Search for extinct Cl: Vigarano CAIs, the Pink Angel from Allende, and a Ningqiang chondrule

We have searched for excesses of ³⁶S derived from the decay of extinct ³⁶Cl in sodalite, a secondary Cl-rich mineral, in Ca-Al-rich inclusions (CAIs) from the Vigarano and Allende CV3 chondrites and in a chondrule from the Ningqiang carbonaceous chondrite. The presence of sodalite in two CAIs from Vigarano and its absence from surrounding CAI fragments suggests sodalite formation after CAI fragmentation. As for sodalite in the Allende Pink Angel CAI, oxygen isotopic compositions have been interpreted as indicative of high temperature interactions, thus suggesting formation prior to accretion to the parent body, probably in a nebular setting. Sodalite in the Ningqiang chondrule is considered to have formed via alkali-Ca exchange, which is believed to have occurred before accretion to the parent body.Sodalites in the Vigarano CAIs and in the Ningqiang chondrule show no clear evidence for the presence of radiogenic ³⁶S. The inferred 2σ upper limits for ³⁶Cl/³⁵Cl at the time of sodalite formation are 1.6 × 10⁻⁶ (Vigarano CAIs) and 3.3 × 10⁻⁶ (Ningqiang chondrule), respectively. In the Pink Angel CAI sodalite exhibits small ³⁶S excesses which weakly correlate with ³⁵Cl/³⁴S ratios. The inferred ³⁶Cl/³⁵Cl ratio of (1.8 ± 2.2) × 10⁻⁶ (2σ error) is lower than that found by Hsu et al. [Hsu, W., Guan, Y., Leshin, L. A., Ushikubo, T. and Wasserburg, G. J. (2006) A late episode of irradiation in the early solar system: Evidence from extinct ³⁶Cl and ²⁶Al in meteorites. Astrophys. J. 640, 525-529], thus indicative of heterogeneous distribution of ³⁶Cl in this CAI. Spallation reactions induced by energetic particles from the young Sun are suggested for the origin of ³⁶Cl, similar to the case of ¹⁰Be. While ¹⁰Be appears to be present in roughly equal abundance in all studied CAIs, our study indicates the level of ³⁶Cl abundances to be variable so that there seems to be no simple relationship between ¹⁰Be and ³⁶Cl. This would be expected if trapped cosmic rays rather than Early Solar System spallation were the dominant source of ¹⁰Be in the Early Solar System, since their contribution to ³⁶Cl would have been tiny.If the variability of ³⁶Cl abundances is caused by temporal differences in the alteration that formed sodalite, sodalite in the Vigarano CAIs and in the Ningqiang chondrule may have formed ?0.5 and ?0.2 Ma after formation of the sodalite in the Ningqiang CAI analyzed by Lin et al. [Lin, Y., Guan, Y., Leshin, L. A., Ouyang, Z. and Wang, D. (2005) Short-lived chlorine-36 in a Ca- and Al-rich inclusion from the Ningqiang carbonaceous chondrite. Proc. Natl. Acad. Sci. USA 102, 1306-1311]. The Pink Angel sodalite that we analyzed may have formed ∼0.3 Ma after formation of the sodalite in the Pink Angel analyzed by Hsu et al. [Hsu, W., Guan, Y., Leshin, L. A., Ushikubo, T. and Wasserburg G. J. (2006) A late episode of irradiation in the early solar system: Evidence from extinct ³⁶Cl and ²⁶Al in meteorites. Astrophys. J. 640, 525-529]. The estimated temporal differences suggest that alteration extended over at least 0.5 Ma. If previous works showing very low initial ³⁶Cl/³⁵Cl in the Allende CAIs and a H3 chondrite CAI are also considered, then alteration processes may have been more than 1.7 Ma.     

The thermal comfort and its changes in the 31 provincial capital cities of mainland China in the past 30 years

Theoretical and Applied Climatology - The thermal comfort and its changes in the 31 provincial capital cities of mainland China in the past 30 years were comprehensively evaluated using...     

