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31.
Hydrothermal alteration and mineralization at the Wunugetu porphyry Cu–Mo deposit, China, include four stages, i.e., the early stage characterized by quartz, K-feldspar and minor mineralization, followed by a molybdenum mineralization stage associated with potassic alteration, copper mineralization associated with sericitization, and the last Pb–Zn mineralization stage associated with carbonation. Hydrothermal quartz contains three types of fluid inclusions, namely aqueous (W-type), daughter mineral-bearing (S-type) and CO2-rich (C-type) inclusion, with the latter two types absent in the late stage. Fluid inclusions in the early stage display homogenization temperatures above 510°C, with salinities up to 75.8 wt.% NaCl equivalent. The presence of S-type inclusions containing anhydrite and hematite daughter minerals and C-type inclusions indicates an oxidizing, CO2-bearing environment. Fluid inclusions in the Mo- and Cu-mineralization stages yield homogenization temperatures of 342–508°C and 241–336°C, and salinities of 8.6–49.4 and 6.3–35.7 wt.% NaCl equivalent, respectively. The presence of chalcopyrite instead of hematite and anhydrite daughter minerals in S-type inclusions indicates a decreasing of oxygen fugacity. In the late stage, fluid inclusions yield homogenization temperatures of 115–234°C and salinities lower than 12.4 wt.% NaCl equivalent. It is concluded that the early stage fluids were CO2 bearing, magmatic in origin, and characterized by high temperature, high salinity, and high oxygen fugacity. Phase separation occurred during the Mo- and Cu-mineralization stages, resulting in CO2 release, oxygen fugacity decrease and rapid precipitation of sulfides. The late-stage fluids were meteoric in origin and characterized by low temperature, low salinity, and CO2 poor. 相似文献
32.
Susanne P. Schwenzer Siegfried Herrmann Ratan K. Mohapatra Ulrich Ott 《Meteoritics & planetary science》2007,42(3):387-412
Abstract— This study provides a complete data set of all five noble gases for bulk samples and mineral separates from three Martian shergottites: Shergotty (bulk, pyroxene, maskelynite), Zagami (bulk, pyroxene, maskelynite), and Elephant Moraine (EET) A79001, lithology A (bulk, pyroxene). We also give a compilation of all noble gas and nitrogen studies performed on these meteorites. Our mean values for cosmic‐ray exposure ages from 3He, 21Ne, and 38Ar are 2.48 Myr for Shergotty, 2.73 Myr for Zagami, and 0.65 Myr for EETA79001 lith. A. Serious loss of radiogenic 4He due to shock is observed. Cosmogenic neon results for bulk samples from 13 Martian meteorites (new data and literature data) are used in addition to the mineral separates of this study in a new approach to explore evidence of solar cosmic‐ray effects. While a contribution of this low‐energy irradiation is strongly indicated for all of the shergottites, spallation Ne in Chassigny, Allan Hills (ALH) 84001, and the nakhlites is fully explained by galactic cosmic‐ray spallation. Implanted Martian atmospheric gases are present in all mineral separates and the thermal release indicates a near‐surface siting. We derive an estimate for the 40Ar/36Ar ratio of the Martian interior component by subtracting from measured Ar in the (K‐poor) pyroxenes the (small) radiogenic component as well as the implanted atmospheric component as indicated from 129Xe, * excesses. Unless compromised by the presence of additional components, a high ratio of ~2000 is indicated for Martian interior argon, similar to that in the Martian atmosphere. Since much lower ratios have been inferred for Chassigny and ALH 84001, the result may indicate spatial and/or temporal variations of 40Ar/36Ar in the Martian mantle. 相似文献
33.
34.
