Flotation als einfache Anreicherungsmethode für die Spurenanalyse in Wässern

Recently the method of flotation is used as a simple step within a number of procedures of chemical analysis for enrichment of waters or industrial lyes to be investigated by ions. By the example of tin analysis all the possible variants are compared with regard to their efficiency. The advantages result from the using conventional methods of chemical analysis in connection with coprecipitation of traces and their flotation at trace levels of ng/ml. The flotation is a fast method of enrichment, it is easily to handle and sufficiently exact. As a proof example the chemical analysis of Sn, Au and Ag is described.     

Possible ion-acoustic soliton formation in the ionospheric perturbations observed on DEMETER before the 2007 Pu’er earthquake

The data of ionospheric perturbations observed on DEMETER before the 2007 Pu’er earthquake are analyzed. The three-component plasma (ions, electrons and heavy ions) is studied in the fluid concept. The linear dispersion relation for ion-acoustic wave is found in the presence of heavy ions. The nonlinear dynamics is studied for arbitrary amplitude of the wave. The Sagdeev potential is calculated, which shows that solitary structure exists for Mach number within a range defined by the presence of heavy ions. ...     

Konzepte zur Mobilitätsabschätzung von Schadstoffen in Boden- und Abfallmaterialien

Concepts for the Evaluation of Contaminant Mobility in Soil and Waste Materials Elution tests (S4, pH_stat, and SDS test) are presented, enabling the evaluation of the mobility of hydrophilic/hydrophobic and inorganic/organic contaminants in soil and waste materials. While elution tests for estimation of the mobilization potential of hydrophilic substances are performed following the pH_stat method, for hydrophobic species surfactant-containing eluents are used. The individual parameters of the elution process are selected assuming a "worst-case" scenario. In principle, because of economic reasons, detailed analytical investigations should be preceded by relevant screening tests.     

The Holocene–Anthropocene transition in lakes of western Spitsbergen,Svalbard (Norwegian High Arctic): climate change and nitrogen deposition

Lake sediments from four small lakes on western Spitsbergen (Svalbard Archipelago, Norwegian High Arctic) preserve biostratigraphic and isotopic evidence for a complex suite of twentieth century environmental changes. At Lake Skardtjørna and Lake Tjørnskardet on Nordenskiöldkysten, there is a marked diatom floristic change coupled to increased diatom concentrations beginning around 1920. At Lake Istjørna and Lake Istjørnelva, 25 km southwest of Longyearbyen, both diatom total valve and chrysophyte stomatocyst concentrations have increased dramatically since the beginning of the 1900s. The early twentieth century changes are probably related to climate warming after the Little Ice Age. However, the most pronounced changes in diatom assemblages seem to have occurred in the last few decades. At the same time, nitrogen stable isotopes in sediment organic matter in two of the lakes became progressively depleted by ~2‰, which is consistent with diffuse atmospheric inputs from anthropogenic sources and attendant fertilization. These data suggest that climate change and nitrogen deposition may be acting together in driving these lakes towards new ecological states that are unique in the context of the Holocene.     

FINDING CAUSES OF OUTLIERS IN MULTIVARIATE ENVIRONMENTAL DATA

Multivariate outliers in environmental data sets are often caused by atypical measurement error in a singlevariable.From a quality assurance perspective it is important to identify these variables efficiently so thatcorrective actions may be performed.We demonstrate a procedure for using two multivariate tests toidentify which variable‘caused’each outlier.The procedure is tested with simulated data sets that havethe same correlation structure as selected water chemistry variables from a survey of lakes in the WesternUnited States.The success rates are evaluated for three of the variables for sample sizes of 50 and 100,significance levels of 0.01 and 0.05 and various amounts of mean shift.The procedure works best forhighly correlated variables.     

Wind velocity and sand transport on a barchan dune

We present measurements of wind velocity and sand flux performed on the windward side of a large barchan dune in Jericoacoara, northeastern Brazil. From the measured profile, we calculate the air shear stress using an analytical approximation and treat the problem of flow separation by an heuristic model. We find that the results from this approach agree well with our field data. Moreover, using the calculated shear velocity, we predict the sand flux according to well-known equilibrium relations and with a phenomenological continuum saltation model that includes saturation transients and thus allows for nonequilibrium conditions. Based on the field data and theoretical predicted results, we indicate the principal differences between saturated and nonsaturated sand flux models. Finally, we show that the measured dune moves with invariant shape and predict its velocity from our data and calculations.     

Distribution of the Neogene Utsira Sand and the succeeding deposits in the Viking Graben area, North Sea

The sandy quartzose parts of the Utsira Formation, the Middle Miocene to mid Pliocene Utsira Sand, extends north–south along the Viking Graben near the UK/Norwegian median line for more than 450 km and 75–130 km east–west. The Utsira Sand is located in basin-restricted seismic depocentres, east of and below prograding sandy units from the Shetland Platform area with Hutton Sands. The Utsira Sand reaches thicknesses up to ca. 300 m in the southern depocentre and 200 m in the two northern depocentres with sedimentation rates up to 2–4 cm/ka. Succeeding Plio–Pleistocene is divided into seismic units, including Base Upper Pliocene, Shale Drape, Prograding Complex and Pleistocene. The units mainly consist of clay, but locally minor sands occur, especially at toes of prograding clinoforms (bottom-set sands) and in the Pleistocene parts, and the total thickness covering the Utsira Sand is in most places more than 800 m, but thins towards the margins.