Westerly jet stream and past millennium climate change in Arid Central Asia simulated by COSMO-CLM model

This study tackles one of the most debated questions around the evolution of Central Asian climate: the “Puzzle” of moisture changes in Arid Central Asia (ACA) throughout the past millennium. A state-of-the-art Regional Climate Model (RCM) is subsequently employed to investigate four different 31-year time slices of extreme dry and wet spells, chosen according to changes in the driving data, in order to analyse the spatio-temporal evolution of the moisture variability in two different climatological epochs: Medieval Climate Anomaly (MCA) and Little Ice Age (LIA). There is a clear regime behavior and bimodality in the westerly Jet phase space throughout the past millennium in ACA. The results indicate that the regime changes during LIA show a moist ACA and a dry East China. During the MCA, the Kazakhstan region shows a stronger response to the westerly jet equatorward shift than during the LIA. The out-of-phase pattern of moisture changes between India and ACA exists during both the LIA and the MCA. However, the pattern is more pronounced during the LIA.     

Binary evolution with relativistic jets

Relativistic jets can extract mass–energy from a black hole. In semi-detached black hole binaries the jet ejection process constitutes a ‘consequential angular momentum loss' (CAML) process. The effect of this jet-induced CAML is to lower the transfer rate below the value set by systemic driving and to stabilize otherwise unstable systems. Implications of jet-induced CAML for GRO J1655−40 are discussed.     

Hydrogen peroxide production rates in clean and polluted coastal marine waters of the Mediterranean, Red and Baltic Seas

The main aim of this study was to assess the hydrogen peroxide (HP) production rates (HPPR) related to anthropogenic pollution in coastal waters by laboratory and field experiments. HPPR's were assessed by simultaneous measurements of HP concentrations, cumulative solar UV irradiation and dissolved organic matter (DOM) fluorescence in the seawater samples at clean and polluted sites in the Mediterranean, Red and the Baltic Seas. The natural HP concentrations at all sites (8–100 nM) fall within the normal range recorded elsewhere, and follows a diurnal pattern. The polluted stations in the Mediterranean and Baltic Seas showed higher HPPR (3.2–16.6 nM m² W⁻¹ h⁻¹) than the clean stations, while in the Red Sea no significant differences were found because the station that was considered a priori polluted was actually rather clean (2–3 nM m² W⁻¹ h⁻¹). Laboratory experiments demonstrated that HPPR was positively linearly correlated to DOM fluorescence, however, this relationship was not found in the natural seawater samples examined in the field. The lack of relationship between HPPR and DOM in the field was attributed to enzymatic breakdown of HP as observed in dark decay experiments. HP dark decay rates were highest in polluted stations, probably due to larger bacterioplankton populations in these samples. Moreover, the HP dark decay rates were much lower in filtered than in non-filtered samples. Sun incubation of filtered (0.2 μm) seawater samples were performed to assess whether elimination of particles would yield higher HPPRs than in non-filtered samples. In the Baltic Sea (low UV irradiation) HPPR was higher in the filtered samples, while at sites with relatively high UV irradiation (Mediterranean and Red Seas), filtration of seawater did not stimulate HPPRs, probably due to UV-damage to planktonic microorganisms.     

Die EG‐Wasserrahmenrichtlinie: Ausweisung und Bewertung künstlicher und erheblich veränderter Gewässer

Designation and Assessment of Artificial and Heavily Modified Water Bodies under the EC Water Framework Directive The EC Water Framework Directive allows the Member States to designate artificial and heavily modified water bodies under specific conditions. For those water bodies the ecological assessment and the resulting programmes of measures will be based on the “maximum ecological potential” as reference conditions and not on the “high ecological status”, which has to be used for natural water bodies. Such designation is possible only, if the hydromorphology of the water bodies concerned has been substantially changed in character to maintain specified uses. The criteria for the designation are fulfilled, if restoration measures needed to meet the high ecological status would have significant adverse effects on the uses and if no other better environmental options would exist to maintain the specified uses. In late 1999 the EC‐Working Group on Heavily Modified Water Bodies (HMWB) has been established to develop criteria for the designation of artificial and heavily modified water bodies as well as for the determination of the maximum ecological potential. The working group has produced the guidance document “Identification and Designation of Artificial and Heavily Modified Water Bodies” in November 2002, which has been agreed by the European Water Directors on 21 November 2002 in Copenhagen. The guidance document is focusing on two time borders, the provisional identification of heavily modified water bodies until 2004 and the legally binding designation as artificial and heavily modified in the first river basin management plan in 2009 at the latest. The guidance document considered the main findings of 34 case studies for rivers, lakes, transitional and coastal waters carried out in 11 European countries. The results of the case studies as well as a summarizing synthesis were used as a fundamental basis to produce the guidance document. The practical examples given by the case studies were compiled as a toolbox which supplements the guidance for the purpose of its better application.     

