Large-Scale Zonal Flows Near the Solar Surface

Migrating bands of weak, zonal flow, associated with the activity bands in the solar cycle, have been observed at the solar surface for some time. More recently, these flows have been probed deep within the convection zone using global helioseismology and examined in more detail close to the surface with the techniques of local helioseismology. We compare the near-surface results from global and local helioseismology using data from the Michelson Doppler Imager and the Global Oscillation Network Group with surface Doppler velocity measurements from the Mount Wilson 150-foot tower and find that the results are in reasonable agreement, with some explicable differences in detail. All of the data sets show zones of faster rotation approaching the equator from mid-latitudes during the solar cycle, with a variation at any given location that can be approximately, but not completely, described by a single sinusoid and an amplitude that does not drop off steeply below the surface.     

Long-Term Variations in Solar Differential Rotation and Sunspot Activity

The solar equatorial rotation rate, determined from sunspot group data during the period 1879–2004, decreased over the last century, whereas the level of activity has increased considerably. The latitude gradient term of the solar rotation shows a significant modulation of about 79 year, which is consistent with what is expected for the existence of the Gleissberg cycle. Our analysis indicates that the level of activity will remain almost the same as the present cycle during the next few solar cycles (i.e., during the current double Hale cycle), while the length of the next double Hale cycle in sunspot activity is predicted to be longer than the current one. We find evidence for the existence of a weak linear relationship between the equatorial rotation rate and the length of sunspot cycle. Finally, we find that the length of the current cycle will be as short as that of cycle 22, indicating that the present Hale cycle may be a combination of two shorter cycles. Presently working for the Mt. Wilson Solar Archive Digitization Project at UCLA.     

On the history of chloride concentrations in the River Lippe (Germany) and the impact on the macroinvertebrates

The River Lippe is situated at the northern part of the rhenish-westphalian coal mining area, Germany and has a long history of being affected by mining water discharge. There has, however, been a massive decrease in the discharge of mining water over the past few decades. While early in the last century concentrations of up to 3500 mg l⁻¹ of chloride were observed, the mean concentration is now below 400 mg l⁻¹. At the same time the water quality has improved greatly so factors other than chloride concentration may be influencing the macroinvertebrate community.Macroinvertebrate data collected from three sites along the River Lippe was analyzed for a change in the occurrence of salt tolerant species in an area where mining water discharge ended in 2000. It was found that also during the period of discharges the macroinvertebrate community was dominated by freshwater species and therefore the impact of mining water discharges in the upper River Lippe is considered to be minor.It was also found that for some species (Nais elinguis, Bithynia tentaculata and Gammarus tigrinus) their proposed salinity preference did not correlate with their occurrence in the field. This may be an area that requires further research.     

Seismohydrological effects related to the NW Bohemia earthquake swarms of 2000 and 2008: Similarities and distinctions

For more than 20 years, seismohydrological investigations have been undertaken at the mineral aquifer system of Bad Brambach (Vogtland, Germany). Two strong swarm earthquake series in 2000–2001 and 2008–2009 at the Nový Kostel epicentre (Czech Republic, 10 km E of BB) have enabled for the first time a comparison of seismological and groundwater hydraulic features in a semi-quantitative way. In spite of their similar spatial distribution in 2001 and 2008, the earthquake foci of each swarm migrated differently through time, horizontally as well as in depth. The seismic energy of the 2008–2009 events was released predominantly within 1 month, in contrast to 2000–2001 when it occurred over 3 months. The main distinctive features of each are seen in the hydraulic pressure anomalies which accompanied the earthquake swarms: number, shape, and progression (duration) of the anomalies. The comprehensive hydraulic data, with high temporal resolution, suggest that fluid triggering dominated not only the earthquake initiating phases. In particular, the long-lasting seismicity of the 2008–2009 swarm can be attributed to a continued triggering of weak earthquakes by over-pressured deep fluids. Here, the remaining static strain was obviously not sufficient to generate strong earthquakes as at the beginning of the earthquake swarm periods. Furthermore, the enduring high fluid pressure in 2009 could also indicate a continuation of the long-term gas flow increase observed at several gas outlets in the Vogtland/NW Bohemia region between 1998 and 2008. However, it is not possible at present to derive a systematic relationship between anomaly occurrence and seismic activity, as generally proposed in the context of earthquake prediction discussion.     

Raman study of apatite amorphised with swift heavy ions under various irradiation conditions

Crystallographically oriented Durango fluorapatites were exposed to swift heavy ions (Xe, Ta, Au, U) at different irradiation conditions. Beam-induced sample modifications were investigated with respect to the effect of fluence (10⁹–10¹³ ions/cm²), electronic energy loss (18–27 keV/nm), and pressure (3.6–11.5 GPa) applied during irradiation. In situ high-pressure irradiation was performed in diamond anvil cells. Confocal Raman spectroscopy was used to trace the occurring changes in the crystal lattice. Fragmentation of the crystal specimen depends on the orientation and sample thickness and was found to scale with energy loss and fluence. The radiation damage for irradiation along the c-axis was found to be larger than for the 〈hk0〉 direction, independent of the confining pressure. Observations on samples irradiated at high pressures indicate a stabilising effect, leading to reduced amorphisation in comparison to the samples irradiated without pressure.     

