Metal dispersion in groundwater in an area with natural and processed black shale – Nationwide perspective and comparison with acid sulfate soils

Black shale is often rich in sulfides and trace elements, and is thus a potential environmental threat in a manner similar to acid sulfate soils and active or abandoned sulfide mines. This study aims at characterising how exposed and processed (mined and burnt) black shale (alum shale) in Degerhamn, SE Sweden, affects the chemistry (Al, As, Ba, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Si, Na, Sr, S, U, V and Zn) of the groundwater. There were large variations in groundwater chemistry between nearby sampling points, while the temporal variations generally were small. Acidic groundwater (around pH 4), found in deposits of burnt and carbonate-poor shale where the conditions for sulfide oxidation were favourable, was strongly elevated in Al, U and several chalcophilic metals (Cd, Co, Cu, Ni and Zn). Cadmium and U were also, together with Mo, abundant in many of the near-neutral waters, both in the non-mined black shale bedrock and in the deposits of burnt shale. An extrapolation to a national level suggests that the dispersion of Ni from naturally occurring black shale is similar to that from anthropogenic point sources, while for Cd and As it is assessed to be approximately one tenth of that from point sources. The processed shale was, however, a much larger source of metals than the black shale bedrock itself, showing this material’s potential as a massive supplier of metals to the aquatic environment. A comparison of waters in contact with the processed Cambrian–Ordovician black shale in Degerhamn and acid sulfate soils of the region shows that these two sulfide-bearing materials, in many respects very different, delivers basically the same suite of trace elements to the aquatic environment. This has implications for environmental planning and protection in areas where these types of materials exist.     

Regional desertification: A global synthesis

The paper presents results on the use of NOAA AVHRR data for desertification monitoring on a regional–global level. It is based on processing of the GIMMS 8 km global NDVI data set. Time series of annually integrated and standardized annual NDVI anomalies were generated and compared with a corresponding rainfall data set (1981–2003).The regions studied include the Mediterranean basin, the Sahel from the Atlantic to the Red Sea, major parts of the drylands of Southern Africa, China–Mongolia and the drylands of South America, i.e. important parts of the desertification prone drylands of the world.It is concluded that the suggested methodology is a robust and reliable way to assess and monitor vegetation trends and related desertification on a regional–global scale. A strong general relationship between NDVI and rainfall over time is demonstrated for considerable parts of the drylands. The results of performed trend analysis cannot be used to verify any systematic generic land degradation/desertification trend at the regional–global level. On the contrary, a “greening-up” seems to be evident over large regions.     

The zircon evidence of temporally changing sediment transport—the NW Gondwana margin during Cambrian to Devonian time (Aoucert and Smara areas,Moroccan Sahara)

International Journal of Earth Sciences - Detrital zircon provenance studies are an established tool to develop palaeogeographic models, mostly based on zircon of siliciclastic rocks and isotope...     

Hydrogeochemical Processes in the Kafue River upstream from the Copperbelt Mining Area, Zambia

Frequent sampling during an annual cycle of dissolved(<0.45 m) and suspended (>0.45 m) elementshas been conducted in the Kafue River at Raglan'sFarm, upstream from the mining activities within theCopperbelt Province, Zambia. Additional sampling ofsediment and interstitial pore water was conductedduring low water discharge. The presence of carbonateswithin the drainage basin naturally gives rise to highelement concentrations in the dissolved phase(Ca = 626, Mg = 494, Na = 360 and K = 24 mmol l^-1).During the rainy season the relative composition ofthe dissolved elements indicated a wash out ofaccumulated weathering products and mineralisedorganic material from the unsaturated zone of the soilprofile. High concentrations of dissolved Al, Fe andMn were measured during high water discharge. At lowwater discharge the sediment was a major source of Fe,Mn and associated Co and Cu to the water column.Enhanced concentrations of dissolved and suspended S,Co and Cu during the rainy season indicated thatatmospheric deposited particles from the mining areawere washed out into the river. Autochthonousformation of particles rich in Si indicated diatomproduction during low water discharge.     

New data on the Neoproterozoic – Cambrian geotectonic setting of the Teplá-Barrandian volcano-sedimentary successions: geochemistry,U-Pb zircon ages,and provenance (Bohemian Massif,Czech Republic)

The Teplá-Barrandian unit (TBU) of the Bohemian Massif was a part of the Avalonian-Cadomian belt at the northern margin of Gondwana during Neoproterozoic and Early Cambrian times. New detrital zircon ages and geochemical compositions of Late Neoproterozoic siliciclastic sediments confirm a deposition of the volcano-sedimentary successions of the TBU in a back-arc basin. A change in the geotectonic regime from convergence to transtension was completed by the time of the Precambrian-Cambrian boundary. The accumulation of around 2,500 m Lower Cambrian continental siliciclastics in a Basin-and-Range-type setting was accompanied by magmatism, which shows within-plate features in a few cases, but is predominantly derived from anatectic melts displaying the inherited island arc signature of their Cadomian source rocks. The geochemistry of clastic sediments suggests a deposition in a rift or strike-slip-related basin, respectively. A marine transgression during Middle Cambrian times indicates markedly thinned crust after the Cadomian orogeny. Upper Cambrian magmatism is represented by 1,500 m of subaerial andesites and rhyolites demonstrating several geochemical characteristics of an intra-plate setting. Zircons from a rhyolite give a U-Pb-SHRIMP age of 499±4 Ma. The Cambrian sedimentary and magmatic succession of the TBU records the beginning of an important rifting event at the northern margin of Gondwana.

