Response of the coccolithophores Emiliania huxleyi and Coccolithus braarudii to changing seawater Mg and Ca concentrations: Mg/Ca, Sr/Ca ratios and δCa, δMg of coccolith calcite

Calcium and magnesium concentrations in seawater have varied over geological time scales. On short time scales, variations in the major ion composition of seawater influences coccolithophorid physiology and the chemistry of biogenically produced coccoliths. Validation of those changes via controlled laboratory experiments is a crucial step in applying coccolithophorid based paleoproxies for the reconstruction of past environmental conditions. Therefore, we examined the response of two species of coccolithophores, Emiliania huxleyi and Coccolithus braarudii, to changes in the seawater Mg/Ca ratio (≈0.5 to 10 mol/mol) by either manipulating the magnesium or calcium concentration under controlled laboratory conditions. Concurrently, seawater Sr/Ca ratios were also modified (≈2 to 40 mmol/mol), while keeping salinity constant at 35. The physiological response was monitored by measurements of the cell growth rate as well as the production rates of particulate inorganic and organic carbon, and chlorophyll a. Additionally, coccolithophorid calcite was analyzed for its elemental composition (Sr/Ca and Mg/Ca) as well as isotope fractionation of calcium and magnesium (Δ^44/40Ca and Δ^26/24Mg). Our results reveal that physiological rates were substantially influenced by changes in seawater calcium rather than magnesium concentration within the range estimated to have occurred over the past 250 million years when coccolithophores appear in the fossil record. All physiological rates of E. huxleyi decreased at a calcium concentration above 25 mmol L⁻¹, whereas C. braarudii displayed a higher tolerance to increased seawater calcium concentrations. Partition coefficient of Sr was calculated as 0.36 ± 0.04 (±2σ) independent of species. Partition coefficient of Mg²⁺ increased with increasing seawater Ca²⁺ concentrations in both coccolithophore species. Calcium isotope fractionation was constant at 1.1 ± 0.1‰ (±2σ) and not altered by changes in seawater Mg/Ca ratio. There is a well-defined inverse linear relationship between calcium isotope fractionation and partition coefficient of Sr²⁺ in all experiments, suggesting similar controls on both proxies in the investigated species. Magnesium isotope ratios were relatively stable for seawater Mg/Ca ratios ranging from 1 to 5, with a higher degree of fractionation in Emiliania huxleyi (by ≈0.2‰ in Δ^26/24Mg). Although Mg/Ca ratios in the calcite of coccolithophores and foraminifera are similar, the former have considerably higher Δ^26/24Mg (by >+3‰), presumably due to differences in calcification mechanisms between the two taxa. These observations suggest, a physiological control over magnesium elemental and isotopic fractionation during the process of calcification in coccolithophores.     

Eastern Mediterranean summer temperatures since 730 CE from Mt. Smolikas tree-ring densities

The Mediterranean has been identified as particularly vulnerable to climate change, yet a high-resolution temperature reconstruction extending back into the Medieval Warm Period is still lacking. Here we present such a record from a high-elevation site on Mt. Smolikas in northern Greece, where some of Europe’s oldest trees provide evidence of warm season temperature variability back to 730 CE. The reconstruction is derived from 192 annually resolved, latewood density series from ancient living and relict Pinus heldreichii trees calibrating at r1911–2015 = 0.73 against regional July–September (JAS) temperatures. Although the recent 1985–2014 period was the warmest 30-year interval (JAS Twrt.1961–1990 = + 0.71 °C) since the eleventh century, temperatures during the ninth to tenth centuries were even warmer, including the warmest reconstructed 30-year period from 876–905 (+ 0.78 °C). These differences between warm periods are statistically insignificant though. Several distinct cold episodes punctuate the Little Ice Age, albeit the coldest 30-year period is centered during high medieval times from 997–1026 (− 1.63 °C). Comparison with reconstructions from the Alps and Scandinavia shows that a similar cold episode occurred in central Europe but was absent at northern latitudes. The reconstructions also reveal different millennial-scale temperature trends (NEur = − 0.73 °C/1000 years, CEur = − 0.13 °C, SEur = + 0.23 °C) potentially triggered by latitudinal changes in summer insolation due to orbital forcing. These features, the opposing millennial-scale temperature trends and the medieval multi-decadal cooling recorded in Central Europe and the Mediterranean, are not well captured in state-of-the-art climate model simulations.     

Contrasting regional and global climate simulations over South Asia

Climate Dynamics - Two ensembles of climate simulations, one global and one regional, are used to investigate model errors and projected climate change in seasonal mean temperature and...     

