Quasi-static slip on the plate boundary associated with the 2003 M8.0 Tokachi-oki and 2004 M7.1 off-Kushiro earthquakes, Japan

We analyzed small repeating earthquakes recorded over a 13-year period and GPS data recorded over an 8-month period to estimate interplate quasi-static slip associated with the 2003 Tokachi-oki earthquake (M8.0) and the 2004 off-Kushiro earthquake (M7.1). The repeating-earthquake analysis revealed that the slip rate near the source region of the Tokachi-oki earthquake was relatively low (< 5 cm/year) prior to the earthquake; however, in the last 3 years leading up to the event, a minor acceleration in slip occurred upon the deeper extension of the coseismic slip area of the earthquake. Repeating-earthquake and GPS data indicate that large amounts of afterslip occurred around the rupture area following the earthquake; the afterslip mainly propagated to the east of the coseismic slip area. We also infer that the occurrence of the 2004 off-Kushiro earthquake, located about 100 km northeast of the epicenter of the Tokachi-oki earthquake, was advanced by the afterslip associated with the Tokachi-oki earthquake.     

Assessment of future stream flow over the Sesan catchment of the Lower Mekong Basin in Vietnam

This study used a regional climate model, driven at a resolution of 30 km, to derive climate estimates that were used as input to a hydrological model to determine stream flow in a changing climate. This regional climate model output was derived using the Weather Research and Forecasting model, which was used to downscale the general circulation model ECHAM5 T63 under the A2 greenhouse gas emission scenario for the future. Two river basins, Dakbla and Poko, over the Sesan catchment of the Lower Mekong region were considered for runoff modeling. A 10‐year climatology of the recent past, 1991–2000, was used as the baseline for the present‐day climate, and another 10‐year climate over the period 2091–2100 was chosen for the future time slice. The results from the simulation of future stream flow indicate that, over both Dakbla and Poko river basins, the stream flow is likely to increase, especially during the peak rainfall season. The Dakbla River Basin shows a substantial increase in stream flow when compared with the Poko River Basin. Copyright © 2011 John Wiley & Sons, Ltd.     

High-pressure/ultrahigh-pressure eclogites from the Hong’an Block,East-Central China: geochemical characterization,isotope disequilibrium and geochronological controversy

The Hongan Block (western Dabieshan) exposes a series of HP/UHP metamorphic rocks, with a S-to-N distribution from blueschist–greenschist, kyanite-free, to kyanite- and coesite-bearing eclogites. The available age data are inconclusive that hinder our understanding of the tectonic evolution of the Block. The metamorphic temperatures in the Hongan Block (T_meta 700 to 500°C) are lower by 50–150°C than that of the Dabie and Sulu terranes. In this work, we undertook new trace element and Sr–Nd–O isotopic analyses on minerals in order to gain more insight into the geochronological problems. The results are as follows: (1) Trace element distribution patterns suggest that garnet and omphacite in many cases are out of chemical equilibrium; and the presence of high-temperature LREE-rich mineral inclusions (e.g., epidote) in garnet and omphacite has contributed to isotope disequilibrium. (2) Sm–Nd isotope analyses yielded no isochron ages for the Hongan eclogites. (3) Rb–Sr isotope analyses gave mixed results; in some cases, coexisting minerals are completely out of isotope equilibrium, and in others, isochron relationship is established, yielding ages from 210 Ma to 225 Ma. The pattern of Rb–Sr isotope disequilibrium appears to be independent of the petrological and O-isotope temperatures. (4) In contrast to the unequilibrated Sm–Nd isotopic systems, oxygen isotopes of the eclogite minerals seem to have attained isotope equilibrium or near-equilibrium. Oxygen isotope temperatures are comparable with petrological temperatures. However, this is an apparent feature due to mass balance constraints. (5) Whole-rock ¹⁸O values show a large variation from +10 to –8, suggesting that their protoliths have undergone very different processes of water–rock interaction. In view of the overall geochronological information, we conclude that the HP/UHP metamorphism in the Hongan Block took place in the Triassic at about 220–230 Ma, as observed in the Dabie and Sulu terranes. The significance of published Paleozoic dates (450–300 Ma) for the Xiongdian eclogite is not clear. However, any hypotheses advocating two periods of UHP metamorphic events for the same tectonic unit or in the same locality are not constrained by the geochronological data.Electronic Supplementary Material Supplementary material is available for this article at     

