Mixed-function oxygenases as biological monitors around petroleum hydrocarbon development sites: Potential for induction by diesel and other drilling mud base oils containing reduced levels of polycyclic aromatic hydrocarbons

The use of oil-based drilling muds has been discouraged in hydrocarbon exploration and production in the marine environment but these muds are presently being used to a considerable degree in the United Kingdom and Norwegian sectors of the North Sea. Field studies in the North Sea have demonstrated only localized impacts around individual drilling sites,^1,2 even including those sites where ‘toxic’ diesel oils were employed as base fluids in drilling muds. Yet the question of disposal of cuttings contaminated with oil from drilling muds remains somewhat controversial. The induction of mixed-function oxygenases (MFO) has been validated on a number of occasions in the field as a sensitive index of low level hydrocarbon exposure (reviewed by Payne),³ including sites in the North Sea where diesel-based muds were used.⁴ The present study demonstrates that any potential for induction by hydrocarbon contaminated cuttings will probably be reduced by substitution of low-aromatic base oils for diesel in drilling mud formulations.     

Estimates of the characteristics of the horizontal turbulent exchange in the northwestern part of the Pacific Ocean

Estimates of the characteristics of the horizontal turbulent exchange (coefficients of horizontal exchange, scales of deviations of the velocity of geostrophic currents from the background flows, and horizontal scales of perturbations) in the upper ocean layer were obtained on the basis of the data of expeditions held in 1978 and 1980 in the northwestern part of the Pacific Ocean. It is shown that the characteristics of the horizontal turbulent exchange strongly depend on the structure of the background flows, and one of the causes of their variability is related to tropical cyclones. A tendency to a decrease (to different degrees) of the turbulent coefficients in the wake of a tropical cyclone is noted.     

Spectra of the Black-Sea tsunamis

We perform the analysis of the time spectra of four tsunamis generated in the Black Sea by the earthquakes of 26.07.1927, 11.09.1927, 26.12.1939, and 12.07.1966. For the analysis of the spectra, we used digitized marigrams obtained for 12 points of the Black-Sea coast. The obtained spectra are, as a rule, multimode and have 1–4 spectral maxima. One maximum corresponds to the periods typical of tsunami waves and the other maxima correspond to the oscillations of the sea level with lower frequencies. It seems likely that the events of tsunami are accompanied by low-frequency oscillations of the level caused by the atmospheric forcing, seiches, or other factors. In numerous cases, the oscillations from the predominant energy range lie outside the characteristic range of periods of the tsunami waves. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 5, pp. 21–30, September–October, 2007.     

Atmospheric forcing of fine-sand transport on a low-energy inner shelf: south-central Louisiana,USA

Hydrodynamic and sediment transport measurements from instrumentation deployed during a 54-day winter period at two sites on the Louisiana inner shelf are presented. Strong extratropical storms, with wind speeds of 7.8 to 15.1 m s^-1, were the dominant forcing mechanism during the study. These typically caused mean oscillatory flows and shear velocities about 33% higher than fair weather (averaging 12.3 and 3.2 cm s^-1 at the landward site, and 11.4 and 2.7 cm s^-1 at the seaward site, respectively). These responses were coupled with mean near-bottom currents more than twice as strong as during fair weather (10.3 and 7.5 cm s^-1 at the landward and seaward sites, respectively). These flowed in approximately the same direction as the veering wind, causing a net offshore transport of fine sand. Weak storms were responsible for little sediment transport whereas during fair weather, onshore sand transport of approximately 25-75% of the storm values appears to have occurred. This contradicts previous predictions of negligible fair-weather sediment movement on this inner shelf.     

Recent and Late Holocene environments on the southeastern shelf of the Laptev Sea as inferred from microfossil data

The study of diatoms and benthic foraminifers from the southeastern shelf of the Laptev Sea shows that their most diverse and abundant recent assemblages populate the peripheral underwater part of the Lena River delta representing the marginal filter of the sea. This area is characterized by an intense interaction between the fresh waters of the Siberian rivers and the basin seawater, the Atlantic one included. Local Late Holocene (～last 2300 years) environments reflect the main regional and global paleoclimatic changes, the Medieval Warm Period (～600–1100 years B.P.) and the Little Ice Age (～100–600 years B.P.) inclusive. In addition, the composition and distribution of planktonic foraminifers implies a strong influence of the Atlantic water during the Holocene optimum ～5100–6200 years B.P.     

