Stability of ice on Mars and the water vapor diurnal cycle: Experimental study of the sublimation of ice through a fine-grained basaltic regolith

In order to advance our understanding of the long-term stability of subsurface ice, the diurnal martian water cycle, and implications for liquid water, we determined diffusion coefficients and adsorption kinetics for the water vapor produced by the sublimation of ice buried beneath various layers of fine-grained (<63, 63-125, and 125-250 μm) basaltic powder under simulated martian conditions. Sublimation rates at shallower depths, <10 mm, were determined to be affected by mass transfer through the atmosphere in addition to the basalt layer. For greater depths, the measured diffusion coefficients for water vapor moving through basalt grains were 1.56±0.53×¹⁰⁻⁴, 2.05±0.82×¹⁰⁻⁴, and for the <63, 63-125, and 125-250 μm basaltic layers, respectively. Through the Brunauer, Emmett and Teller (BET) isotherm, which assumes multiple molecular layers of adsorbed water, we determined the adsorption constants of 52.6±8.3 at 270 K for <63 μm, 39.0±6.4 at 267 K for 63-125 μm, and 54.3±9.3 at 266 K for 125-250 μm, resulting in surface areas of 2.6±0.1×¹⁰⁴, 1.7±0.3×¹⁰⁴, , respectively. These results suggest that while diffusion is too rapid to explain the purported diurnal cycle in water content of the atmosphere, adsorption is efficient and rapid, and does provide an effective mechanism to explain such a cycle. The present diffusion data suggest that very thin, <50 pr μm, shallow, 10 mm, ice deposits would last for >10 h at ∼224 K, just above the freezing point of saturated CaCl₂. Temperatures can remain above ∼224 K over most of the planet, which means that water, even as saturated brine, will sublimate before the freezing point is reached and liquid could be formed. On the other hand, 1 m ice layers below 1 m of fine-grained basaltic regolith at 235 K and 10 Pa of atmospheric water could last 600 to 1300 years. At deeper depths and lower temperatures, ice could last since the last major obliquity change 400,000 years ago.     

Simultaneous determination of global topography, tidal Love number and libration amplitude of Mercury by laser altimetry

Solar tidal forces generate elevation changes of Mercury's surface of the order 1 m within one Hermean year, and solar torques on the non-symmetric permanent mass distribution of the planet cause an uneven rotation of Mercury's surface with a libration amplitude of the order of 40 arcsec. Knowledge of the precise reaction of the planet to tidal forcing, expressed by the Love numbers h₂ and k₂, as well as accurate knowledge of the amplitude of forced libration Φ_lib, puts constraints on the internal structure, for example the state and the size of the core. The MESSENGER and BepiColombo missions to Mercury carry laser altimeters, whose primary goal is to accurately map the topography. Here we investigate if the Love number h₂ and the amplitude of forced libration can be determined together with the static topography of the planet from a global altimetry record. We do this by creating synthetic altimeter data for the nominal orbit of BepiColombo over the nominal mission duration of approximately four Mercury years and inverting them for the static and time-dependent parts of the topography. We assume purely Gaussian noise. We find that it is possible to extract both parameters h₂ and Φ_lib with an accuracy of approximately 10%, while the static topography coefficients of a spherical harmonic expansion can be determined simultaneously with an accuracy at the centimetre level. Extraction of the static topography to higher harmonic degrees improves the precision of the measurement of h₂ and Φ_lib. The simulation results demonstrate that it seems feasible to test current models on Mercury's interior with sufficient precision using BepiColombo Laser Altimeter data.     

Models of magnetic field generation in partly stable planetary cores: Applications to Mercury and Saturn

A substantial part of Mercury's iron core may be stably stratified because the temperature gradient is subadiabatic. A dynamo would operate only in a deep sublayer. We show that such a situation arises for a wide range of values for the heat flow and the sulfur content in the core. In Saturn the upper part of the metallic hydrogen core could be stably stratified because of helium depletion. The magnetic field is unusually weak in the case of Mercury and unusually axisymmetric at Saturn. We study numerical dynamo models in rotating spherical shells with a stable outer region. The control parameters are chosen such that the magnetic Reynolds number is in the range of expected Mercury values. Because of its slow rotation, Mercury may be in a regime where the dipole contribution to the internal magnetic field is weak. Most of our models are in this regime, where the dynamo field consists mainly of rapidly varying higher multipole components. They can hardly pass the stable conducting layer because of the skin effect. The weak low-degree components vary more slowly and control the structure of the field outside the core, whose strength matches the observed field strength at Mercury. In some models the axial dipole dominates at the planet's surface and in others the axial quadrupole is dominant. Differential rotation in the stable layer, representing a thermal wind, is important for attenuating non-axisymmetric components in the exterior field. In some models that we relate to Saturn the axial dipole is intrinsically strong inside the dynamo. The surface field strength is much larger than in the other cases, but the stable layer eliminates non-axisymmetric modes. The Messenger and Bepi Colombo space missions can test our predictions that Mercury's field is large-scaled, fairly axisymmetric, and shows no secular variations on the decadal time scale.     

