crystallized accessory minerals, and K-Ar (³⁹Ar-⁴⁰Ar) dating of clast-free melt rocks. Fission track counting on glassy material has yielded correct ages, and paleomagnetic measurements have been successfully applied to post-Triassic craters. In the ideal case of a fast-cooling impact melt layer, all these different techniques should give identical ages. Allochthonous breccias contain shocked, unshocked, and/or glassy components in various proportions; and, hence, each of these ejecta deposits has its own individual thermal history, making sample evaluation difficult Glassy melt particles in suevitic breccias are well suited for fission track and Ar-Ar dating. Weakly shocked material may yield reliable Ar-Ar and fission track ages, if formation temperatures were high, and cooling rates moderate. In contrast, highly shocked but rapidly cooled lithologies show only disturbed and not reset isotopic systems. For ejecta deposits and the crater wall of young craters, dating with cosmogenic nuclides is a new and powerful technique. Crater basement lithologies have a high potential in impact dating, although it has not been exploited so far. A prerequisite for resetting of isotopic clocks in these lithologies is the presence of an overlaying impact melt layer, which causes thermal metamorphism. Fission track and K-Ar techniques are most promising, because both systems are easily reset at low temperatures. Good candidates for impact dating are long-term annealed rocks, even if shock metamorphic overprint is very weak. In addition, Ar-Ar dating dating of pseudotachylites appears promising. In large impact structures, where high temperatures persist for long times, polymict “footwall” breccias beneath the melt sheet are also appropriate for dating, using the isochron approach and U-Pb on accessory minerals. Distant ejecta material have undergone very fast cooling, and the ejecta deposits have ambient formation temperatures. Among this material, tektites and impact melt glass are ideal objects for Ar-Ar and fission track impact dating. Dating on other material from distant ejecta deposits, such as U-Pb analyses on zircons, offers new possibilities. Efforts to correlate distant ejecta with distinct craters critically depend on proper error assignment to a specific age. This aspect is illustrated on the K/T boundary example.     

The effect of initial230Th disequilibrium on young UPb ages: the Makalu case,Himalaya

Comparative UPb dating of zircon, xenotime and monazite from two different samples of the Himalayan “Makalu” granite shows the two U decay series to be in disequilibrium, particularly in monazite. This disequilibrium is due to excess or deficit amounts of radiogenic²⁰⁶Pb which originate from an excess or deficit of²³⁰Th, respectively, occurring initially in the mineral. Such an initial disequilibrium is caused by UTh fractionation between the crystallising mineral and the magma. Therefore, the UPb ages of Th-rich minerals such as monazite (and allanite) have to be corrected for excess²⁰⁶Pb due to excess²³⁰Th, whereas Th-poor minerals such as zircon and xenotime require a correction for a deficit of²⁰⁶Pb due to deficiency of²³⁰Th. The extent of this correction depends on the degree of ThU fractionation and on the age of the rock. For the two monazite populations analysed here, these excess amounts of²⁰⁶Pb were, with reference to the amount of radiogenic²⁰⁶Pb, 8–10% and 15–20% respectively, and less than 1% for zircon and xenotime. The varying degrees of Th enrichment relative to U in monazite show that the ThU partition coefficients for this mineral are not constant within a single granite. Furthermore, for monazite there is evidence for excess amounts of radiogenic²⁰⁷Pb originating from the decay of initial excess²³¹Pa, also enriched during crystal growth.The very low Th/U ratios of 0.196 and 0.167, determined for thetwo whole rocks from which the minerals have been extracted, substantiate the view that granite formation is a fundamental mechanism for ThU fractionation in continental crust.The different ages of 21.9 ± 0.2m.y. and24.0 ± 0.4m.y., obtained by averaging the corrected²³⁸U²⁰⁶Pb ages of the monazites, suggest that the apparently homogeneous Makalu granite was generated over a period of at least 2 m.y.     

The Palung granite (Himalaya); high-resolution UPb systematics in zircon and monazite

UPb analyses of fractions of zircon and monazite (3–8 grains each) and of single zircon grains resolve a lower Ordovician age of 470 ±4m.y. for the Palung granite which occurs in the High Himalayan nappes south of Kathmandu. Its thrusting during the Alpine orogeny under lower greenschist facies conditions did not affect the UPb systems in zircon and monazite. The granite crystallized from a magma which was mainly generated by anatexis of Precambrian continental crust. The magma was heterogeneous with respect to primary ages and/or metamorphic histories of the magma source rocks. This indicates either a derivation from (meta-) sediments or an intense mixing of different crustally derived magmas. The genesis of the Palung granite is possibly related to an orogeny which affected the Indian shield in lower Palaeozoic times. The detected inherited radiogenic lead in the Palung zircons occurs in perfectly homogeneous, transparent crystals; i.e. this radiogenic (“excess”) lead is not related to the presence of old, microscopically visible, overgrown zircon cores. The minimum ages of the inherited lead components range from about 800 to 1700 m.y.