Provenance and reconnaissance study of detrital zircons of the Palaeozoic Cape Supergroup in South Africa: revealing the interaction of the Kalahari and R��o de la Plata cratons

In order to facilitate the understanding of the geological evolution of the Kalahari Craton and its relation to South America, the provenance of the first large-scale cratonic cover sequence of the craton, namely the Ordovician to Carboniferous Cape Supergroup was studied through geochemical analyses of the siliciclastics, and age determinations of detrital zircon. The Cape Supergroup comprises mainly quartz-arenites and a Hirnantian tillite in the basal Table Mountain Group, subgreywackes and mudrocks in the overlying Bokkeveld Group, while siltstones, interbedded shales and quartz-arenites are typical for the Witteberg Group at the top of the Cape Supergroup. Palaeocurrent analyses indicate transport of sediment mainly from northerly directions, off the interior of the Kalahari Craton with subordinate transport from a westerly source in the southwestern part of the basin near Cape Town. Geochemical provenance data suggest mainly sources from passive to active continental margin settings. The reconnaissance study of detrital zircons reveals a major contribution of Mesoproterozoic sources throughout the basin, reflecting the dominance of the Namaqua-Natal Metamorphic Belt, situated immediately north of the preserved strata of Cape Supergroup, as a source with Archaean-aged zircons being extremely rare. We interpret the Namaqua-Natal Metamorphic Belt to have been a large morphological divide at the time of deposition of the Cape Supergroup that prevented input of detrital zircons from the interior early Archaean Kaapvaal cratonic block of the Kalahari Craton. Neoproterozoic and Cambrian zircons are abundant and reflect the basement geology of the outcrops of Cape strata. Exposures close to Cape Town must have received sediment from a cratonic fragment that was situated off the Kalahari Craton to the west and that has subsequently drifted away. This cratonic fragment predominantly supplied Meso- to Neoproterozoic, and Cambrian-aged zircon grains in addition to minor Silurian to Lower Devonian zircons and very rare Archaean (2.5?Ga) and late Palaeoproterozoic (1.8-2.0?Ga) ones. No Siluro-Devonian source has yet been identified on the Kalahari Craton, but there are indications for such a source in southern Patagonia. Palaeozoic successions in eastern Argentina carry a similar detrital zircon population to that found here, including evidence of a Silurian to Lower Devonian magmatic event. The Kalahari and Río de la Plata Cratons were thus in all likelihood in close proximity until at least the Carboniferous.     

FIRST RESULTS FROM VIRGO,THE EXPERIMENT FOR HELIOSEISMOLOGY AND SOLAR IRRADIANCE MONITORING ON SOHO

First results from the VIRGO experiment (Variability of solar IRradiance and Gravity Oscillations) on the ESA/NASA Mission SOHO (Solar and Heliospheric Observatory) are reported. The observations started mid-January 1996 for the radiometers and sunphotometers and near the end of March for the luminosity oscillation imager. The performance of all the instruments is very good, and the time series of the first 4–6 months are evaluated in terms of solar irradiance variability, solar background noise characteristics and p-mode oscillations. The solar irradiance is modulated by the passage of active regions across the disk, but not all of the modulation is straightforwardly explained in terms of sunspot flux blocking and facular enhancement. Helioseismic inversions of the observed p-mode frequencies are more-or-less in agreement with the latest standard solar models. The comparison of VIRGO results with earlier ones shows evidence that magnetic activity plays a significant role in the dynamics of the oscillations beyond its modulation of the resonant frequencies. Moreover, by comparing the amplitudes of different components ofp -mode multiplets, each of which are influenced differently by spatial inhomogeneity, we have found that activity enhances excitation.     

An experimental investigation of Na incorporation in cordierite in low P/high T metapelites

Mineralogy and Petrology - The aim of this experimental study was to investigate the incorporation of Na in cordierite in metapelites as a function of temperature and pressure using natural...     

Single-crystal structure and Raman spectroscopy of synthetic titanite analog CaAlSiO<Subscript>4</Subscript>F

Synthetic CaAlSiO₄F, the Al-F analog of titanite, has been investigated using single-crystal synchrotron diffraction experiments at Beamline X06DA (Swiss Light Source, Paul Scherrer Institute, Villigen, Switzerland) and Raman spectroscopy. The presented structural model with 40 parameters was refined against 506 unique reflections to a final R _{o b s} of 0.026 (space group A2/a, a = 6.9120(11), b = 8.5010(10), c = 6.435(2) Å, β = 114.670(11)°, and Z = 4) and exhibits less distorted coordination polyhedra than earlier models from powder data. Vibrational spectra were calculated in harmonic approximation at the Γ point from fully relaxed energy optimisations of the crystal structure, using 3D-periodic density functional theory with Gaussian basis sets and the software CRYSTAL06. The lattice parameters of the fully relaxed structure were in good agreement with the experimental values, with the calculated values 0.8 ± 0.4 % too large; the monoclinic angle was calculated 0.4° too large. The agreement of the calculated Raman frequencies with the observed ones was very good, with standard deviation ±3 cm^?1 and maximum deviations of ±7 cm^?1. Furthermore, a detailed discussion of the atomic displacements associated with each Raman mode is given.     

