Variability of petroleum inclusions in vein, fossil and vug cements—a geochemical study in the Barrandian Basin (Lower Palaeozoic, Czech Republic)

Although no commercial oil or gas occurrences have been found in the Barrandian Basin, residual oils and petroleum inclusions give evidence about the petroleum history of this Lower Palaeozoic Basin. Petroleum inclusions are hosted in six generations of calcite and quartz cements that can be attributed to different stages of a basinal cycle and associated diagenetic events. They were analysed using an on-line crushing and an off-line crush-and-leach approach. Five different groups (PI-A to PI-E) and intermediate mixtures (PI-M) could be differentiated based on the relative distribution of n-alkanes. All oils had a calculated aromatic maturity R_c ranging between 0.9 and 1.6%. PI-A shows a molecular weight maximum in the range of n-C_8–11 with a constant attenuation towards higher carbon numbered n-alkanes. This distribution is interpreted as the pristine precursor oil for other petroleum inclusion groups. PI-B has a maximum weight abundance at n-C_15–20. The genetic relationship between PI-B and PI-A can tentatively be explained by mixing effects or by gas stripping. PI-C is bimodal and characterised by a molecular weight maximum at n-C_32–34, and also a molecular weight maximum at n-C_15–20 similar to that of group PI-B. PI-D shows a normally distributed molecular weight maximum in the range n-C_25–28 and is interpreted as a wax precipitate from ascending gas saturated in n-alkanes. PI-E contains predominantly gaseous compounds with only a few higher hydrocarbons. Thompson's aromaticity values are elevated for condensates of group PI-E, and also for group PI-C that is dominated by long-chained n-alkanes. This gives evidence that fault-bound petroleum migration in the Barrandian Basin was associated with evaporative fractionation for group PI-C and PI-E. Samples of group PI-E yielded gas-range compounds only, and all come from a last generation of vein-filling whitish calcite that was formed in a late uplift phase of the basin. For other petroleum inclusion groups, only a vague preferential occurrence in specific mineralisation phases or stratigraphic intervals of the host rock has been found. This reflects the predominance of fracture-bound migration in the Barrandian Basin. Aromatic maturity values also showed no correlation between either crystal type or PI-group. In six of the investigated petroleum inclusion samples alk-1-enes are present. These terminal olefins are interpreted to be the result of the natural pyrolysis of petroleum due to the intrusion of volcanic dykes or hydrothermal processes. An artificial generation of olefins during sample work-up and analysis is unlikely. The preservation of alk-1-enes from Palaeozoic times was possible due to the protecting environment of petroleum inclusions.     

Geochronology and geochemistry of a dyke–host rock association and implications for the formation of the Bavarian Pfahl shear zone, Bohemian Massif

To place constraints on the formation and deformation history of the major Variscan shear zone in the Bavarian Forest, Bavarian Pfahl zone, SW Bohemian Massif, granitic dykes and their feldspar-phyric massive host rock (so-called palite), zircons were dated by the U–Pb isotope dilution and Pb-evaporation methods. The dated samples comprise two host rocks and four dykes from a K-rich calc-alkaline complex adjoining the SW part of the Bavarian Pfahl shear zone. The palites, which appear to be the oldest magmatic rocks emplaced in the shear zone, yield ages of 334±3, 334.5±1.1 Ma (average ²⁰⁷Pb/²⁰⁶Pb-evaporation zircon ages) and 327–342 Ma (range of U/Pb zircon ages) suggesting a Lower Carboniferous age for the initiation of the Pfahl zone. Absence of inherited older cores in all investigated zircons indicates that incorporation of crustal zircon material has played virtually no role or that the melting temperature was very high. Determination of the dyke emplacement age is complicated by partial Pb-loss in most of the fractions analysed. This Pb-loss can be ascribed to higher U content of the dyke zircons compared to those from host rock. Upper discordia intercept ages of the different dykes range from 322±5 to 331±9 Ma. The dykes are pre- to synkinematic with respect to penetrative regional mylonitisation along the Pfahl zone, and the upper intercept ages provide a maximum age for this tectonic event.     

The Negra Muerta Volcanic Complex, southern Central Andes: geochemical characteristics and magmatic evolution of an episodically active volcanic centre

This petrologic analysis of the Negra Muerta Volcanic Complex (NMVC) contributes to understanding the magmatic evolution of eruptive centres associated with prominent NW-striking fault zones in the southern Central Andes. Specifically, the geochemical characteristics and magmatic evolution of the two eruptive episodes of this Complex are analysed. The first one occurred as an explosive eruption at 9 Ma and is represented by a strongly welded, fiamme-rich, andesitic to dacitic ignimbrite deposit. The second commenced with an eruption of a rhyolitic ignimbrite at 7.6 Ma followed by effusive discharge of hybrid lavas at 7.3 Ma and by emplacement of andesitic to rhyodacitic dykes and domes. Both explosive and effusive eruptions of the second episode occurred within a short time span, but geochemical interpretations permit consideration of the existence of different magmas interacting in the same magma chamber. Our model involves an andesitic recharge into a partially cooled rhyolitic magma chamber, pressurising the magmatic system and triggering explosive eruption of rhyolitic magma. Chemical or mechanical evidence for interaction between the rhyolitic and andesitic magma in the initial stages are not obvious because of their difference in composition, which could have been strong enough to inhibit the interaction between the two magmas. After the initial explosive stages of the eruption at 7.6 Ma, the magma chamber become more depressurised and the most mafic magma settled in compositional layers by fractional crystallisation. Restricted hybridisation occurred and was effective between adjacent and thermally equivalent layers close to the top of the magma chamber. At 7.3 Ma, increments of caldera formation were accompanied by effusive discharge of hybrid lavas through radially disposed dykes whereby andesitic magma gained in importance toward the end of this effusive episode in the central portion of the caldera. Assimilation during turbulent ascent (ATA) is invoked to explain a conspicuous reversed isotopic signature (⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd) in the entire volcanic series. Therefore, the 7.6 to 7.3 Ma volcanic rocks of the NMVC resulted from synchronous and mutually interacting petrological processes such as recharge, fractional crystallization, hybridisation, and Assimilation during Turbulent Ascent (ATA).Geochemical characteristics of both volcanic episodes show diverse type and/or depth in the sources and variable influence of upper crustal processes, and indicate a recurrence in the magma-forming conditions. Similarly, other minor volcanic centres in the transversal volcanic belts of the Central Andes repeated their geochemical signatures throughout the Miocene.     

