The Vigny limestones: a record of Palaeocene (Danian) tectonic-sedimentary events in the Paris Basin

Danian marine sedimentation in the Paris Basin occurred between two major erosional phases. The earlier was responsible for the stripping of presumably deposited Maastrichtian sediments and of a variable thickness of Campanian chalk. The later occurred during the late Palaeocene and resulted in the erosion of almost all Danian deposits, which are now limited to small and scattered outcrops. One of these outcrops corresponds to reefal and peri‐reefal limestones of middle to late Danian age, exposed in the quarries of Vigny (NW of Paris). Danian deposits here show intricate relations with the surrounding Campanian chalk. Danian sedimentation was contemporaneous with faulting, which generated signifiant sea‐floor relief and resulted in contrasting depositional areas: topographic highs with coralgal reefs, and depressions where calcirudite channel fill accumulated. Normal faulting occurred along WNW–ESE master faults. The generation of submarine fault scarps gave rise to various types of gravity‐driven phenomena, including the sliding and slumping of large blocks of reefal limestone and the deposition of carbonate debris flows. Along with the redeposition of the Danian carbonates, flows of fluidized and reworked Campanian chalk resulted from the peculiar physical properties of the undercompacted chalks. Erosion and faulting occurred predominantly during the Palaeocene and represent a major episode in the physiographic evolution of the Paris Basin.     

Trace-element-rich brines in eclogitic veins: implications for fluid composition and transport during subduction

Primary and pseudosecondary fluid inclusions occur in oscillatory-and sector-zoned omphacite in eclogitic veins from the Monviso ophiolitic complex in the Western Alps. The inclusions contain aqueous brines and daughter crystals of halite, sylvite, calcite, dolomite, albite, anhydrite and/or gypsum, barite, baddeleyite, rutile, sphene, Fe oxides, pyrite and monazite. This daughter mineral suite indicates high solubilites of Na, K, Ca, Mg, Fe, Zr, Ti, P, Ba, Ce, La, Th, and S species and provides direct evidence for transport of high-fieldstrenght, large-ion-lithophile, and light-rare-earth elements as dissolved species during subduction. Fluid-inclusion heterogeneities preserved within and between adjacent grains in the veins, however, suggest that the scale of fluid equilibration was small. A crack-seal geometry in some of the veins implies that fluid release in pulses rather than steady flow controlled mineral deposition and growth in the veins. From these observations, we develop a model of fluid release and entrapment in which pulses of fluid are associated in time with increments of shear and tensile failure; the rate of fluid release and the reduction in porosity both depend on the rate of plastic flow. Vein fluids may initially be derived from decreptitation of early fluid inclusions in the host eclogites, Small-scale fluid heterogeneities implied by the fluid inclusions in the veins are best interpreted in terms of limited fluid flow, and hence limited metasomatism. We conclude that element recycling into the mantle wedge during subduction will depend at least as strongly on fluid transport mechanisms as on element solubilities in the fluid phase. At Monviso, despite evidence for high trace element solubilities in saline brines, the elements were not removed from the downgoing slab prior to teaching depths of 40 km.     

Measurement of natural stresses in a Provence mine (Southern France)

Stress measurements were carried out in the Arc syncline using drifs in a lignite mine. Eleven sites were investigated using the flat jack and hydraulic fracturing (or stimulating) methods. Two stress states were found to coexist, one isotropic, the other highly anisotropic. The orientations of the principal stresses are not homogeneous and an orientation ranging from E-W to NE-SW predominates locally. This does not accord with the regional stress field. The vertical stresses are systematically underestimated.     

应用各种示踪剂研究岩溶泉系统的补给边界

应用三种化学示踪剂,对桂林岩溶水文地质试验场“31号泉系统”的补给边界进行了研究。试验在雨期进行,示踪剂分别是降雨后投入落水洞随表层岩溶水带入地下;或在降雨前投入无水的落水洞中,待降雨后由地表产流带入地下。 试验表明,氯化锌、钼酸铵是较理想的示踪剂,地下水速度为4～250米/小时,速度差可能是由于包气带岩溶含水介质渗透性和水力坡度不同所致;泉口历时浓度曲线常呈多峰型,多是由于降雨脉冲影响所致;峰丛区高程不等的洼地多通道补给山边泉,峰丛区含水介质结构具有叠置性,即水平方向多通道,垂直方向多层次,故水均衡计算不可忽视;“31号泉系统”的补给边界,通过圈定有水力连系之洼地的地表分水岭来确定。      

Fluid composition and evolution in coesite-bearing rocks (Dora-Maira massif,Western Alps): implications for element recycling during subduction

