Salinization of groundwater in the North German Basin: results from conjoint investigation of major, trace element and multi-isotope distribution

Conjoint consideration of distribution of major, rare earth elements (REE) and Y (combined to REY) and of H, O, C, S, Sr isotopes reveals that four types of groundwater are distinguishable by their chemical composition presented by spider patterns. REY patterns indicate thermo-saline deep water and two types of shallow saline groundwaters. Presence of connate waters is not detectable. Sr isotope ratios distinguish three sources of Sr: fast and slow weathering of biotite and K-feldspar in Pleistocene sediments, respectively, and dissolution of limestones. δ¹³C(DIC) indicate dissolution of limestone under closed and open system conditions. Numerous samples show δ¹³C(DIC) > 13‰ which is probably caused by incongruent dissolution of calcite and dolomite. The brines from below 1,000 m represent mixtures of pre-Pleistocene seawater or its evaporation brines and infiltrated post-Pleistocene precipitation. The shallow waters represent mixtures of Pleistocene and Recent precipitation salinized by dissolution of evaporites or by mixing with ascending brines. The distribution of water types is independent on geologic units and lithologies. Even the Tertiary Rupelian aquiclude does not prevent salinization of the upper aquifer.     

A large wet snow avalanche cycle in West Greenland quantified using remote sensing and in situ observations

Natural Hazards - On 11 April 2016 we observed high slushflow and wet snow avalanche activity at the environmental monitoring station Kobbefjord in W-Greenland. Snow avalanches released as a result...     

First U–Pb geochronology on detrital zircons from Early-Middle Cambrian strata of the Torgau-Doberlug Syncline (eastern Germany) and palaeogeographic implications

International Journal of Earth Sciences - LA-ICP-MS U–Pb data from detrital zircons of the Ediacaran to Cambrian siliciclastic sequence of the Torgau-Doberlug Syncline (TDS, Saxo-Thuringia,...     

A Note on Velocity Spectra in the Marine Boundary Layer

Spectra of longitudinal and vertical velocity have been studied at a marine site, östergarnsholm, in the Baltic Sea during a period of six days with near-neutral or slightly unstable conditions, when the wave state gradually changed from pure wind sea to strong swell having approximately the same direction as the wind. During the pure wind sea phase, spectra are shown to adhere closely to general forms for the neutral atmospheric surface layer obtained from a new theory. As soon as the wave age goes slightly beyond that representative of pure wind sea conditions, the spectra deviate in shape from the ideal forms. The spectral modification appears to start at a frequency typical of the swell component. As the wave age increases, it progresses in frequency as a downscale cascade, which is particularly prominent in the spectrum of the vertical component but which is also observed in the longitudinal component. In addition, there is a strong effect in the low-frequency part of the spectra. It is interpreted as an indirect effect of large-scale inactive turbulence, which becomes progressively more important as wave-age increases. It is found that the ratio of the spectrum of the vertical component and the spectrum of the corresponding longitudinal component attains the theoretically predicted value of 4/3 for cases of developing sea (gale force wind) for frequencies above approximately 4 Hz but never much exceeds unity for cases with swell. It is argued that this is an indication of local anisotropy and that the inertial-dissipation method for determination of the momentum flux is inappropriate in the case of mixed seas or swell.     

Gravity signals from the lithosphere in the Central European Basin System

We study the gravity signals from different depth levels in the lithosphere of the Central European Basin System (CEBS). The major elements of the CEBS are the Northern and Southern Permian Basins which include the Norwegian–Danish Basin (NDB), the North-German Basin (NGB) and the Polish Trough (PT). An up to 10 km thick sedimentary cover of Mesozoic–Cenozoic sediments, hides the gravity signal from below the basin and masks the heterogeneous structure of the consolidated crust, which is assumed to be composed of domains that were accreted during the Paleozoic amalgamation of Europe. We performed a three-dimensional (3D) gravity backstripping to investigate the structure of the lithosphere below the CEBS.Residual anomalies are derived by removing the effect of sediments down to the base of Permian from the observed field. In order to correct for the influence of large salt structures, lateral density variations are incorporated. These sediment-free anomalies are interpreted to reflect Moho relief and density heterogeneities in the crystalline crust and uppermost mantle. The gravity effect of the Moho relief compensates to a large extent the effect of the sediments in the CEBS and in the North Sea. Removal of the effects of large-scale crustal inhomogeneities shows a clear expression of the Variscan arc system at the southern part of the study area and the old crust of Baltica further north–east. The remaining residual anomalies (after stripping off the effects of sediments, Moho topography and large-scale crustal heterogeneities) reveal long wavelength anomalies, which are caused mainly by density variations in the upper mantle, though gravity influence from the lower crust cannot be ruled out. They indicate that the three main subbasins of the CEBS originated on different lithospheric domains. The PT originated on a thick, strong and dense lithosphere of the Baltica type. The NDB was formed on a weakened Baltica low-density lithosphere formed during the Sveco-Norwegian orogeny. The major part of the NGB is characterized by high-density lithosphere, which includes a high-velocity lower crust (relict of Baltica passive margin) overthrusted by the Avalonian terrane. The short wavelength pattern of the final residuals shows several north–west trending gravity highs between the Tornquist Zone and the Elbe Fault System. The NDB is separated by a gravity low at the Ringkøbing–Fyn high from a chain of positive anomalies in the NGB and the PT. In the NGB these anomalies correspond to the Prignitz (Rheinsberg anomaly), the Glueckstadt and Horn Graben, and they continue further west into the Central Graben, to join with the gravity high of the Central North Sea.     

