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91.
Thomas Ulrich Balz S. Kamber Jon D. Woodhead Lizzy A. Spencer 《Geostandards and Geoanalytical Research》2010,34(2):161-174
High precision isotope ratio and trace element determination can be achieved with modern quadrupole ICP-MS provided that short and long-term instrument performance is accurately monitored. Here we present results for the isotope ratios 6Li/7Li, 147Sm/149Sm, 160Dy/161Dy, 207Pb/206Pb, 208Pb/206Pb, 206Pb/204Pb and 235U/238U with which we determined long-term isotope ratio stability of relevance to both trace element and isotope determination. With respect to trace element determination, we first present long-term observations regarding oxide formation rates of Ba and Nd on light REE and heavy REE, as well as Zr on Ag. These showed good correlations and could be used to correct effectively the interference. The efficacy of this correction was demonstrated with analyses of the rock reference material BHVO-2 at both low and high oxide formation rates. Next, we studied the long-term reproducibility of a Dy isotope ratio that was measured to correct for the isobaric interference on Gd. It was found that, regardless of tuning condition, the ratio reproduced very well (0.58% RSD, 1s) and that the estimate of the Gd concentration did not suffer from the large correction (> 10%) caused by the Dy isobar. Long-term reproducibilities of Li, Sm and U isotope ratios, required for accurate mass bias correction when isotopically enriched internal standards of these elements are employed, were measured in the rock reference materials AGV-2 and JA-3 over a time period of up to 3 years. As expected, the Li isotope ratio showed the largest variability (RSD = 7%), but the other two ratios had relative external reproducibilities of only 1.01% (1s, U) and 0.67% (Sm). The mass bias-induced scatter in measurements for Sm and U was so small that the internal standard correction was effective, even for samples with high concentrations of these elements. With regard to Pb-isotope ratio determination, we also present long-term reproducibility for NIST SRM 982, run as an unknown and two accuracy tests for Pb separated from granitoids and from meteorites. It is demonstrated that the obtained ratios, including those involving 204Pb, are accurate relative to MC-ICP-MS determinations and of comparable precision to conventional TIMS analysis. The excellent agreement between all data sets shows the potential of modern quadrupole ICP-MS instrumentation for Pb-isotope determination, particularly for samples with very low Pb content. 相似文献
92.
Fragility curves for masonry structures submitted to permanent ground displacements and earthquakes 总被引:1,自引:1,他引:0
Usually, the vulnerability of structures is treated considering only one single hazard, for example either seismic hazard or ground instability. However, historical monuments, cultural heritage structures or old masonry structures can be affected, over the past centuries of existence, by a succession of different hazards. The objective of this paper was to quantify the changes in the seismic vulnerability of a given structure previously damaged by quasi-static differential settlements. In view of this, a soil-structure model of the masonry building is constructed using TREMURI software by putting springs at the base of the building to account for the soil behaviour. Classical empirical relationships are used for setting the mechanical properties of these foundation springs. The chosen equations are valid for both static and dynamic situations. The soil-structure model is first submitted to differential settlements with maximum magnitudes ranging from 5 to 25 cm. Then, the damaged structures are submitted to a set of time-histories. Fragility curves taking into consideration permanent differential settlements are finally obtained, using a modified regression technique accounting for the presence of residual drift due to the prior static loading. 相似文献
93.
The carbonate carbon isotope record of the Phanerozoic is marked by repeated high-amplitude excursions towards more positive values. Although the interpretation of C-isotope events remains controversial, they are regarded as a proxy of the global C-cycle. Using δ13 COrg -measurements of samples from DSDP Site 416, it is shown that a classic example of platform drowning coincided with the onset of the mid-Valanginian carbon-cycle excursion. Widespread carbonate platform drowning would have contributed to the observed positive shift in the C-isotope record. As choking of carbonate production was compensated by increased organic production, both processes favoured a shift in marine carbon partitioning from the oxidized to the reduced carbon reservoir. This would have resulted in an increased flux of CO2 from the atmosphere into the marine and sedimentary carbon reservoir. 相似文献
94.