Fluid inclusions and F, Cl concentration of hydrous minerals were analysed in the coesite-pyrope quartzite, the interlayered jadeite quartzite and their country-rock gneiss from the Dora-Maira massif using a combination of microthermometry, Raman spectrometry, synchrotron X-ray microfiuorescence and electron microprobe analysis. Three populations of fluid inclusions were recognized texturally and can be related to distinct metamorphic stages. A low-salinity aqueous fluid occurs in the retrogressed country gneiss and as late secondary inclusions in jadeite quartzite and chloritized pyrope. An earlier secondary population is found in matrix quartz of the jadeite- and pyro-pe-quartzites. This population can be related to the early decompression and so to incipient breakdown of garnet into phlogopite-bearing assemblages. The inclusion fluid is highly saline (up to 84 wt% equivalent NaCl) and contains Na, Ca, Fe, Cu and Zn as major cations. In pyrope quartzite, additional K was found in these brines, which locally coexist with CO₂-rich inclusions. The oldest fluid inclusions are preserved in kyanite grains included in fresh pyrope and in pyrope itself. In pyrope, all inclusions have decrepitated and contain magnesite, an Mg-phosphate, sheet-silicate(s), a chloride and an opaque phase, with no fluid preser ved. In contrast, the kyanite inclusions in pyrope preserve primary H₂O-CO₂ low-salinity fluid inclusions, probably owing to the low compressibility of the kyanite inclusions and host garnet. In spite of in-situ re-equilibration, these inclusions can be interpreted as relics of the dehydration fluid that attended pyrope growth. These correlations between textural and chemical fluid inclusion data and metamorphic stages are consistent with the fluid composition calculated from the halogen content of different generations of phlogopite and biotite. The preservation of different fluid compositions, both in time and space, is evidence for local control and possibly origin of the fluids, in agreement with isotopic data. These results, in particular the absence of CO₂ in the jadeite quartzite, are best interpreted in terms of a fluid-melt system evolution. With increasing metamorphism, partitioning of H₂O, Na, Ca, Fe and heavy metals into melt (jadeite quartzite) and Mg, Na/K, F, CO₂ and P(?) into a residual aqueous fluid can account for depletion in Na, Ca and Fe of the pyrope quartzite. During the retrograde path, a _{H 2 O} rose as melt crystallized, generating the two populations of hypersaline and water-rich fluids that were highly reactive to pyrope. The process of fluid-melt interaction envisioned here coupled with models of melt extraction in subduction zones provides an attractive opportunity for the instantaneous ( < 1 Ma) and selective transport of elements between a downgoing slab and the overlying mantle wedge.     

Speciation of naturally-accumulated uranium in an organic-rich soil of an alpine region (Switzerland)

Very high concentrations of uranium (up to 4000 ppm) were found in a natural soil in the Dischma valley, an alpine region in the Grisons canton in Switzerland. The goal of this study was to examine the redox state and the nature of uranium binding in the soil matrix in order to understand the accumulation mechanism. Pore water profiles collected from Dischma soil revealed the establishment of anoxic conditions with increasing soil depth. A combination of chemical extraction methods and spectroscopy was applied to characterize the redox state and binding environment of uranium in the soil. Bicarbonate extraction under anoxic conditions released most of the uranium indicating that uranium occurs predominantly in the hexavalent form. Surprisingly, the uranium redox state did not vary greatly as a function of depth. X-ray absorption near edge spectroscopy (XANES), confirmed that uranium was present as a mixture of U(VI) and U(IV) with U(VI) dominating. Sequential extractions of soil samples showed that the dissolution of solid organic matter resulted in the simultaneous release of the majority of the soil uranium content (>95%). Extended X-ray absorption fine structure (EXAFS) spectroscopy also revealed that soil-associated uranium in the soil matrix was mainly octahedrally coordinated, with an average of 1.7 axial (at about 1.76 Å) and 4.6 to 5.3 equatorial oxygen atoms (at about 2.36 Å) indicating the dominance of a uranyl-like (UO₂²⁺) structure presumably mixed with some U(IV). An additional EXAFS signal (at about 3.2 Å) identified in some spectra suggested that uranium was also bound (via an oxygen atom) to a light element such as carbon, phosphorus or silicon. Gamma spectrometric measurements of soil profiles failed to identify uranium long-life daughter products in the soil which is an indication that uranium originates elsewhere and was transported to its current location by water. Finally, it was found that the release of uranium from the soil was significantly promoted at very low pH values (pH 2) and increased with increasing pH values (between pH 5 and 9).     

An empirical approach to estimating population parameters from censored fracture-length distributions

Most fracture data sets are length-censored because of incomplete exposure at the surface, so estimating values of parameters of the sampled populations is difficult. Unless the form of the distribution function of the population is known, or one which is analytically tractable is assumed, length-censoring presents formidable problems in determining population parameters. Tests conducted on experimental fracture patterns developed in clay samples subjected to simple shear loading are the basis of a distribution-free way to estimate population parameters. Comparison of random samples of censored and uncensored fracture lengths shows that a useful, homogeneous data set consists of those cracks which lie entirely within the sampling area (two-ended cracks). The properties of this data set can be used to estimate the mean and variance of uncensored data. Estimates of the maximum fracture length of uncensored data, using the variance and maximum length of these two-ended cracks, show good agreement with measured values. Knowledge of the mean, variance, and maximum value of fracture-length populations are of interest in engineering and hydraulic studies, as well as in remote sensing studies of the Earth and other planets. Application of these results to data on rock masses are subject to the caveat that different crack-growth mechanisms in clay and rock may affect the accuracy of the calculations.     