Provenance of the Lower Paleozoic Balcarce Formation (Tandilia System, Buenos Aires Province, Argentina): Implications for paleogeographic reconstructions of SW Gondwana

Lower Paleozoic moderately sorted quartz–arenites from the Balcarce Formation deposited in eastern Argentina (Tandilia System) comprise mainly detrital material derived from old upper crustal material. The sources were magmatic, sedimentary, and subordinated felsic metamorphic terranes. High concentrations of tourmaline and Ti-rich heavy minerals, including zircon and nearly euhedral chromite, are common. Trace element concentrations (Nb, Cr) on rutile indicate pelitic and metabasaltic sources, respectively. Major element analyses on chromites indicate a basic volcanic protolith of mid-oceanic ridge origin, which was exposed close to the depositional basin. The delivery of chromite may be associated with convergent tectonics causing the consumption and obduction of oceanic crust during pre-Upper Ordovician times. The oblique/orthogonal collision of the Precordillera Terrane with the western border of the Rio de la Plata Craton, west of the Balcarce Basin or source further to the east from a Lower Palaeozoic extensional basin are possibilities.Geochemical and petrographic data exclude the underlying Precambrian and Cambrian sedimentary rocks as dominant sources, and favour the basement of the Río de La Plata Craton, including Cambrian rift-related granites of South Africa and the Sierras Australes (eastern Argentina), as main suppliers of detritus. Trace element geochemistry of recycled pyroclastic material, associated with the quartz–arenites, also suggests volcanic arc sources. The provenance of the pyroclastic material may either be the Puna–Famatina arc, located in north and central Argentina, or a hypothetical active margin further to the south. These ash layers are equivalent in age to volcanic zircons found in the Devonian Bokkeveld Group in western South Africa.The deposition of a glacial diamictite of Hirnantian age (Sierra del Volcán Diamictite) is interpreted as a member of the Balcarce Formation. Based on the stratigraphic re-location of the glacial diamictite and trace fossils, the Balcarce Formation is considered here to be Ordovician to Silurian in age. The Balcarce Formation can be correlated with similar rocks in South Africa, the Peninsula Formation, and the upper Table Mountain Group (Windhoek and Nardouw subgroups), including the Hirnantian glacial deposit of the Pakhuis Formation.     

Nickeloan pyrite from Prangenhaus quarry, Niederberg area, Germany—A short communication

The mineral chemistry of two nickeloan pyrite samples from the Prangenhaus quarry, Wülfrath, is presented. Sample PRH 5: main zone=4.32-9.7 wt% Ni (0.089-0.202 atoms per formula unit (a.p.f.u.)), 0.21-1.31 wt% Co (0.004-0.027 a.p.f.u.); rim zone=11.76-22.38 wt% Ni (0.244-0.466 a.p.f.u. ), 1.35-8.16 wt% Co (0.028-0.168 a.p.f.u.). Sample PRH 6: 6.75-11.33 wt% Ni (0.139-0.234 a.p.f.u.), 0.86-2.46 wt% Co (0.018-0.051 a.p.f.u.). Estimated Fe/Ni and Fe/Co ratios of the hydrothermal fluids forming the nickeloan pyrite point to very local fluctuations in the chemistry of the ore forming fluids in the Prangenhaus quarry. The presence of nickeloan pyrite indicates formation temperatures below 137 °C, which is in accordance with earlier findings of formation temperatures for sphalerite (60-130 °C) in the Niederberg area.     

Selective grazing by cattle on spatially and seasonally heterogeneous rangeland in Sahel

The selective use by cattle of range resources in the Sahel was assessed in terms of quantity and nutritional quality of the herbage grazed and diet selected. Peak standing crop was 1951 kg ha⁻¹dry matter (DM) with 47·9 kg nitrogen (N) ha⁻¹and 7·4 kg phosphorus (P) ha⁻¹. Esophageally fistulated cattle diets were consistently (p<0·05) higher in N, P and organic matter digestibility (OMD) than the herbage grazed. Cattle consumed 48% of the mean annual herbage production. The results indicate grazing ruminants select a higher quality diet from Sahelian rangelands than can be predicted on the basis of pasture evaluation alone. Therefore, the foraging behaviour of the animals needs to be considered in the evaluation of Sahelian rangelands for animal production.     