Air–Sea Interaction Features in the Baltic Sea and at a Pacific Trade-Wind Site: An Inter-comparison Study

A systematic comparison of wind profiles and momentum exchange at a trade wind site outside Oahu, Hawaii and corresponding data from the Baltic Sea is presented. The trade wind data are to a very high degree swell dominated, whereas the Baltic Sea data include a more varied assortment of wave conditions, ranging from a pure growing sea to swell. In the trade wind region swell waves travel predominantly in the wind direction, while in the Baltic, significant cross-wind swells are also present. Showing the drag coefficient as a function of the 10-m wind speed demonstrates striking differences for unstable conditions with swell for the wind-speed range 2 m s^?1 < U ₁₀ < 7 m s^?1, where the trade-wind site drag values are significantly larger than the corresponding Baltic Sea values. In striking contrast to this disagreement, other features studied are surprisingly similar between the two sites. Thus, exactly as found previously in Baltic Sea studies during unstable conditions and swell, the wind profile in light winds (3 m s^?1) shows a wind maximum at around 7–8 m above the water, with close to constant wind speed above. Also, for slightly higher wind speeds (4 m s^?1 < U ₁₀ < 7 m s^?1), the similarity between wind profiles is striking, with a strong wind-speed increase below a height of about 7–8 m followed by a layer of virtually constant wind speed above. A consequence of these wind-profile features is that Monin–Obukhov similarity is no longer valid. At the trade-wind site this was observed to be the case even for wind speeds as high as 10 m s^?1. The turbulence kinetic energy budget was evaluated for four cases of 8–16 30- min periods at the trade-wind site, giving results that agree very well with corresponding figures from the Baltic Sea.     

A Stochastic Object Model Conditioned to High-Quality Seismic Data

We present an approach for modeling facies bodies in which a highly constrained stochastic object model is used to integrate detailed seismic interpretation of the reservoir’s sedimentological architecture directly in a three-dimensional reservoir model. The approach fills the gap between the use of seismic data in a true deterministic sense, in which the facies body top and base are resolved and mapped directly, and stochastic methods in which the relationship between seismic attributes and facies is defined by conditional probabilities. The lateral geometry of the facies bodies is controlled by seismic interpretations on horizon slices or by direct body extraction, whereas facies body thickness and cross-sectional shape are defined by a mixture of seismic data, well data, and user defined object shapes. The stochastic terms in the model are used to incorporate local geometric variability, which is used to increase the geological realism of the facies bodies and allow for correct, flexible well conditioning. The result is a set of three-dimensional facies bodies that are constrained to the seismic interpretations and well data. Each body is defined as a parametric object that includes information such as location of the body axis, depositional direction, axis-to-margin normals, and external body geometry. The parametric information is useful for defining geologically realistic intrabody petrophysical trends and for controlling connectivity between stacked facies bodies.     

The Namuskluft and Dreigratberg sections in southern Namibia (Kalahari Craton,Gariep Belt): a geological history of Neoproterozoic rifting and recycling of cratonic crust during the dispersal of Rodinia until the amalgamation of Gondwana