Roger K. Ulrich Larry Webster John E. Boyden Nick Magnone Richard S. Bogart 《Solar physics》1991,135(2):211-241
We describe enhancements to the hardware and software for the 150-foot tower system on Mt. Wilson which make possible the acquisition of high precision line profile measurements. This system utilizes the 75-foot pit spectrograph with a photomultiplier detector system to scan line profiles repeatedly in order to study variations induced by the passage of waves vertically through the solar atmosphere. Oscillations of line profile parameters with an amplitude as low as 1.7 m s–1 have been detected with this system using integrated sunlight. Phase relations between oscillations of different parts of the line profile are appropriate to upward energy transport. Consistent with the previous conclusion by Mein and Schmieder (1981), we find that the magnitude of the energy transport is compatible with the 5-min oscillations making an important contribution to the heating of the low chromosphere.The Mount Wilson Observatory is operated by the Mount Wilson Institute under agreement with the Carnegie Institution of Washington. 相似文献
95.
Time variable Earth’s gravity field from SLR satellites 总被引:4,自引:4,他引:0
96.
97.
P. Riley M. Ben-Nun J. A. Linker Z. Mikic L. Svalgaard J. Harvey L. Bertello T. Hoeksema Y. Liu R. Ulrich 《Solar physics》2014,289(3):769-792
The observed photospheric magnetic field is a crucial parameter for understanding a range of fundamental solar and heliospheric phenomena. Synoptic maps, in particular, which are derived from the observed line-of-sight photospheric magnetic field and built up over a period of 27 days, are the main driver for global numerical models of the solar corona and inner heliosphere. Yet, in spite of 60 years of measurements, quantitative estimates remain elusive. In this study, we compare maps from seven solar observatories (Stanford/WSO, NSO/KPVT, NSO/SOLIS, NSO/GONG, SOHO/MDI, UCLA/MWO, and SDO /HMI) to identify consistencies and differences among them. We find that while there is a general qualitative consensus, there are also some significant differences. We compute conversion factors that relate measurements made by one observatory to another using both synoptic map pixel-by-pixel and histogram-equating techniques, and we also estimate the correlation between datasets. For example, Wilcox Solar Observatory (WSO) synoptic maps must be multiplied by a factor of 3?–?4 to match Mount Wilson Observatory (MWO) estimates. Additionally, we find no evidence that the MWO saturation correction factor should be applied to WSO data, as has been done in previous studies. Finally, we explore the relationship between these datasets over more than a solar cycle, demonstrating that, with a few notable exceptions, the conversion factors remain relatively constant. While our study was able to quantitatively describe the relationship between the datasets, it did not uncover any obvious “ground truth.” We offer several suggestions for how this may be addressed in the future. 相似文献
98.
99.
Ulrich Riller 《Meteoritics & planetary science》2005,40(11):1723-1740
Abstract— Orogenic deformation, both preceding and following the impact event at Sudbury, strongly hinders a straightforward assessment of impact‐induced geological processes that generated the Sudbury impact structure. Central to understanding these processes is the state of strain of the Sudbury Igneous Complex, the solidified impact melt sheet, its underlying target rocks, overlying impact breccias and post‐impact sedimentary rocks. This review addresses (1) major structural, metamorphic and magmatic characteristics of the impact melt sheet and associated dikes, (2) attempts that have been made to constrain the primary geometry of the igneous complex, (3) modes of impact‐induced deformation as well as (4) mechanisms of pre‐ and post‐impact orogenic deformation. The latter have important consequences for estimating parameters such as magnitude of structural uplift, tilting of pre‐impact (Huronian) strata and displacement on major discontinuities which, collectively, have not yet been considered in impact models. In this regard, a mechanism for the emplacement of Offset Dikes is suggested, that accounts for the geometry of the dikes and magmatic characteristics, as well as the occurrence of sulfides in the dikes. Moreover, re‐interpretation of published paleomagnetic data suggests that orogenic folding of the solidified melt sheet commenced shortly after the impact. Uncertainties still exist as to whether the Sudbury impact structure was a peak‐ring or a multi‐ring basin and the deformation mechanisms of rock flow during transient cavity formation and crater modification. 相似文献
100.
David E. Lange Kent Frost Paul P. Sipiera Carleton B. Moore 《Meteoritics & planetary science》1974,9(4):271-280
The Canyonlands meteorite weighing 1,520 grams was found near the confluence of the Green and Colorado Rivers, Utah, near lat 38°11′N.; long 109°53′W. It is a shocked, brecciated H6 chondrite containing large black veins which do not differ in composition from the main chondritic mass. A black fusion crust remains on part of the meteorite. 相似文献