La vallée d'Ys : un paléoréseau hydrographique immergé en baie de Douarnenez (Finistère,France)

Interpretation of the recent high-resolution survey, CANADOU 2000, in the Bay of Douarnenez (Finistère, France) allowed us to restore the morphology of the substratum and the sedimentary filling of the bay. The Brioverian and Palaeozoic substratum reveals a well-defined network of incised valleys as results of successive emergence stages of the Bay during the Quaternary. Valleys join in a westward-widened mean valley, called Ys Valley. The present-day sedimentary fill of the bay of Douarnenez appears mainly controlled by the Holocene rise and the consecutive highstand. It comprises fluvial and estuarine deposits filling up incised valleys and marine sedimentation extending out of the incised valleys. To cite this article: G. Jouet et al., C. R. Geoscience 335 (2003).To cite this article: G. Jouet et al., C. R. Geoscience 335 (2003).     

Southern Hemisphere extra-tropical forcing: a new paradigm for El Ni?o-Southern Oscillation

The main goal of this paper is to shed additional light on the reciprocal dynamical linkages between mid-latitude Southern Hemisphere climate and the El Ni?o-Southern Oscillation (ENSO) signal. While our analysis confirms that ENSO is a dominant source of interannual variability in the Southern Hemisphere, it is also suggested here that subtropical dipole variability in both the Southern Indian and Atlantic Oceans triggered by Southern Hemisphere mid-latitude variability may also provide a controlling influence on ENSO in the equatorial Pacific. This subtropical forcing operates through various coupled air?Csea feedbacks involving the propagation of subtropical sea surface temperature (SST) anomalies into the deep tropics of the Atlantic and Indian Oceans from boreal winter to boreal spring and a subsequent dynamical atmospheric response to these SST anomalies linking the three tropical basins at the beginning of the boreal spring. This atmospheric response is characterized by a significant weakening of the equatorial Atlantic and Indian Inter-Tropical Convergence Zone (ITCZ). This weakened ITCZ forces an equatorial ??cold Kelvin wave?? response in the middle to upper troposphere that extends eastward from the heat sink regions into the western Pacific. By modulating the vertical temperature gradient and the stability of the atmosphere over the equatorial western Pacific Ocean, this Kelvin wave response promotes persistent zonal wind and convective anomalies over the western equatorial Pacific, which may trigger El Ni?o onset at the end of the boreal winter. These different processes explain why South Atlantic and Indian subtropical dipole time series indices are highly significant precursors of the Ni?o34 SST index several months in advance before the El Ni?o onset in the equatorial Pacific. This study illustrates that the atmospheric internal variability in the mid-latitudes of the Southern Hemisphere may significantly influence ENSO variability. However, this surprising relationship is observed only during recent decades, after the so-called 1976/1977 climate regime shift, suggesting a possible linkage with global warming or decadal fluctuations of the climate system.     

Impacts of warm and cold situations in the Mediterranean basins on the West African monsoon: observed connection patterns (1979–2006) and climate simulations

Using both empirical and numerical ensemble approaches this study focuses on the Mediterranean/West African relationship in northern summer. Statistical analyses utilize skin temperature, sea surface temperature, in situ and satellite rainfall, outgoing longwave radiation (OLR) observations and reanalyzed data winds and specific humidity on isobaric surfaces. Numerical investigations are based on a large set of sensitivity experiments performed on four atmospheric general circulation models (AGCM): ARPEGE-Climat3, ECHAM4, LMDZ4 and UCLA7.3. Model outputs are compared to observations, discussed model by model and with an ensemble (multi-model) approach. As in previous studies the anomalous Mediterranean warm events are associated with specific impacts over the African monsoon region, i.e., a more intense monsoon, enhanced flux convergence and ascendances around the ITCZ, a strengthening of low level moisture advection and a more northward location of ascending motion in West Africa. The results show also new features (1) thermal variability observed in the two Mediterranean basins has unalike impacts, i.e. the western Mediterranean covaries with convection in Gulf of Guinea, while the eastern Mediterranean can be interpreted as Sahelian thermal-forcing; (2) although observations show symmetry between warming and cooling, modelling evidences only support the eastern warming influence; (3) anomalous East warm situations are associated with a more northward migration of the monsoon system accompanied by enhanced southwertely flow and weakened northeasterly climatological wind; (4) the multi-model response shows that anomalous East warm surface temperatures generate an enhancement of the overturning circulation in low and high levels, an increase in TEJ (Tropical Eeasterly Jet) and a decrease in AEJ (African Eeasterly Jet).