This paper presents combined U/Pb, Th/U and Hf isotope analyses on detrital and magmatic zircon grains together with whole-rock geochemical analyses of two basement and eight sedimentary rock samples from the Namuskluft and the Dreigratberg in southern Namibia (Gariep Belt). The sedimentary sections evolved during the Cryogenian on the SW part of the Kalahari Craton and where therefore deposited in an active rift setting during the break-up of Rodinia. Due to insufficient palaeomagnetic data, the position of the Kalahari Craton within Rodinia is still under discussion. There are possibilities to locate Kalahari along the western side of Australia/Mawsonland (Pisarevski et al. in Proterozoic East Gondwana: supercontinent assembly and break-up, Geological Society, London, 2003; Evans in Ancient Orogens and modern analogues. Geological Society, London, 2009; and others) or together with the Congo-Sao Francisco and Rio de la Plata Cratons (Li et al. in Prec Res 45: 203–2014, 2008; Frimmel et al. in Int J Earth Sci (Geol Rundsch) 100: 323–354, 2011; and others). It is sill unclear which craton rifted away from the Kalahari Craton during the Cryogenian. Although Middle to Upper Cryogenian magmatic activity is known for the SE Kalahari Craton (our working area) (Richtersveld Suite, Rosh Pinah Fm), all the presented samples show no U/Pb zircon ages younger than ca. 1.0 Ga and non-older than 2.06 Ga. The obtained U/Pb ages fit very well to the exposed basement of the Kalahari Craton (1.0–1.4 Ga Namaqua Province, 1.7–2.0 Ga Vioolsdrif Granite Suite and Orange River Group) and allow no correlation with a foreign craton such as the Rio de la Plata or Australia/Mawsonland. Lu–Hf isotopic signatures of detrital zircon point to the recycling of mainly Palaeoproterozoic and to a smaller amount of Archean crust in the source areas. εHf(t) signatures range between ?24 and +14.8, which relate to T_DM model ages between 1.05 and 3.1 Ga. Only few detrital zircon grains derived from magmas generated from Mesoproterozoic crustal material show more juvenile εHf(t) signatures of +14, +8 to +4 with T_DM model ages of 1.05–1.6 Ga. During Neoproterozoic deposition, only old cratonic crust with an inherited continental arc signature was available in the source area clearly demonstrated by Hf isotope composition of detrital zircon and geochemical bulk analysis of sedimentary rocks. The granodiorites of the Palaeoproterozoic basement underlying Namuskluft section are ca. 1.9 Ga old and show εHf(t) signatures of ?3 to ?5.5 with T_DM model ages of 2.4–2.7 Ga. These basement rocks demonstrate the extreme uplift and deep erosion of the underlying Kalahari Craton at its western margin before general subsidence during Cryogenian and Ediacaran time. The sedimentary sequence of the two examined sections (Namuskluft and Dreigratberg) proposes the presence of a basin and an increasing subsidence at the SW part of the Kalahari Craton during the Cryogenian. Therefore, we propose the initial formation of an intra-cratonic sag basin during the Lower Cryogenian that evolved later to a rift basin at the cratonic margin due to increasing crustal tension and rifting together with the opening of the Adamastor Ocean. As the zircons of the sedimentary rocks filling this basin show neither rift-related U/Pb ages nor an exotic craton as a possible source area, the only plausible sedimentary transport direction providing the found U/Pb ages would be from the E or the SE, directly from the heart of the Kalahari Craton. Due to subsidence and ongoing sedimentation from E/SE directions, the rift-related magmatic rocks were simply covered by the input of old intra-cratonic material that explains the absence of Neoproterozoic zircon grains in our samples. The geochemical analyses show the erosion of a continental arc and related sedimentary rocks with an overall felsic provenance. The source area was a deeply eroded and incised magmatic arc that evolved on continental crust, without any evidence for a passive margin. All of this can be explained by the erosion of rocks related to the Namaqua Belt, which represents one of the two major peaks of zircon U–Pb ages in all analysed samples. Therefore, the Namaqua Belt was well exposed during the Cryogenian, available to erosion and apart from the also well-exposed Palaeoproterozoic basement of the Kalahari Craton one potential source area for the sedimentary rocks in the investigated areas.     

Armorican provenance for the mélange deposits below the Lizard ophiolite (Cornwall,UK): evidence for Devonian obduction of Cadomian and Lower Palaeozoic crust onto the southern margin of Avalonia

Devonian sedimentary rocks of the Meneage Formation within the footwall of the Lizard ophiolite complex in SW England are thought to have been derived from erosion of the over-riding Armorican microplate during collision with Avalonia and the closure of the Rheic Ocean. We further test this hypothesis by comparison of their detrital zircon suites with those of autochthonous Armorican strata. Five samples analysed from SW England (Avalonia) and NW France (Armorica) have a bimodal U–Pb zircon age distribution dominated by late Neoproterozoic to middle Cambrian (c. 710–518 Ma) and Palaeoproterozoic (c. 1,800–2,200 Ma) groupings. Both can be linked with lithologies exposed within the Cadomian belt as well as the West African craton, which is characterized by major tectonothermal events at 2.0–2.4 Ga. The detrital zircon signature of Avalonia is distinct from that of Armorica in that there is a much larger proportion of Mesoproterozoic detritus. The common provenance of the samples is therefore consistent with: (a) derivation of the Meneage Formation mélange deposits from the Armorican plate during Rheic Ocean closure and obduction of the Lizard Complex and (b) previous correlation of quartzite blocks within the Meneage Formation with the Ordovician Grès Armoricain Formation of NW France.     

Thermal tracer testing in a sedimentary aquifer: field experiment (Lauswiesen,Germany) and numerical simulation

An active and short-duration thermal tracer test (TTT) was conducted in a shallow sedimentary aquifer at the Lauswiesen test site, near Tübingen, Germany. By injecting 16  m³ of warm water at 22°C, a thermal anomaly was created, which propagated along the local groundwater flow direction. This was comprehensively monitored in five observation wells at a few meters distance. The purpose of this well-controlled experiment was to determine the practicability of such a TTT and its suitability to examine hydraulic characteristics of heterogeneous aquifers. The results showed that the thermal peak arrival times in the observation wells were consistent with previous observations from alternative field testing such as direct-push injection logging (DPIL). Combined analysis of depth-dependent temperatures and peak arrival times, and comparison with a numerical heat transport model, offers valuable insights into the natural flow field and spatial distribution of hydraulic conductivities. The study was able to identify vertical flow focusing and bypassing, which are attributed to preferential flow paths common in such sedimentary sand and gravel aquifers. These findings are fundamental for further development of experimental designs of active and short-duration TTTs and provide a basis for a more quantitative analysis of advective and conductive transport processes.