An EELS study of near edge structures of the oxygen K-edge in spinels

Spectra of seven aluminate, ferrite and chromate spinels were collected at the oxygen K-edge in order to examine the effect of octahedral ion composition on the near edge structures and explore whether these may shed some light on previously reported major variations in the optical absorption coefficient (ε) for the spin-allowed d–d band transitions due to tetrahedrally coordinated Fe²⁺ in optical spectra of oxide spinels. Interpretation of the energy loss near edge structure (ELNES) spectra was aided using the multiple scattering code FEFF8.40. For the chromate samples spin polarised calculations were included. Gold’s iterative deconvolution method was utilized to improve on energy resolution, resulting in spectra equal in merit to those recorded by technically superior instruments. Results include absolute energy positions and interpretation of ELNES features in terms of transitions to available states. We conclude that the major causes of differences in the optical absorption coefficient mentioned above are hybridization between oxygen p- and octahedral metal orbitals. Our study does not support the idea presented by other authors that there exists a local antiferromagnetic ordering in MgCr₂O₄ at room temperature.     

High-resolution aquifer analog of fluvial–aeolian sediments of the Guarani aquifer system

The Guarani aquifer system (GAS) represents one of the biggest aquifers in the world and is the most relevant groundwater resource in South America. For the first time, by combining field and laboratory measurements, a high-resolution aquifer analog model of fluvial–aeolian sediments of the GAS in São Paulo State (Brazil) is constructed. Three parallel sections of frontal outcrops, 28 m × 5.8 m, and two parallel sections of lateral outcrops, 7 m × 5.8 m, are recorded during open-pit mining of sandy sediments and describe in detail the three-dimensional distribution of the local lithofacies and hydrofacies. Variations of hydraulic conductivity, K, and porosity, n, are resolved on the centimeter scale, and the most permeable units of the fluvial–aeolian facies association are identified. The constructed aquifer analog model shows moderate hydraulic heterogeneity and a mean K value of 1.36 × 10^?4 m/s, which is greater than the reported range of K values for the entire GAS in São Paulo State. The results suggest that the examined sedimentary unit constitutes a relevant portion of the GAS in São Paulo State in the context of groundwater extraction and pollution. Moreover, the constructed aquifer analog is considered an ideal basis for future numerical model experiments, aiming at in-depth understanding of the groundwater flow and contaminant transport patterns at this GAS portion or at comparable fluvial–aeolian facies associations.     

Precise U–Pb baddeleyite ages of mafic dykes and intrusions in southern West Greenland and implications for a possible reconstruction with the Superior craton

The Archaean block of southern Greenland constitutes the core of the North Atlantic craton (NAC) and is host to a large number of Precambrian mafic intrusions and dyke swarms, many of which are regionally extensive but poorly dated. For southern West Greenland, we present a U–Pb zircon age of 2990 ± 13 Ma for the Amikoq mafic–ultramafic layered intrusion (Fiskefjord area) and four baddeleyite U–Pb ages of Precambrian dolerite dykes. Specifically, a dyke located SE of Ameralik Fjord is dated at 2499 ± 2 Ma, similar to a previously reported ⁴⁰Ar/³⁹Ar age of a dyke in the Kangâmiut area. For these and related intrusions of ca. 2.5 Ga age in southern West Greenland, we propose the name Kilaarsarfik dykes. Three WNW-trending dykes of the MD3 swarm yield ages of 2050 ± 2 Ma, 2041 ± 3 Ma and 2029 ± 3 Ma. A similar U–Pb baddeleyite age of 2045 ± 2 Ma is also presented for a SE-trending dolerite (Iglusuataliksuak dyke) in the Nain Province, the rifted western block of the NAC in Labrador. We speculate that the MD3 dykes and age-equivalent NNE-trending Kangâmiut dykes of southern West Greenland, together with the Iglusuataliksuak dyke (after closure of the Labrador Sea) represent components of a single, areally extensive, radiating swarm that signaled the arrival of a mantle plume centred on what is presently the western margin of the North Atlantic craton. Comparison of the magmatic ‘barcodes’ from the Nain and Greenland portions of the North Atlantic craton with the established record from the north-eastern Superior craton shows matches at 2500 Ma, 2214 Ma, 2050–2030 Ma and 1960–1950 Ma. We use these new age constraints, together with orientations of the dyke swarms, to offer a preliminary reconstruction of the North Atlantic craton near the north-eastern margin of the Superior craton during the latest Archaean and early Palaeoproterozoic, possibly with the Core Zone craton of eastern Canada intervening.