Future impacts of global warming and reforestation on drought patterns over West Africa

This study investigates how a large-scale reforestation in Savanna (8–12°N, 20°W–20°E) could affect drought patterns over West Africa in the future (2031–2060) under the RCP4.5 scenario. Simulations from two regional climate models (RegCM4 and WRF) were analyzed for the study. The study first evaluated the performance of both RCMs in simulating the present-day climate and then applied the models to investigate the future impacts of global warming and reforestation on the drought patterns. The simulated and observed droughts were characterized with the Standardized Precipitation and Evapotranspiration Index (SPEI), and the drought patterns were classified using a Self-organizing Map (SOM) technique. The models capture essential features in the seasonal rainfall and temperature fields (including the Saharan Heat Low), but struggle to reproduce the onset and retreat of the West African Monsoon as observed. Both RCMs project a warmer climate (about 1–2 °C) over West Africa in the future. They do not reach a consensus on future change in rainfall, but they agree on a future increase in frequency of severe droughts (by about 2 to 9 events per decade) over the region. They show that reforestation over the Savanna could reduce the future warming by 0.1 to 0.8 °C and increase the precipitation by 0.8 to 1.2 mm per day. However, the impact of reforestation on the frequency of severe droughts is twofold. While reforestation decreases the droughts frequency (by about 1–2 events per decade) over the Savanna and Guinea coast, it increases droughts frequency (by 1 event per decade) over the Sahel, especially in July to September. The results of this study have application in using reforestation to mitigate impacts of climate change in West Africa.     

An experimental study of the titanomagnetite solid solution series

Summary Analysis of saturation magnetization measurements and data from the literature indicate that the cation distribution in the titanomagnetite solid solution series is temperature dependent. The ionic configuration of ferric and ferrous ions on both lattice sites of their spinel structure can be described by a modified Boltzmann relation in agreement with theoretical consideratios. Thermodynamic equilibrium isotherms for the cation distribution and the resulting variation of saturation magnetization are calculated on the basis of the experimental values. These results should be especially valuable for the interpretation of magnetic properties of rapidly cooled igneous rock units where a respective high-temperature metastable state may exist in the magnetic ore component.Further measurements of the Curie temperature and lattice constant did not confirm a similar effect. Both these parameters should therefore be qualified for the identification of naturally occurring titanomagnetites.     

Prediction of algal growth in batch cultures

The growth of algae in batch cultures is often well characterized by the logistic growth function. The equation used contents three parameters which have to be estimated. Two methods are presented: The linearizing procedure, and the direct method of least squares. We give an example for comparing several logistic growth curves.     

Imaging DOAS for volcanological applications

The simultaneous quantitative determination of two-dimensional bromine monoxide (BrO) and sulphur dioxide (SO₂) distributions in volcanic gas plumes is described. Measurements at the fumarolic field on the island Vulcano (autumn 2004) and in the plume of Mt. Etna volcano (spring 2005) were carried out with an Imaging DOAS instrument. The SO₂ fluxes of several fumaroles were estimated from two-dimensional distributions of SO₂. Additionally, the first two-dimensional distributions of BrO within a volcanic plume were successfully retrieved. Slant column densities of up to 2.6 × 10¹⁴ molecules per square centimetre were detected in the plume of Mt. Etna. The investigation of the BrO/SO₂ ratio, calculated from the two-dimensional distributions of SO₂ and BrO, shows an increase from the centre to the edge of the volcanic plume. These results have significance for the involvement of ozone during BrO formation processes in volcanic emissions.     

Assessment of Primary Production by Statistical Analysis of Water‐quality Data

Time series of weekly water‐quality data at Schnackenburg on the Elbe River (1985—2000) were subjected to principal component analysis (PCA). Considering the amplitudes of composite patterns of variables is a step towards a process‐oriented interpretation of waterquality data. One specific objective was to investigate the impact of improved water quality after the German reunification in 1990 on primary production and the oxygen budget. To discriminate anthropogenic signals from natural fluctuations a separation of the impact of discharge was attempted based on a linear regression approach. A dominant pattern of co‐variation in the residual data could be attributed to biological activity (primary production). The most relevant variables of this 'biomode' are oxygen saturation, pH, and orthophosphate. We conclude that multivariate statistical analysis of water‐quality data can help to estimate primary production when direct observations of algal concentrations are missing. In the years from 1998—2000 the trend of the ‘biomode’ indicates an increased load of oxygen consuming biomass caused by enhanced primary production in the middle stretches of the Elbe River which corresponds with the observation of more severe oxygen deficits in the tidal section of the river.     