Chemistry of Halogen Oxides in the Troposphere: Comparison of Model Calculations with Recent Field Data

Reactive halogen species (RHS = X, XO, HOX, OXO; X = Cl, Br, I) are known to have an important influence on the chemistry in the polar boundary layer (BL), where they are responsible for ozone depletion events in spring. Recent field campaigns at Mace Head, Ireland, and the Dead Sea, Israel, identified for the first time iodine oxide (IO) at mixing ratios of up to 6.6 ppt and 90 ppt bromine oxide (BrO), respectively, by DOAS also at lower latitudes. These results intensified the discussion about the role of the RHS in the mid-latitude BL.Photochemical box model calculations show that the observed IO mixing ratios can destroy ~0.45 ppb ozone per hour. This is comparable to the rates of the known O₃-loss processes in the boundary layer. The model studies also reveal that IO, at these levels, has a strong influence on the BL photochemistry, increasing the OH/HO₂- and the NO₂/NO - ratios. In combination these changes lead to a reduction of the photochemical ozone formation, which - in addition - reduces ozone mixing ratios by up to 0.15 ppb/h.The studies for the Dead Sea case give no information on the heterogeneous process responsible for the bromine release, but they show that a total of 2 – 4 ppb of total bromine have to be released to explain the observed complete depletion of 60 ppb ozone in 2 – 3 hours.     

A multi-method approach for the identification and quantification of water balance components of two lentic small water bodies

The protection of the globally widespread lentic small water bodies (LSWB) must be based on detailed knowledge about their hydrological connectivity and water balance. The study aimed to identify and quantify water balance components as well as surface-groundwater interaction of two LSWB in a characteristic lowland region with a combination of different methods. This includes the collection of hydrological data and the use of bromide and water stable isotopes (δ²H and δ¹⁸O) as tracers. With their help, mixing models were established, and daily water balances were assessed. The results show a strong bidirectional interaction of both LSWB systems with shallow groundwater. Bromide and stable isotope tracers allowed for the identification of the most relevant in- and outflow sources and pathways. Thereby, isotope data revealed isotopic enrichment typical for open-water bodies and only minor precipitation inputs mainly relevant at the end of the dry season. Water balance calculations suggested accentuated seasonal dynamics that were strongly influenced by shallow groundwater, which represented large inputs into both LSWB. By that, different phases could be identified, with high inflow rates in winter and spring and decreasing fluxes in summer. In one LSWB, a drainage system was found to have a major impact next to the shallow groundwater interaction. The findings of this research provide detailed insights into the influence and importance of shallow groundwater for LSWB in lowland regions. This impacts the diffuse input of agricultural pollutants into these ecologically important landscape features.     

The orientation of magnetic fields in quiescent prominences

We have measured the longitudinal component, B, of the magnetic field in quiescent prominences and obtained a relationship between B and , where is the angle between the long axis of the prominence and the north-south direction on the sun. From this relationship we deduce a distribution function for the magnetic field vector in quiescent prominences in terms of the angle between the field and the long axis of the prominence. The mean angle, , for our data is small, - 15°, indicating that the magnetic field traverses quiescent prominences under a small, but finite angle.On leave from Max-Planck Institut für Physik und Astrophysik, München.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Parameters of quiescent prominences derived from magnetic field measurements

Based upon the new magnetic field vector measurements of Bommieret al. (1994) we construct prominence models which are in magnetohydrostatic equilibrium. We compare these new models with earlier ones and find that they are on average more massive and also considerably narrower.     

Spectral investigation of chromospheric fine structure

H spectra and effectively simultaneous filtergrams were taken at the Fraunhofer Observatory on Capri with the 35 cm domeless Coudé. The spatial resolution of the 19 best spectra selected for analysis was estimated to be 1–2 arc sec. The comparison of several hundred H line profiles emitted by typical chromospheric structure elements with theoretical prediction yielded strong evidence to suggest that the chromosphere consists of two parts: A lower, rather uniform layer at rest superposed by clouds (condensations of great spatial variability) which constitute the well-known structure pattern of H filtergrams. For most image points the line-of-sight velocity, optical thickness, source function and Doppler broadening of these clouds could be determined. While the values of the latter three quantities were found to be similar to what Beckers (1968) has found for limb spicules the velocity of the bright and of the dark mottles is considerably smaller than to be expected if these features were the spicules as seen on the disk. However, our results do not rule out the possibility that the spicules rise at the centers of rosettes where they are difficult to detect.Mitteilung aus dem Fraunhofer Institut No. 105.     

Observations of chromospheric lines from OSO-8

The line profiles of L, Ca ii K and Mg iik were measured with the spectrometer of the Laboratoire de Physique Stellaire et Planétaire on board of OSO-8. The results of these measurements are presented.Mitteilungen aus dem Kiepenheuer-Institut Nr. 181.