Jürgen Oberst Valéry Lainey Christophe Le Poncin-Lafitte Veronique Dehant Pascal Rosenblatt Stephan Ulamec Jens Biele J?rn Spurmann Ralph Kahle Volker Klein Ulrich Schreiber Anja Schlicht Nicolas Rambaux Philippe Laurent Beno?t Noyelles Bernard Foulon Alexander Zakharov Leonid Gurvits Denis Uchaev Scott Murchie Cheryl Reed Slava G. Turyshev Jesus Gil Mariella Graziano Konrad Willner Kai Wickhusen Andreas Pasewaldt Marita W?hlisch Harald Hoffmann 《Experimental Astronomy》2012,34(2):243-271
GETEMME (Gravity, Einstein??s Theory, and Exploration of the Martian Moons?? Environment), a mission which is being proposed in ESA??s Cosmic Vision program, shall be launched for Mars on a Soyuz Fregat in 2020. The spacecraft will initially rendezvous with Phobos and Deimos in order to carry out a comprehensive mapping and characterization of the two satellites and to deploy passive Laser retro-reflectors on their surfaces. In the second stage of the mission, the spacecraft will be transferred into a lower 1500-km Mars orbit, to carry out routine Laser range measurements to the reflectors on Phobos and Deimos. Also, asynchronous two-way Laser ranging measurements between the spacecraft and stations of the ILRS (International Laser Ranging Service) on Earth are foreseen. An onboard accelerometer will ensure a high accuracy for the spacecraft orbit determination. The inversion of all range and accelerometer data will allow us to determine or improve dramatically on a host of dynamic parameters of the Martian satellite system. From the complex motion and rotation of Phobos and Deimos we will obtain clues on internal structures and the origins of the satellites. Also, crucial data on the time-varying gravity field of Mars related to climate variation and internal structure will be obtained. Ranging measurements will also be essential to improve on several parameters in fundamental physics, such as the Post-Newtonian parameter ?? as well as time-rate changes of the gravitational constant and the Lense-Thirring effect. Measurements by GETEMME will firmly embed Mars and its satellites into the Solar System reference frame. 相似文献
35.
The Acid-Producing Potential (APP) and the Acid-Consuming Capacity (ACC) are introduced as basic parameters for long-term
pollution assessment of mud disposal. They can be obtained by a four-step sequential leaching technique. The concentration
of Ca extracted by the first Na-acetate step permits calculating the ACC. Both the Fe- and S-fractions deliberated by subsequent
leaching steps are used to calculate the APP. When the APP of a sample is substacted from its ACC, a negative value indicates
a potential increase of the bioavailability of the toxic metal load upon disposal of this mud in oxic environments. 相似文献
36.
Boron abundances and isotopic ratios of olivine grains on Itokawa returned by the Hayabusa spacecraft 下载免费PDF全文
We report the B abundances and isotopic ratios of two olivine grains from the S‐type asteroid Itokawa sampled by the Hayabusa spacecraft. Olivine grains from the Dar al Gani (DaG) 989 LL6 chondrite were used as a reference. Since we analyzed polished thin sections in both cases, we expect the contribution from the solar wind B (rich in 10B) to be minimal because the solar wind was implanted only within very thin layers of the grain surface. The Itokawa and DaG 989 olivine grains have homogeneous B abundances (~400 ppb) and 11B/10B ratios compatible with the terrestrial standard and bulk chondrites. The observed homogeneous B abundances and isotopic ratios of the Itokawa olivine grains are likely the result of thermal metamorphism which occurred in the parent asteroid of Itokawa, which had a similar composition as LL chondrites. The chondritic B isotopic ratios of the Itokawa samples suggest that they contain little cosmogenic B (from cosmic‐ray spallation reactions) rich in 10B. This observation is consistent with the short cosmic‐ray exposure ages of Itokawa samples inferred from the small concentrations of cosmogenic 21Ne. If other Itokawa samples have little cosmogenic B as well, the enrichment in 10B found previously on the surface of another Itokawa particle (as opposed to the bulk grain study here) may be attributed to implanted solar wind B. 相似文献
37.
