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121.
122.
Jin Qian Ulf Skyllberg Wolfgang FrechWilliam F Bleam Paul R Bloom Pierre Emmanuel Petit 《Geochimica et cosmochimica acta》2002,66(22):3873-3885
We combined synchrotron-based X-ray absorption near edge structure (XANES) spectroscopy, extended X-ray absorption fine structure (EXAFS) spectroscopy and binding affinity studies to determine the coordination, geometry, and strength of methyl mercury, CH3Hg (II), bonding in soil and stream organic matter. Samples of organic soil (OS), potentially soluble organic substances (PSOS) from the soil, and organic substances from a stream (SOS) draining the soil were taken along a short “hydrological transect.” We determined the sum of concentrations of highly reduced organic S groups (designated Org-SRED), such as thiol (RSH), disulfane (RSSH), sulfide (RSR), and disulfide (RSSR), using sulfur K-edge XANES. Org-SRED varied between 27% and 64% of total S in our samples. Hg LIII-edge EXAFS analysis were determined on samples added CH3Hg (II) to yield CH3Hg (II)/Org-SRED ratios in the range 0.01-1.62. At low ratios, Hg was associated to one C atom (the methyl group) at an average distance of 2.03 ± 0.02 Å and to one S atom at an average distance of 2.34 ± 0.03 Å, in the first coordination shell. At calculated CH3Hg(II)/Org-SRED ratios above 0.37 in OS, 0.32 in PSOS, and 0.24 in SOS, the organic S sites were saturated by CH3Hg+, and O (and/or N) atoms were found in the first coordination shell of Hg at an average distance of 2.09 ± 0.01 Å. Based on the assumption that RSH (and possibly RSSH) groups take part in the complexation of CH3Hg+, whereas RSSR and RSR groups do not, approximately 17% of total organic S consisted of RSH (+ RSSH) functionalities in the organic soil. Corresponding figures for samples PSOS and SOS were 14% and 9%, respectively. Competitive complexation of CH3Hg+ by halide ions was used to determine the average binding strength of native concentrations of CH3Hg (II) in the OS sample. Using data for Org-SRED, calculated surface complexation constants were in the range from 1016.3 to 1016.7 for a model RSH site having an acidity constant of mercaptoacetic acid. These values compare favorably with identically defined stability constants (log K1) for the binding of methyl mercury to thiol groups in well-defined organic compounds. 相似文献
123.
Black shale is often rich in sulfides and trace elements, and is thus a potential environmental threat in a manner similar to acid sulfate soils and active or abandoned sulfide mines. This study aims at characterising how exposed and processed (mined and burnt) black shale (alum shale) in Degerhamn, SE Sweden, affects the chemistry (Al, As, Ba, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Si, Na, Sr, S, U, V and Zn) of the groundwater. There were large variations in groundwater chemistry between nearby sampling points, while the temporal variations generally were small. Acidic groundwater (around pH 4), found in deposits of burnt and carbonate-poor shale where the conditions for sulfide oxidation were favourable, was strongly elevated in Al, U and several chalcophilic metals (Cd, Co, Cu, Ni and Zn). Cadmium and U were also, together with Mo, abundant in many of the near-neutral waters, both in the non-mined black shale bedrock and in the deposits of burnt shale. An extrapolation to a national level suggests that the dispersion of Ni from naturally occurring black shale is similar to that from anthropogenic point sources, while for Cd and As it is assessed to be approximately one tenth of that from point sources. The processed shale was, however, a much larger source of metals than the black shale bedrock itself, showing this material’s potential as a massive supplier of metals to the aquatic environment. A comparison of waters in contact with the processed Cambrian–Ordovician black shale in Degerhamn and acid sulfate soils of the region shows that these two sulfide-bearing materials, in many respects very different, delivers basically the same suite of trace elements to the aquatic environment. This has implications for environmental planning and protection in areas where these types of materials exist. 相似文献
124.
Regional desertification: A global synthesis 总被引:3,自引:0,他引:3
The paper presents results on the use of NOAA AVHRR data for desertification monitoring on a regional–global level. It is based on processing of the GIMMS 8 km global NDVI data set. Time series of annually integrated and standardized annual NDVI anomalies were generated and compared with a corresponding rainfall data set (1981–2003).The regions studied include the Mediterranean basin, the Sahel from the Atlantic to the Red Sea, major parts of the drylands of Southern Africa, China–Mongolia and the drylands of South America, i.e. important parts of the desertification prone drylands of the world.It is concluded that the suggested methodology is a robust and reliable way to assess and monitor vegetation trends and related desertification on a regional–global scale. A strong general relationship between NDVI and rainfall over time is demonstrated for considerable parts of the drylands. The results of performed trend analysis cannot be used to verify any systematic generic land degradation/desertification trend at the regional–global level. On the contrary, a “greening-up” seems to be evident over large regions. 相似文献
125.