Chemical and structural characterization of As immobilization by nanoparticles of mackinawite (FeSm)

The mobility and availability of arsenite, As(III), in anoxic environments is largely controlled by adsorption onto iron sulfides and/or precipitation of arsenic in solid phases. The interaction of As(III) with synthetic mackinawite (FeS_m) in pH 5 and 9 suspensions was investigated using high-angle annular dark field (HAADF) scanning transmission electron microscopy (STEM), STEM elemental mapping, high resolution TEM, and X-ray photoelectron spectroscopy (XPS). At pH 5, arsenic sulfide phases precipitate among the FeS_m particles as discrete particles that are an amorphous hydrous phase of arsenic sulfide. The oxidation state of As in the surface layers of the arsenic sulfide precipitates is ‘realgar-like’ based on XPS results showing that > 75% of the As 3d peak area is due to As with oxidation states between 0 and 2+. Discrete, arsenic sulfide precipitates are absent at pH 9, but elemental mapping in STEM-EDX mode shows that arsenic is uniformly distributed on the FeS_m, suggesting that uptake is caused by the sorption of As(III) oxyanions and/or the precipitation of highly dispersed arsenic sulfides on FeS_m. XPS also revealed that the FeS_m that equilibrated without As(III) has a more oxidized surface composition than the sample at pH 9, as indicated by the higher concentration of O ( three times greater than that at pH 9) and the larger fraction of Fe(III) species making up the total Fe (2p_3/2) peak. These findings provide a better understanding of redox processes and phase transitions upon As(III) adsorption on iron sulfide substrates.     

A proposed new type of arsenian pyrite: Composition, nanostructure and geological significance

This report describes a new form of arsenian pyrite, called As³⁺-pyrite, in which As substitutes for Fe [(Fe,As)S₂], in contrast to the more common form of arsenian pyrite, As¹⁻-pyrite, in which As¹⁻ substitutes for S [Fe(As,S)₂]. As³⁺-pyrite has been observed as colloformic overgrowths on As-free pyrite in a hydrothermal gold deposit at Yanacocha, Peru. XPS analyses of the As³⁺-pyrite confirm that As is present largely as As³⁺. EMPA analyses show that As³⁺-pyrite incorporates up to 3.05 at % of As and 0.53 at. %, 0.1 at. %, 0.27 at. %, 0.22 at. %, 0.08 at. % and 0.04 at. % of Pb, Au, Cu, Zn, Ni, and Co, respectively. Incorporation of As³⁺ in the pyrite could be written like: As³⁺+yAu⁺+1-y(□)⇔2Fe²⁺; where Au⁺ and vacancy (□) help to maintain the excess charge. HRTEM observations reveal a sharp boundary between As-free pyrite and the first overgrowth of As³⁺-pyrite (20-40 nm thick) and co-linear lattice fringes indicating epitaxial growth of As³⁺-pyrite on As-free pyrite. Overgrowths of As³⁺-pyrite onto As-free pyrite can be divided into three groups on the basis of crystal size, 8-20 nm, 100-300 nm and 400-900 nm, and the smaller the crystal size the higher the concentration of toxic arsenic and trace metals. The Yanacocha deposit, in which As³⁺-pyrite was found, formed under relatively oxidizing conditions in which the dominant form of dissolved As in the stability field of pyrite is As³⁺; in contrast, reducing conditions are typical of most environments that host As¹⁻-pyrite. As³⁺-pyrite will likely be found in other oxidizing hydrothermal and diagenetic environments, including high-sulfidation epithermal deposits and shallow groundwater systems, where probably kinetically controlled formation of nanoscale crystals such as observed here would be a major control on incorporation and release of As³⁺ and toxic heavy metals in oxidizing natural systems.     

The continent‐ocean transition on the northwestern South China Sea

Rifted margins are created as a result of stretching and breakup of continental lithosphere that eventually leads to oceanic spreading and formation of a new oceanic basin. A cornerstone for understanding what processes control the final transition to seafloor spreading is the nature of the continent‐ocean transition (COT). We reprocessed multichannel seismic profiles and use available gravity data to study the structure and variability of the COT along the Northwest subbasin (NWSB) of the South China Sea. We have interpreted the seismic images to discern continental from oceanic domains. The continental‐crust domain is characterized by tilted fault blocks generally overlain by thick syn‐rift sedimentary units, and underlain by fairly continuous Moho reflections typically at 8–10 s twtt. The thickness of the continental crust changes greatly across the basin, from ~20 to 25 km under the shelf and uppermost slope, to ~9–6 km under the lower slope. The oceanic‐crust domain is characterized by a highly reflective top of basement, little faulting, no syntectonic strata and fairly constant thickness (over tens to hundreds of km) of typically 6 km, but ranging from 4 to 8 km. The COT is imaged as a ~5–10 km wide zone where oceanic‐type features directly abut or lap on continental‐type structures. The South China margin continental crust is cut by abundant normal faults. Seismic profiles show an along‐strike variation in the tectonic structure of the continental margin. The NE‐most lines display ~20–40 km wide segments of intense faulting under the slope and associated continental‐crust thinning, giving way to a narrow COT and oceanic crust. Towards the SW, faulting and thinning of the continental crust occurs across a ~100–110 km wide segment with a narrow COT and abutting oceanic crust. We interpret this 3D structural variability and the narrow COT as a consequence of the abrupt termination of continental rifting tectonics by the NE to SW propagation of a spreading centre. We suggest that breakup occurred abruptly by spreading centre propagation rather than by thinning during continental rifting. We propose a kinematic evolution for the oceanic domain of the NWSB consisting of a southward spreading centre propagation followed by a first narrow ridge jump to the north, and then a younger larger jump to the SE, to abandon the NWSB and create the East subbasin of the South China Sea.