Sulfide Inhibition of Nitrate Removal in Coastal Sediments

Microbial nitrate (NO₃⁻) removal via denitrification (DNF) at high sulfide (H₂S) concentrations was compared in sediment from a coastal freshwater pond in a developed area that receives salt-water influx during storm events, and a saline pond proximal to an undeveloped estuary. Sediments were incubated with added SO₄²⁻ (1,000 μg per gram dry weight basis (gdw)) to determine whether acid volatile sulfides (AVS) were formed. DNF in the sediments was measured with NO₃–N (300 μg gdw⁻¹) alone, and with NO₃–N and H₂S (1,000 μg S²⁻ gdw⁻¹). SO₄²⁻ addition to the freshwater sediments resulted in AVS formation (970 ± 307 μg S gdw⁻¹) similar to the wetland with no added SO₄²⁻ (986 ± 156 μg S gdw⁻¹). DNF rates measured with no added H₂S were greater in the freshwater than the wetland site (10.6 ± 0.6 vs. 6.4 ± 0.1 μg N₂O–N gdw⁻¹ h⁻¹, respectively). High H₂S concentrations retained NH₄–N in the undeveloped wetland and retained NO₃–N in the developed freshwater site, suggesting that potential salt-water influx may reduce the ability of the freshwater sediments to remove NO₃–N.     

Experimental shock synthesis of diamonds in a graphite gneiss

Abstract— The occurrence of diamonds in terrestrial impact craters and meteorites is related to dynamic shock loading during hypervelocity impacts. To understand the mechanism of impact diamond formation in natural rocks, shock‐recovery experiments with graphite gneiss were carried out at shock pressures between 35 and 79 GPa. This is the first report on the successful shock synthesis of microdiamonds in a natural rock. Micrometer‐size diamonds and a wide range of intermediate, presently unclassified, amorphous, and disordered carbon phases were observed within vesiculated biotite melts in the vicinity of relic graphite grains using microRaman spectrometry. We explain these findings by jetting mechanisms of carbon and graphite clusters, originating at the edges of graphite grains, into the very hot and volatile rich biotitic melt veins during shock loading. This environment enabled the thermally activated crystallization of diamonds during shock compression in a period of less than 0.5 μsec. Regraphitization of diamonds during pressure release was widespread and caused the formation of the amorphous to disordered carbon phases recorded frequently with microRaman spectroscopy. The surviving diamonds must have cooled down to 2000 K during the compression phase at local thermal sinks and cooler interfaces to avoid regraphitization.     

The resolved red giant branches of E/S0 galaxies

Formation paradigms for massive galaxies have long centered around two antipodal hypotheses – the monolithic-collapse and the accretion/merger scenarios. Empirical data on the stellar contents of galaxy halos is crucial in order to develop galaxy formation and assembly scenarios which have their root in observations, rather than in numerical simulations. The Hubble Space Telescope (HST) has enabled us to study directly individual stars in the nearby E/S0 galaxies Cen A, NGC 3115, NGC 5102, and NGC 404. We here present and discuss HST single-star photometry in V and I bands. Using color-magnitude diagrams and stellar luminosity functions, we gauge the galaxies' stellar contents. This can be done at more than one position in the halo, but data with deeper limiting magnitudes are desired to quantify the variation of metallicity with galactocentric radius. We here compare the color distributions of red giant stars with stellar isochrones, and we intercompare the galaxies' halo populations, noting that their total absolute V magnitudes cover the range from about –21.5 to –17.5. In the future, we plan to model the stellar metallicity distributions with the aim to constrain chemical enrichment scenarios, a step towards unravelling the evolutionary history of elliptical and lenticular galaxies. This revised version was published online in August 2006 with corrections to the Cover Date.     