Marius N. Müller Ba?ak K?sakürek Ruth Gutperlet Ulf Riebesell Anton Eisenhauer 《Geochimica et cosmochimica acta》2011,75(8):2088-5818
Calcium and magnesium concentrations in seawater have varied over geological time scales. On short time scales, variations in the major ion composition of seawater influences coccolithophorid physiology and the chemistry of biogenically produced coccoliths. Validation of those changes via controlled laboratory experiments is a crucial step in applying coccolithophorid based paleoproxies for the reconstruction of past environmental conditions. Therefore, we examined the response of two species of coccolithophores, Emiliania huxleyi and Coccolithus braarudii, to changes in the seawater Mg/Ca ratio (≈0.5 to 10 mol/mol) by either manipulating the magnesium or calcium concentration under controlled laboratory conditions. Concurrently, seawater Sr/Ca ratios were also modified (≈2 to 40 mmol/mol), while keeping salinity constant at 35. The physiological response was monitored by measurements of the cell growth rate as well as the production rates of particulate inorganic and organic carbon, and chlorophyll a. Additionally, coccolithophorid calcite was analyzed for its elemental composition (Sr/Ca and Mg/Ca) as well as isotope fractionation of calcium and magnesium (Δ44/40Ca and Δ26/24Mg). Our results reveal that physiological rates were substantially influenced by changes in seawater calcium rather than magnesium concentration within the range estimated to have occurred over the past 250 million years when coccolithophores appear in the fossil record. All physiological rates of E. huxleyi decreased at a calcium concentration above 25 mmol L−1, whereas C. braarudii displayed a higher tolerance to increased seawater calcium concentrations. Partition coefficient of Sr was calculated as 0.36 ± 0.04 (±2σ) independent of species. Partition coefficient of Mg2+ increased with increasing seawater Ca2+ concentrations in both coccolithophore species. Calcium isotope fractionation was constant at 1.1 ± 0.1‰ (±2σ) and not altered by changes in seawater Mg/Ca ratio. There is a well-defined inverse linear relationship between calcium isotope fractionation and partition coefficient of Sr2+ in all experiments, suggesting similar controls on both proxies in the investigated species. Magnesium isotope ratios were relatively stable for seawater Mg/Ca ratios ranging from 1 to 5, with a higher degree of fractionation in Emiliania huxleyi (by ≈0.2‰ in Δ26/24Mg). Although Mg/Ca ratios in the calcite of coccolithophores and foraminifera are similar, the former have considerably higher Δ26/24Mg (by >+3‰), presumably due to differences in calcification mechanisms between the two taxa. These observations suggest, a physiological control over magnesium elemental and isotopic fractionation during the process of calcification in coccolithophores. 相似文献
126.
Anne Randi Syversveen Ragnar Hauge Jan Inge Tollefsrud Ulf Lægreid Alister MacDonald 《Mathematical Geosciences》2011,43(7):763-781
We present an approach for modeling facies bodies in which a highly constrained stochastic object model is used to integrate
detailed seismic interpretation of the reservoir’s sedimentological architecture directly in a three-dimensional reservoir
model. The approach fills the gap between the use of seismic data in a true deterministic sense, in which the facies body
top and base are resolved and mapped directly, and stochastic methods in which the relationship between seismic attributes
and facies is defined by conditional probabilities. The lateral geometry of the facies bodies is controlled by seismic interpretations
on horizon slices or by direct body extraction, whereas facies body thickness and cross-sectional shape are defined by a mixture
of seismic data, well data, and user defined object shapes. The stochastic terms in the model are used to incorporate local
geometric variability, which is used to increase the geological realism of the facies bodies and allow for correct, flexible
well conditioning. The result is a set of three-dimensional facies bodies that are constrained to the seismic interpretations
and well data. Each body is defined as a parametric object that includes information such as location of the body axis, depositional
direction, axis-to-margin normals, and external body geometry. The parametric information is useful for defining geologically
realistic intrabody petrophysical trends and for controlling connectivity between stacked facies bodies. 相似文献
127.