Shock-induced formation mechanism of seifertite in shergottites

The Martian meteorites Shergotty, Zagami and Dhofar 378 have been re-investigated in order to elucidate the shock-induced formation of seifertite. The occurrence of orthorhombic seifertite (α-PbO₂ structured SiO₂) has been confirmed for the mesostasis of Shergotty and Zagami by transmission electron microscopy with lattice parameters of a = 4.05(1) Å, b = 5.05(1) Å and c = 4.45(1) Å. Seifertite crystals are interpreted as shock-induced transformation products occurring together with maskelynite of both plagioclase and alkali-feldspar composition in a largely preserved eutectic crystallisation texture. Shock-induced microstructures in accessory minerals demonstrate that these regions cannot have been completely re-molten. No further features indicating shock-pressures above ~30 GPa are detected. Hence, seifertite must have been formed below its stability field by a fast solid-state process. Significantly higher shock-pressures of Dhofar 378 indicate an inhibition of a potential seifertite crystallisation by resulting high post-shock temperatures. Crystallographic considerations reveal that a direct formation of seifertite from a high-pressure derivate of cristobalite is possible without breaking any silicon-oxygen bonds. Important implications arise from the existence of such a non-equilibrium pathway. Inferring shock-pressures from metastably formed phases appears implausible, and the transition pressure could be even below 30 GPa. Furthermore, the transformation product is determined by the precursor phase. Epitaxial intergrowth with other silica high-pressure polymorphs should be induced by certain features of the precursor, for example, planar defects, or heterogeneous strain conditions. Due to symmetrical considerations, seifertite will get amorphous during a potential back-transformation, which provides an explanation for the formation of numerous amorphous lamellae.     

Natural Obsidian Glass as an External Accuracy Reference Material in Laser Ablation‐Inductively Coupled Plasma‐Mass Spectrometry

Compared with solution ICP‐MS, LA‐ICP‐MS studies have thus far reported comparatively few external reference data for accuracy estimates of experiments. This is largely the result of a paucity of available reference materials of natural composition. Here, we report an evaluation of natural glass (obsidian) as an inexpensive and widely available external reference material. The homogeneity of over forty elements in six different obsidian samples was assessed by LA‐ICP‐MS. Accuracy was tested with two obsidian samples that were fully characterised by electron probe microanalysis and solution ICP‐MS. Laser ablation experiments were performed with a variety of ablation parameters (fluence, spot sizes, ablation repetition rates) and calibration approaches (natural vs. synthetic reference materials, and different internal standard elements) to determine the best practice for obsidian analysis. Furthermore, the samples were analysed using two different laser wavelengths (193 nm and 213 nm) to compare the effect of potential ablation‐related phenomena (e.g., fractionation). Our data indicate that ablation with fluences larger than 6 J cm^?2 and repetition rates of 5 or 10 Hz resulted in the most accurate results. Furthermore, synthetic NIST SRM 611 and 612 glasses worked better as reference materials compared with lower SiO₂ content reference materials (e.g., BHVO‐2G or GOR128‐G). The very similar SiO₂ content of the NIST SRM glasses and obsidian (i.e., matrix and compositional match) seems to be the first‐order control on the ablation behaviour and, hence, the accuracy of the data. The use of different internal standard elements for the quantification of the obsidian data showed that Si and Na yielded accurate results for most elements. Nevertheless, for the analysis of samples with high SiO₂ concentrations, it is recommended to use Si as the internal standard because it can be more precisely determined by electron probe microanalysis. At the scale of typical LA analyses, the six obsidian samples proved to be surprisingly homogenous. Analyses with a spot size of 80 μm resulted in relative standard deviations (% RSD) better than 8% for all but the most depleted elements (e.g., Sc, V, Ni, Cr, Cu, Cd) in these evolved glasses. The combined characteristics render obsidian a suitable, inexpensive and widely available, external quality‐control material in LA‐ICP‐MS analysis for many applications. Moreover, obsidian glass is suited for tuning purposes, and well‐characterised obsidian could even be used as a matrix‐matched reference material for a considerable number of elements in studies of samples with high SiO₂ contents.     

Cathodoluminescence microscopy and spectroscopy of forsterite from Kaba meteorite: An application to the study of hydrothermal alteration of parent body

Highly forsteritic olivine (Fo: 99.2–99.7) in the Kaba meteorite emits bright cathodoluminescence (CL). CL spectra of red luminescent forsterite grains have two broad emission bands at approximately 630 nm (impurity center of divalent Mn ions) in the red region and above 700 nm (trivalent Cr ions) in the red–IR region. The cores of the grains show CL blue luminescence giving a characteristic broad band emission at 400 nm, also associated with minor red emissions related to Mn and Cr ions. CL color variation of Kaba forsterite is attributed to structural defects. Electron probe microanalyzer (EPMA) analysis shows concentrations of Ca, Al, and Ti in the center of the forsterite grain. The migration of diffusible ions of Mn, Cr, and Fe to the rim of the Kaba meteoritic forsterite was controlled by the hydrothermal alteration at relatively low temperature (estimated at about 250 °C), while Ca and Al ions might still lie in the core. A very unusual phase of FeO (wüstite) was also observed, which may be a terrestrial alteration product of FeNi‐metal.