Kinematics and stellar populations of 17 dwarf early-type galaxies

We present kinematics and stellar population properties of 17 dwarf early-type galaxies in the luminosity range -14 ≥ M _B ≥ -19. Our sample fills the gap between the intensively studied giant elliptical and Local Group dwarf spheroidal galaxies. The dwarf ellipticals of the present sample have constant velocity dispersion profiles within their effective radii and do not show significant rotation, hence are clearly anisotropic. The dwarf lenticulars, instead, rotate faster and are, at least partially, supported by rotation. From optical Lick absorption indices, we derive metallicities and element abundances. Combining our sample with literature data of the Local Group dwarf spheroidals and giant ellipticals, we find a surprisingly tight linear correlation between metallicity and luminosity over a wide range: -8 ≥ M _B ≥ -22. The α/Fe ratios of our dwarf ellipticals are significantly lower than the ones of giant elliptical galaxies, which is in agreement with spectroscopy of individual stars in Local Group dwarf spheroidals. Our results suggest the existence of a clear kinematic and stellar population dichotomy between dwarf and giant elliptical galaxies. This result is important for theories of galaxy formation, because it implies that present-day dwarf ellipticals are not the fossiled building blocks of giant ellipticals. This revised version was published online in August 2006 with corrections to the Cover Date.     

Analysing the interaction between emission trading and renewable electricity support in TIMES

As the number of instruments applied in the area of energy and climate policy is rising, the issue of policy interaction needs to be explored further. This article analyses the interdependencies between the EU Emissions Trading Scheme (EU ETS) and the German feed-in tariffs (FITs) for renewable electricity in a quantitative manner using a bottom-up energy system model. Flexible modelling approaches are presented for both instruments, with which all impacts on the energy system can be evaluated endogenously. It is shown that national climate policy measures can have an effect on the supranational emissions trading system by increasing emission reduction in the German electricity sector by up to 79 MtCO₂ in 2030. As a result, emission certificate prices decline by between 1.9 €/tCO₂ and 6.1 €/tCO₂ and the burden sharing between participating countries changes, but no additional emission reduction is achieved at the European level. This also implies, however, that the cost efficiency of such a cap-and-trade system is distorted, with additional costs of the FIT system of up to €320 billion compared with lower costs for ETS emission certificates of between €44 billion and €57 billion (cumulated over the period 2013–2020).

Policy relevance

In order to fulfil ambitious emission reduction targets a large variety of climate policy instruments are being implemented in Europe. While some, like the EU ETS, directly address CO₂ emissions, others aim to promote specific low-carbon technologies. The quantitative analysis of the interactions between the EU ETS and the German FIT scheme for renewable sources in electricity generation presented in this article helps to understand the importance of such interaction effects. Even though justifications can be found for the implementation of both types of instrument, the impact of the widespread use of support mechanisms for renewable electricity in Europe needs to be taken into account when fixing the reduction targets for the EU ETS in order to ensure a credible long-term investment signal.     

A multi-frequency Acoustic Concentration and Velocity Profiler (ACVP) for boundary layer measurements of fine-scale flow and sediment transport processes

The use of acoustics to measure sediment transport boundary layer processes has gained increasing acceptance over the past two decades. This has occurred through the development of increasingly sophisticated measuring systems and theoretical developments, which have enabled flow and suspended sediment parameters to be obtained from acoustic data with a high degree of accuracy. Until relatively recently, separate acoustic systems were used to measure flow and suspended sediment concentration. Over the past few years, however, the technology has become sufficiently advanced so that flow and sediment measurements can be integrated into a single system. This integration provides, quasi-instantaneous, non-intrusive, co-located, high temporal-spatial resolution measurements of benthic flow and sediment processes. Here the development of such an instrument, the Acoustic Concentration and Velocity Profiler (ACVP) is described. The theory underpinning its application is outlined, new approaches to velocity de-aliasing and suspended sediment inversion instabilities using multi-frequency capabilities are presented and the application of the system to sediment transport processes over a sandy ripple bed is illustrated. The observations clearly show the value of such instrumentation for studying the dynamical interaction between the bed, the flow and the sediments at and within the bottom boundary layer.     