Kai-Uwe Ulrich Eugene S. Ilton Jonathan O. Sharp Rizlan Bernier-Latmani John R. Bargar 《Geochimica et cosmochimica acta》2009,73(20):6065-7290
The long-term stability of biogenic uraninite with respect to oxidative dissolution is pivotal to the success of in situ bioreduction strategies for the subsurface remediation of uranium legacies. Batch and flow-through dissolution experiments were conducted along with spectroscopic analyses to compare biogenic uraninite nanoparticles obtained from Shewanella oneidensis MR-1 and chemogenic UO2.00 with respect to their equilibrium solubility, dissolution mechanisms, and dissolution kinetics in water of varied oxygen and carbonate concentrations. Both materials exhibited a similar intrinsic solubility of ∼10−8 M under reducing conditions. The two materials had comparable dissolution rates under anoxic as well as oxidizing conditions, consistent with structural bulk homology of biogenic and stoichiometric uraninite. Carbonate reversibly promoted uraninite dissolution under both moderately oxidizing and reducing conditions, and the biogenic material yielded higher surface area-normalized dissolution rates than the chemogenic. This difference is in accordance with the higher proportion of U(V) detected on the biogenic uraninite surface by means of X-ray photoelectron spectroscopy. Reasonable sources of a stable U(V)-bearing intermediate phase are discussed. The observed increase of the dissolution rates can be explained by carbonate complexation of U(V) facilitating the detachment of U(V) from the uraninite surface. The fraction of surface-associated U(VI) increased with dissolved oxygen concentration. Simultaneously, X-ray absorption spectra showed conversion of the bulk from UO2.0 to UO2+x. In equilibrium with air, combined spectroscopic results support the formation of a near-surface layer of approximate composition UO2.25 (U4O9) coated by an outer layer of U(VI). This result is in accordance with flow-through dissolution experiments that indicate control of the dissolution rate of surface-oxidized uraninite by the solubility of metaschoepite under the tested conditions. Although U(V) has been observed in electrochemical studies on the dissolution of spent nuclear fuel, this is the first investigation that demonstrates the formation of a stable U(V) intermediate phase on the surface of submicron-sized uraninite particles suspended in aqueous solutions. 相似文献
38.
Frank Kaspar Kerstin Prömmel Ulrich Cubasch 《International Journal of Earth Sciences》2010,99(7):1677-1686
A global atmosphere–ocean model has been forced with topographic and orbital scenarios in order to evaluate the relative role
of both factors for the past climate of East Africa. Forcing the model with a significantly reduced topography in Eastern
and Southern Africa leads to a distinct increase in moisture transport from the Indian Ocean into the eastern part of the
continent and increased precipitation in Eastern Africa. Simulations with step-wise reduced height show that this climate
change occurs continuously with the change in topography, i.e., an abrupt change of local climatic features with a critical
height is not found. Simulations of the last interglacial (at 125,000 years before present, i.e., the Eemian interglacial)
and the last glacial inception (at 115,000 years before present) are used as examples for the role of orbital-induced changes
in insolation. Here, changes in meridional temperature gradients lead to modifications in moisture transport of similar order
of magnitude, but with different spatial and seasonal structure. For the Eemian interglacial, a distinct increase in summer
moisture transport from the Atlantic deep into the continent at around 20°N is simulated. 相似文献
39.
The carbonate carbon isotope record of the Phanerozoic is marked by repeated high-amplitude excursions towards more positive values. Although the interpretation of C-isotope events remains controversial, they are regarded as a proxy of the global C-cycle. Using δ13 COrg -measurements of samples from DSDP Site 416, it is shown that a classic example of platform drowning coincided with the onset of the mid-Valanginian carbon-cycle excursion. Widespread carbonate platform drowning would have contributed to the observed positive shift in the C-isotope record. As choking of carbonate production was compensated by increased organic production, both processes favoured a shift in marine carbon partitioning from the oxidized to the reduced carbon reservoir. This would have resulted in an increased flux of CO2 from the atmosphere into the marine and sedimentary carbon reservoir. 相似文献
40.
Roger K. Ulrich Larry Webster John E. Boyden Nick Magnone Richard S. Bogart 《Solar physics》1991,135(2):211-241
We describe enhancements to the hardware and software for the 150-foot tower system on Mt. Wilson which make possible the acquisition of high precision line profile measurements. This system utilizes the 75-foot pit spectrograph with a photomultiplier detector system to scan line profiles repeatedly in order to study variations induced by the passage of waves vertically through the solar atmosphere. Oscillations of line profile parameters with an amplitude as low as 1.7 m s–1 have been detected with this system using integrated sunlight. Phase relations between oscillations of different parts of the line profile are appropriate to upward energy transport. Consistent with the previous conclusion by Mein and Schmieder (1981), we find that the magnitude of the energy transport is compatible with the 5-min oscillations making an important contribution to the heating of the low chromosphere.The Mount Wilson Observatory is operated by the Mount Wilson Institute under agreement with the Carnegie Institution of Washington. 相似文献