Phytoplankton biomass and size fractions in surface waters of the Australian sector of the southern ocean

We collected surface water along the 142nd E meridian from Tasmania to Antarctica in December 1999. We measured temperature, salinity and total chlorophyll a; additionally, we collected suspended particle size fractions and used fluorometric analysis to determine the quantity of chlorophyll a in each of four cell size classes: picoplankton (<3 μm), two nanoplankton fractions (3–10 μm and 10–20 μm) and microplankton (> 20 μm). Changes in temperature and salinity show that we crossed 6 water masses separated by 5 fronts. We found low abundance (<0.2 mg m⁻³) of chlorophyll in all size classes, with the exception of higher values near the continent (0.2 to 0.4 mg m⁻³). Lowest chlorophyll values (<0.1 mg m⁻³) were found in the Polar Frontal Zone (51° to 54°S). Microplankton made up the largest portion of total chlorophyll throughout most of the region. We conclude that biomass of all phytoplankton fractions, especially pico-and nanoplankton, was constrained by limiting factors, most probably iron, throughout the region and that ecosystem dynamics within a zone are not circumpolar but are regionalized within sectors.     

New sets of wavelet-forming functions

One of the most efficient tools of studying meteorological and climatic time series is wavelet analysis, which allows local properties of a nonstationary time series to be examined. New sets of continuous and discrete wavelet-forming functions are proposed. All proposed wavelets are finite (have a bounded carrier), even, and well localized in the spectral space.     

Change of multifractal thermal characteristics in the western Philippine sea upper layer during internal wave-soliton propagation

The upper layer (above 140 m depth) temperature in the western Philippine Sea near Taiwan was sampled using a coastal monitoring buoy (CMB) with 15 attached thermistors during July 28–August 7, 2005. The data were collected every 10 min at 1, 3, 5, 10, 15, and 20 m using the CMB sensors, and every 15 sec at 15 different depths between 25 m and 140 m. Internal waves and solitons were identified from the time-depth plot of the temperature field. Without the internal waves and solitons, the power spectra, structure functions, and singular measures (representing the intermittency) of temperature field satisfy the power law with multi-scale characteristics at all depths. The internal waves do not change the basic characteristics of the multifractal structure. However, the internal solitons change the power exponent of the power spectra drastically, especially in the low wave number domain; they also break down the power law of the structure function and increase the intermittency parameter. The physical mechanisms causing these different effects need to be explored further.     

Geomorphological evidence for upslope canyon-forming processes on the northern KwaZulu-Natal shelf,SW Indian Ocean,South Africa

A geomorphological and statistical analysis of slope canyons from the northern KwaZulu-Natal continental margin is documented and compared with submarine canyons from the Atlantic margin of the USA. The northern KwaZulu-Natal margin is characterized by increasing upslope relief, concave slope-gradient profiles and features related to upslope growth of the canyon forms. Discounting slope-gradient profile, this morphology is strikingly similar to canyon systems of the New Jersey slope. Several phases of canyon incision indicate that downslope erosion is also an important factor in the evolution of the northern KwaZulu-Natal canyon systems. Despite the strong similarities between the northern KwaZulu-Natal and New Jersey slope-canyon systems, key differences are evident: (1) the concavity of the northern KwaZulu-Natal slope, contrasting with the ∼linear New Jersey slope; (2) the relative isolation of the northern KwaZulu-Natal canyons, rather than the dense clustering of the New Jersey canyons; and (3) the absence of strongly shelf-breaching canyons along the northern KwaZulu-Natal margin. In comparison with the New Jersey margin, we surmise a more youthful stage of canyon evolution, a result of either the canyons themselves being younger or the formative processes being less active. Less complicated patterns of erosion resulting from reduced sediment availability have developed in northern KwaZulu-Natal. The reduction in slope concavity on the New Jersey margin may be the result of grading of the upper slope by intensive headward erosion, a process more subdued—or less evident—on the KwaZulu-Natal margin.     

Model estimates for the mean gas exchange between the ocean and the atmosphere under the conditions of the present-day climate and its changes expected in the 21st century

Annual mean fluxes of CO₂ and oxygen across the sea surface are estimated with the use of numerical modeling for several regions located in the Gulf Stream and Kuroshio zones. The present-day climatic conditions and the climatic conditions expected in the middle and at the end of the 21st century are considered. Specific features of gas exchange under a strong wind that are associated with gas exchange by bubbles and with changes in the air-water difference of the gas concentrations were taken into account in the calculations. The estimates obtained differ substantially from the results based on the traditional approach, which disregards the above features. A considerable increase in the absorption of CO₂ by the ocean, which is mainly caused by the continuing increase in the CO₂ concentration in the air during its small changes in the ocean, is expected in the 21st century. At the same time, no trends are revealed in the annual mean fluxes of oxygen across the ocean surface. The conclusion is made that, in calculations of CO₂ absorption by the world ocean, it is necessary to take into account both specific features of gas transfer under a strong wind and an increase in the atmospheric concentration of CO₂.