Henry's law constant and hydrolysis of peroxyacetyl nitrate (PAN)

The effect of temperature on the solubility of PAN and on its hydrolysis rate in near-neutral and slightly acidic water were studied in a bubble column apparatus. The results obtained are a Henry's law coefficient H=10^–9.04±0.6 exp[(6513±376)/T] M atm^–1, and a first-order hydrolysis rate constant k=10^6.60±1.0 exp[(–6612±662)/T] s^-1, which was independent of pH in the range 3.2pH6.7. The products formed are nitrite and nitrate in approximately equal proportions under near-neutral conditions. At a pH<4, nitrite is oxidized in a secondary reaction, and nitrate becomes the only product at low pH. Previously measured deposition velocities of PAN on stagnant water surfaces are shown to be hydrolysis rate limited.     

Differential geodetic stereo SAR with TerraSAR-X by exploiting small multi-directional radar reflectors

In this paper, we report on the direct positioning of small multi-directional radar reflectors, so-called octahedrons, with the synthetic aperture radar (SAR) satellite TerraSAR-X. Its highest resolution imaging mode termed staring spotlight enables the use of such octahedron reflectors with a dimension of only half a meter, but still providing backscatter equivalent to 1–2 cm observation error. Four octahedrons were deployed at Wettzell geodetic observatory, and observed by TerraSAR-X with 12 acquisitions in three different geometries. By applying our least squares stereo SAR algorithm already tested with common trihedral corner reflectors (CRs), and introducing a novel differential extension using one octahedron as reference point, the coordinates of the remaining octahedrons were directly retrieved in the International Terrestrial Reference Frame (ITRF). Contrary to our standard processing, the differential approach does not require external corrections for the atmospheric path delays and the geodynamic displacements, rendering it particularly useful for joint geodetic networks employing SAR and GNSS. In this paper, we present and discuss both methods based on results when applying them to the aforementioned Wettzell data set of the octahedrons. The comparison with the independently determined reference coordinates confirms the positioning accuracy with 2–5 cm for the standard approach, and 2–3 cm for the differential processing. Moreover, we present statistical uncertainty estimates of the observations and the positioning solutions, which are additionally provided by our parameter estimation algorithms. The results also include our 1.5 m CR available at Wettzell, and the outcomes clearly demonstrate the advantage of the multi-directional octahedrons over conventional CRs for global positioning applications with SAR.     

Geometric methods for estimating representative sidewalk widths applied to Vienna’s streetscape surfaces database

Space, and in particular public space for movement and leisure, is a valuable and scarce resource, especially in today’s growing urban centres. The distribution and absolute amount of urban space—especially the provision of sufficient pedestrian areas, such as sidewalks—is considered crucial for shaping living and mobility options as well as transport choices. Ubiquitous urban data collection and today’s IT capabilities offer new possibilities for providing a relation-preserving overview and for keeping track of infrastructure changes. This paper presents three novel methods for estimating representative sidewalk widths and applies them to the official Viennese streetscape surface database. The first two methods use individual pedestrian area polygons and their geometrical representations of minimum circumscribing and maximum inscribing circles to derive a representative width of these individual surfaces. The third method utilizes aggregated pedestrian areas within the buffered street axis and results in a representative width for the corresponding road axis segment. Results are displayed as city-wide means in a 500 by 500 m grid and spatial autocorrelation based on Moran’s I is studied. We also compare the results between methods as well as to previous research, existing databases and guideline requirements on sidewalk widths. Finally, we discuss possible applications of these methods for monitoring and regression analysis and suggest future methodological improvements for increased accuracy.