The Rožná uranium deposit (Bohemian Massif, Czech Republic): shear zone-hosted, late Variscan and post-Variscan hydrothermal mineralization

Three major mineralization events are recorded at the Rožná uranium deposit (total mine production of 23,000 t U, average grade of 0.24% U): (1) pre-uranium quartz-sulfide and carbonate-sulfide mineralization, (2) uranium, and (3) post-uranium quartz-carbonate-sulfide mineralization. (1) K–Ar ages for white mica from wall rock alteration of the pre-uranium mineralization style range from 304.5 ± 5.8 to 307.6 ± 6.0 Ma coinciding with the post-orogenic exhumation of the Moldanubian orogenic root and retrograde-metamorphic equilibration of the high-grade metamorphic host rocks. The fluid inclusion record consists of low-salinity aqueous inclusions, together with H₂O-CO₂-CH₄, CO₂-CH₄, and pure CH₄ inclusions. The fluid inclusion, paragenetic, and isotope data suggest that the pre-uranium mineralization formed from a reduced low-salinity aqueous fluid at temperatures close to 300°C. (2) The uraniferous hydrothermal event is subdivided into the pre-ore, ore, and post-ore substages. K–Ar ages of pre-ore authigenic K-feldspar range from 296.3 ± 7.5 to 281.0 ± 5.4 Ma and coincide with the transcurrent reorganization of crustal blocks of the Bohemian Massif and with Late Stephanian to Early Permian rifting. Massive hematitization, albitization, and desilicification of the pre-ore altered rocks indicate an influx of oxidized basinal fluids to the crystalline rocks of the Moldanubian domain. The wide range of salinities of fluid inclusions is interpreted as a result of the large-scale mixing of basinal brines with meteoric water. The cationic composition of these fluids indicates extensive interaction with crystalline rocks. Chlorite thermometry yielded temperatures of 260°C to 310°C. During this substage, uranium was probably leached from the Moldanubian crystalline rocks. The hydrothermal alteration of the ore substage followed, or partly overlapped in time, the pre-ore substage alteration. K–Ar ages of illite from ore substage alteration range from 277.2 ± 5.5 to 264.0 ± 4.3 Ma and roughly correspond with the results of chemical U–Pb dating of authigenic monazite (268 ± 50 Ma). The uranium ore deposition was accompanied by large-scale decomposition of biotite and pre-ore chlorite to Fe-rich illite and iron hydrooxides. Therefore, it is proposed that the deposition of uranium ore was mostly in response to the reduction of the ore-bearing fluid by interaction with ferrous iron-bearing silicates (biotite and pre-ore chlorite). The Th data on primary, mostly aqueous, inclusions trapped in carbonates of the ore substage range between 152°C and 174°C and total salinity ranges over a relatively wide interval of 3.1 to 23.1 wt% NaCl eq. Gradual reduction of the fluid system during the post-ore substage is manifested by the appearance of a new generation of authigenic chlorite and pyrite. Chlorite thermometry yielded temperatures of 150°C to 170°C. Solid bitumens that post-date uranium mineralization indicate radiolytic polymerization of gaseous and liquid hydrocarbons and their derivatives. The origin of the organic compounds can be related to the diagenetic and catagenetic transformation of organic matter in Upper Stephanian and Permian sediments. (3) K–Ar ages on illite from post-uranium quartz-carbonate-sulfide mineralization range from 233.7 ± 4.7 to 227.5 ± 4.6 Ma and are consistent with the early Tethys-Central Atlantic rifting and tectonic reactivation of the Variscan structures of the Bohemian Massif. A minor part of the late Variscan uranium mineralization was remobilized during this hydrothermal event.