苏鲁超高压变质岩的构造热历史：中国大陆科学钻探工程(CCSD)主孔（MH）和先导孔（PP2）的磷灰石裂变径迹约束

本文包括中国大陆科学钻（CCSD）主孔（MH）0~5000m和先导孔（PP2）0~1000m的磷灰石裂变径迹分折结果,先导孔PP2的裂变径迹表观年龄变化范围为79.5±5.1~50.4±6.2Ma,主孔的裂变径迹表观年龄变化范围为98.6±17.0~2.9±2.0Ma,主孔在4200m以下,磷灰石样品中实际上已不存在自发裂变径迹,表明裂变径迹时钟已经“置零”。实验资料表明,裂变径迹表观年龄值随样品深度的增加而逐渐减少,直到一定深度,即达到磷灰石的裂变径迹封闭温度（~120℃）以后,年龄值为零。根据主孔0~2000m和先导孔0~1000m的裂变径迹年龄剖面,作为一级近似,计算出超高压变质岩体在90~30Ma期间,平均隆升速度为~35m/Ma。对主孔测定了9个样品的约束径迹（Confined track）长度,样品约束径迹平均长度的变化范围约为13.1~7.4μm,总的变化趋势是：约束径迹平均长度随样品深度的增加而逐渐减少。样品的约束径迹长度分布都具有双峰型特征。根据裂变径迹年龄和约束径迹长度的资料,应用计算机模拟得到了样品的时间-温度（t-T）轨迹。结果表明,岩体从早白垩世（~120Ma）快速冷却以后,在晚白垩世和始新世又经历了两次加热作用,始新世末岩体所达到的温度大约是80℃,随后岩体则一直上升和缓慢冷却到现今所处的位置。在最后~30Ma岩体的平均隆升速度为~53m/Ma。     

New Relationship for Estimation of Wave Overtopping on Vertical Walls

Soft computing tools in the form of combination of multiple nonlinear regression and M5'' model tree were used for estimation of overtopping rate at the vertical coastal structures. For reliable and precise estimation of overtopping rate, the experimental data available in the database CLASH were used. The dimensionless overtopping rate was estimated in terms of conventional dimensionless parameters including the relative crest freeboard R_c/H_s, seabed slope tanθ, deep water wave steepness S_om, surf similarity ξ_om and local relative water depth h_t/H_s. The accuracy of the new model was compared with other existing models and also evaluated with some field measurements. The results indicated that the model presented in this paper is more accurate than other existing models. With statistical parameters, it is shown that the accuracy of predictions in the new model is better than that of other models.     

Tri-Phonic Helioseismology: Comparison of Solar p Modes Observed by the Helioseismology Instruments Aboard SOHO

The three helioseismology instruments aboard SOHO observe solar p modes in velocity (GOLF and MDI) and in intensity (VIRGO and MDI). Time series of two months duration are compared and confirm that the instruments indeed observe the same Sun to a high degree of precision. Power spectra of 108 days are compared showing systematic differences between mode frequencies measured in intensity and in velocity. Data coverage exceeds 97% for all the instruments during this interval. The weighted mean differences (V-I) are −0.1 μHz for l=0, and −0.16 μHz for l=1. The source of this systematic difference may be due to an asymmetry effect that is stronger for modes seen in intensity. Wavelet analysis is also used to compare the shape of the forcing functions. In these data sets nearly all of the variations in mode amplitude are of solar origin. Some implications for structure inversions are discussed.     

Die Matrix der Fische IX. Beiträge zur Kenntnis des Vitamingehaltes von Forellenmuskelfleisch

Summary The vitamin content of muscles of about 2^1/2 years old rainbow trouts (Salmo irideus) has been estimated microbiologically. The trouts were artificially cultivated from fry and exclusively nourished with fresh beef liver. Vitamin B₁, B₂, pp, pantothenic acid, B₆, biotin, folic acid and B₁₂ have been considered.

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8. Mitteilung siehe diese Zeitschrift, S. 99.     

Carrington Coordinates and Solar Maps

Solar synoptic charts are normally displayed using Carrington Coordinates with each Carrington rotation being centered at a Carrington longitude of 180^° and with a full 360^° of solar surface properties included. For the case of reproducing solar magnetic fields in the corona and heliosphere, these maps are wrapped onto the solar surface to provide the boundary conditions for a solution to a set of modeling equations such as the potential field theory equations. Due to differential rotation, the full solar surface cannot be reproduced in this fashion since different parts of the solar surface are observed at different times. We describe here the proper technique for combining observations of the solar magnetic or velocity fields made at different times into a representation of the whole solar surface at a particular specified time that we refer to as a “snapshot heliographic map“.