Rob A. Strachan Ulf Linnemann Teresa Jeffries Kerstin Drost Jens Ulrich 《International Journal of Earth Sciences》2014,103(5):1359-1383
Devonian sedimentary rocks of the Meneage Formation within the footwall of the Lizard ophiolite complex in SW England are thought to have been derived from erosion of the over-riding Armorican microplate during collision with Avalonia and the closure of the Rheic Ocean. We further test this hypothesis by comparison of their detrital zircon suites with those of autochthonous Armorican strata. Five samples analysed from SW England (Avalonia) and NW France (Armorica) have a bimodal U–Pb zircon age distribution dominated by late Neoproterozoic to middle Cambrian (c. 710–518 Ma) and Palaeoproterozoic (c. 1,800–2,200 Ma) groupings. Both can be linked with lithologies exposed within the Cadomian belt as well as the West African craton, which is characterized by major tectonothermal events at 2.0–2.4 Ga. The detrital zircon signature of Avalonia is distinct from that of Armorica in that there is a much larger proportion of Mesoproterozoic detritus. The common provenance of the samples is therefore consistent with: (a) derivation of the Meneage Formation mélange deposits from the Armorican plate during Rheic Ocean closure and obduction of the Lizard Complex and (b) previous correlation of quartzite blocks within the Meneage Formation with the Ordovician Grès Armoricain Formation of NW France. 相似文献
128.
Ulf Högström Anna Rutgersson Erik Sahlée Ann-Sofi Smedman Tihomir S. Hristov W. M. Drennan K. K. Kahma 《Boundary-Layer Meteorology》2013,147(1):139-163
A systematic comparison of wind profiles and momentum exchange at a trade wind site outside Oahu, Hawaii and corresponding data from the Baltic Sea is presented. The trade wind data are to a very high degree swell dominated, whereas the Baltic Sea data include a more varied assortment of wave conditions, ranging from a pure growing sea to swell. In the trade wind region swell waves travel predominantly in the wind direction, while in the Baltic, significant cross-wind swells are also present. Showing the drag coefficient as a function of the 10-m wind speed demonstrates striking differences for unstable conditions with swell for the wind-speed range 2 m s?1 < U 10 < 7 m s?1, where the trade-wind site drag values are significantly larger than the corresponding Baltic Sea values. In striking contrast to this disagreement, other features studied are surprisingly similar between the two sites. Thus, exactly as found previously in Baltic Sea studies during unstable conditions and swell, the wind profile in light winds (3 m s?1) shows a wind maximum at around 7–8 m above the water, with close to constant wind speed above. Also, for slightly higher wind speeds (4 m s?1 < U 10 < 7 m s?1), the similarity between wind profiles is striking, with a strong wind-speed increase below a height of about 7–8 m followed by a layer of virtually constant wind speed above. A consequence of these wind-profile features is that Monin–Obukhov similarity is no longer valid. At the trade-wind site this was observed to be the case even for wind speeds as high as 10 m s?1. The turbulence kinetic energy budget was evaluated for four cases of 8–16 30- min periods at the trade-wind site, giving results that agree very well with corresponding figures from the Baltic Sea. 相似文献
129.
130.
Jan Esper Lara Klippel Paul J. Krusic Oliver Konter Christoph C. Raible Elena Xoplaki Jrg Luterbacher Ulf Bntgen 《Climate Dynamics》2020,54(3):1367-1382
The Mediterranean has been identified as particularly vulnerable to climate change, yet a high-resolution temperature reconstruction extending back into the Medieval Warm Period is still lacking. Here we present such a record from a high-elevation site on Mt. Smolikas in northern Greece, where some of Europe’s oldest trees provide evidence of warm season temperature variability back to 730 CE. The reconstruction is derived from 192 annually resolved, latewood density series from ancient living and relict Pinus heldreichii trees calibrating at r1911–2015 = 0.73 against regional July–September (JAS) temperatures. Although the recent 1985–2014 period was the warmest 30-year interval (JAS Twrt.1961–1990 = + 0.71 °C) since the eleventh century, temperatures during the ninth to tenth centuries were even warmer, including the warmest reconstructed 30-year period from 876–905 (+ 0.78 °C). These differences between warm periods are statistically insignificant though. Several distinct cold episodes punctuate the Little Ice Age, albeit the coldest 30-year period is centered during high medieval times from 997–1026 (− 1.63 °C). Comparison with reconstructions from the Alps and Scandinavia shows that a similar cold episode occurred in central Europe but was absent at northern latitudes. The reconstructions also reveal different millennial-scale temperature trends (NEur = − 0.73 °C/1000 years, CEur = − 0.13 °C, SEur = + 0.23 °C) potentially triggered by latitudinal changes in summer insolation due to orbital forcing. These features, the opposing millennial-scale temperature trends and the medieval multi-decadal cooling recorded in Central Europe and the Mediterranean, are not well captured in state-of-the-art climate model simulations. 相似文献