West African provenance for Saxo-Thuringia (Bohemian Massif): Did Armorica ever leave pre-Pangean Gondwana? – U/Pb-SHRIMP zircon evidence and the Nd-isotopic record

Neoproterozoic rocks in the Saxo-Thuringian part of Armorica formed in an active margin setting and were overprinted during Cadomian orogenic processes at the northern margin of Gondwana. The Early Palaeozoic overstep sequence in Saxo-Thuringia was deposited in a Cambro-Ordovician rift setting that reflects the separation of Avalonia and other terranes from the Gondwana mainland. Upper Ordovician and Silurian to Early Carboniferous shelf sediments of Saxo-Thuringia were deposited at the southern passive margin of the Rheic Ocean. SHRIMP U/Pb geochronology on detrital and inherited zircon grains from pre-Variscan basement rocks of the northern part of the Bohemian Massif (Saxo-Thuringia, Germany) demonstrates a distinct West African provenance for sediments and magmatic rocks in this part of peri-Gondwana. Nd-isotope data of Late Neoproterozoic to Early Carboniferous sedimentary rocks show no change in sediment provenance from the Neoproterozoic to the Lower Carboniferous, which implies that Saxo-Thuringia did not leave its West African source before the Variscan Orogeny leading to the Lower Carboniferous configuration of Pangea. Hence, large parts of the pre-Variscan basement of Western and Central Europe often referred to as Armorica or Armorican Terrane Assemblage may have remained with Africa in pre-Pangean time, which makes Armorica a remnant of a Greater Africa in Gondwanan Europe. The separation of Armorica from the Gondwana mainland and a long drift during the Palaeozoic is not supported by the presented data.     

Precious-metal distribution and fluid-inclusion petrography of the Elatsite porphyry copper deposit,Bulgaria

The Elatsite porphyry copper deposit occurs in an island-arc setting hosted by Late Cretaceous monzonitic-monzodioritic porphyry stocks which were emplaced into Precambrian-Cambrian phyllites. Trace element data of the Late Cretaceous intrusive rocks suggest that they are I-type volcanic arc granitoids. Two main ore mineral assemblages are distinguished: (1) magnetite-bornite-chalcopyrite, and (2) chalcopyrite-pyrite. The first one is linked to potassic-propylitic, and the second to phyllic-argillic alteration. Minor ore minerals are hematite, molybdenite, sphalerite, pyrrhotite, marcasite, hessite, and solid solutions of linnaeite-siegenite-carrollite, tetrahedrite-tennantite, clausthalite-galena, gold-electrum and merenskyite-moncheite. Precious-metal contents are relatively high throughout the deposit but Au, Pd and Pt are concentrated more strongly in the magnetite-bornite-chalcopyrite assemblage. Average grades of Au, Ag, Pd and Pt calculated for the 0.33% Cu ore body are 0.96, 0.19, 0.007 and 0.002 g/t respectively. Analyses of flotation concentrates revealed 25.6% Cu, and Ag, Au, Pd and Pt contents of 33.0, 13.6, 0.72 and 0.15 g/t respectively. The copper mineralisation at Elatsite took place at pressures of 120 to 300 bar, corresponding to depths of formation of 1 to 3 km under hydrostatic conditions. The precious metals were probably transported jointly as chloride complexes in highly saline magmatic-hydrothermal solutions. The fluids had temperatures of 340 to >700 °C and salinities of 28 to 64% NaCl, and mixed with meteoric water.     

Lake Vostok Behaves Like A 'Captured Lake' and May Be Near To Creating An Antarctic Jökulhlaup

The most well known sub‐glacial lake is probably Grímsvötn under Vatnajökul, Iceland, from where jökulhlaups regularly burst forth. It is created by thermal melting under the ice cap. The Antarctic Lake Vostok, on the other hand, is considered to be located over a region with normal geothermal heat transfer, where it can exist because the ice is so thick that its base is at the pressure melting point. This makes it a candidate for testing the captured ice shelf (CIS) hypothesis, which states that the motion of a totally confined ice shelf creates a hydrostatic seal in the form of an ice rim over the threshold. The CIS hypothesis may offer a source of water for the controversial Laurentian jökulhlaups inferred from field data, implicated in dramatic climatic changes. Here I show that Lake Vostok agrees with the hypothesis, and that it may be on the verge of a jökulhlaup, which could create an ice stream and regional downdraw. The result also implies that the lake may well be of pre‐glacial origin, and that it may have experienced jökulhlaups during previous interglacials.     

Fluid-dynamics driving saline water in the North East German Basin

In several areas of the North German Basin, saline water comes close to, or even reaches the surface. Available data from wells indicate that brine stratification is under unstable conditions in the deeper underground. In order to analyse the possible transport mechanisms, 3D thermohaline simulations have been carried out for two different scenarios. The 3D regional model (230×330 km) indicates that salty water is driven to the surface by hydrostatical forces from the surrounding highlands. In addition, a smaller scale model (10×10 km) has been constructed with a grid resolution accounting for possible convective flow. The results indicate that convective flow may play a dominant role in areas with minor topography. In summary, the complex pattern of near surface occurrences of saline water probably results from the interaction of hydrostatic and thermal forces.