Equilibrium scour depths around piles in noncohesive sediments under currents and waves

A universal formula for the estimation of equilibrium scour depth around a single cylindrical pile under the action of steady currents, tidal and short waves is presented.     

Response of a proglacial delta to rapid high‐amplitude lake‐level change: an integration of outcrop data and high‐resolution shear wave seismics

In this paper, we will present the stratigraphic evolution, internal facies architecture and geomorphology of the Middle Pleistocene Emme delta, controlled by rapid high‐amplitude lake‐level change. The Emme delta was deposited on the northern margin of glacial Lake Weser, located in north‐west Germany. Rates of lake‐level rise were probably >50 mm year^?1 and rates of lake‐level fall 30–50 m within a few days or weeks, due to the opening of lake outlets. We use digital elevation models, sedimentology and shear wave seismics to improve earlier reconstructions and investigate the influence of rapid base‐level change on delta development. Shear wave seismic data resolve architectural elements in the range of metres and bridge the common gap between outcrop and conventional compression wave seismic data. The radial delta complex is about 2 km long, 1.8 km wide and up to 70 m thick, overlying a concave, up to 13° steep dipping ramp surface. It consists of vertically and laterally stacked delta lobes, caused by lobe switching during base‐level change. During the lake‐level rise, vertically stacked (Gilbert‐type) delta systems formed. The decrease in thickness and lateral extent indicates a rapid upslope shift of depocentres. A high rate and magnitude of lake‐level fall (50 m) promoted the development of a single incised valley and the deposition of forced regressive coarse‐grained delta lobes in front of the valley. The incised valley was filled during decreasing rates of lake‐level fall and low base‐level, because the alluvial gradient was larger than the emergent lake profile. Attached sand‐rich forced regressive aprons formed during lower magnitudes of lake‐level falls in the range of 30–35 m. Valley incision occurred, but was limited to the uppermost portion of the delta, controlled by the steep slope. The incised valley related to the final lake drainage is associated with long‐wavelength (60–90 m) bedforms at the downslope end, attributed to the formation of standing waves as a result of a hydraulic jump. Estimated palaeoflow depth during standing wave formation was ～9–14 m and flow velocity was 10–12 m s^?1. Because subsidence, waves or tides did not play a major role, the Emme delta can be used as an analogue‐based predictive stratigraphical and sedimentological model for steep glacigenic deltas controlled by rapid base‐level change and can help to understand better the facies distribution and three‐dimensional geometry of these depositional systems.     

Glacier fluctuations between 1975 and 2008 in the Greater Himalaya Range of Zanskar, southern Ladakh

Glaciers in the Himalaya are often heavily covered with supraglacial debris,making them difficult to study with remotely-sensed imagery alone.Various methods such as band ratios can be used effectively to map clean-ice glaciers;however,a thicker layer of debris often makes it impossible to distinguish between supraglacial debris and the surrounding terrain.Previously,a morphometric mapping approach employing an ASTER-derived digital elevation model has been used to map glaciers in the Khumbu Himal and the Tien Shan.This study on glaciers in the Greater Himalaya Range in Zanskar,southern Ladakh,aims (i) to use the morphometric approach to map large debris-covered glaciers;and (ii) to use Landsat and ASTER data and GPS and field measurements to document glacier change over the past four decades.Field work was carried out in the summers of 2008.For clean ice,band ratios from the ASTER dataset were used to distinguish glacial features.For debris-covered glaciers,topographic features such as slope were combined with thermal imagery and supervised classifiers to map glacial margins.The method is promising for large glaciers,although problems occurred in the distal and lateral parts and in the fore field of the glaciers.A multi-temporal analysis of glaciers in Zanskar showed that in general they have receded since at least the mid-to late-1970s.However,some few glaciers that advanced or oscillated - probably because of specific local environmental conditions - do exist.