Variations of radon content in groundwaters and possible correlation with seismic activities in northern Taiwan

Radon (²²²Rn) concentration in geothermal waters and CO₂-rich cold springwaters collected weekly in duplicate samples from four stations in northern Taiwan were measured from July 1980 to December 1983. Seven spike-like radon anomalies (increases of 2 to 3 times the standard deviation above the mean) were observed at three stations. Following every anomaly except one, an earthquake ofM _L above 4.6 occurred within 4 to 51 days, at an epicentral distance 14 to 45 km, and at a focal depth of less than 10 km. The distribution of the earthquakes preceded by radon anomalies is skewed in certain directions from the radon stations; the radon stations seem to be insensitive to earthquakes occurring in the other directions. At the fourth station, near a volcanic area, much gas (mainly CO₂) is discharged from the well, together with hot water. A very high concentration of radon was detected in the discharged gas; therefore trapping of gas in the water can result in anomalously high radon contents. According to limited measurements, the radon concentration in water appears to be undersaturated with respect to that in gas. This suggests that hot water is very susceptible to radon loss, and monitoring of radon in gas is more desirable.     

Abrupt changes of intermediate-water oxygen in the northwestern Pacific during the last 27 kyr

An oxygen minimum zone (OMZ) currently exists at intermediate water depths on the northern Japanese margin in the northwestern Pacific. The OMZ results largely from a combination of high surface–water productivity and poor ventilation of intermediate waters. We investigated the late Quaternary history (last 27 kyr) of the intensity of this OMZ using changes in benthic foraminiferal carbon isotopes and assemblages in a sediment core taken on the continental slope off Shimokita Peninsula, northern Japan, at a water depth of 975 m. The core was located well within the region of the present-day OMZ and high surface–water productivity. The benthic foraminiferal δ¹³C values, which indicate millennial-scale fluctuations of nutrient contents at the sediment–water interface, were 0.48‰ lower during the last glacial maximum (LGM) than during the late Holocene. These results do not indicate the formation of glacial intermediate waters of subarctic Pacific origin, but rather the large contribution of high-nutrient water masses such as the Antarctic Intermediate Water, implying that the regional circulation pattern during the LGM was similar to that of modern times. Benthic foraminiferal assemblages underwent major changes in response to changes in dissolved oxygen concentrations in ocean floor sediments. The lowest oxygen and highest nutrient conditions, marked by dysoxic taxa and negative values of benthic foraminiferal δ¹³C, occurred during the Bølling/Allerød (B/A) and Pre-Boreal warming events. Dysoxic conditions in this region during these intervals were possibly caused by high surface–water productivity at times of reduced intermediate–water ventilation in the northwestern Pacific. The benthic assemblages show dysoxic events on approx. 100- to 200-year cycles during the B/A, reflecting centennial-scale productivity changes related to freshwater cycles and surface–water circulation in the North Pacific.     

Metamorphic record of the Asemi‐gawa eclogite unit in the Sanbagawa belt,southwest Japan: Constraints from inclusions study in garnet porphyroblasts

The Sanbagawa belt is one of the famous subduction‐related high‐pressure (HP) metamorphic belts in the world. However, spatial distributions of eclogite units in the belt have not yet satisfactorily established, except within the Besshi region, central Shikoku, southwest Japan because most eclogitic rocks were affected by lower pressure overprinting during exhumation. In order to better determine the areal distribution of the eclogite units and their metamorphic features, inclusion petrography of garnet porphyroblasts using a combination of electron probe microanalyser and Raman spectroscopy was applied to pelitic and mafic schists from the Asemi‐gawa region, central Shikoku. All pelitic schist samples are highly retrogressed, and include no index HP minerals such as jadeite, omphacite, paragonite, or glaucophane in the matrix. Garnet porphyroblasts in pelitic schists occur as subhedral or anhedral crystals, and show compositional zoning with irregular‐shaped inner segments and overgrown outer segments, the boundary of which is marked by discontinuous changes in spessartine. This feature suggests that a resorption process of the inner segment occurred prior to the formation of the outer segment, indicating discontinuous crystallization between the two segments. The inner segment of some composite‐zoned garnet grains displays Mn oscillations, implying infiltration of metamorphic fluid during the initial exhumation stage. Evidence for an early eclogite facies event was determined from mineral inclusions (e.g., jadeite, paragonite, glaucophane) in the garnet inner segments. Mafic schists include no index HP minerals in the matrix as with pelitic schists. Garnet grains in mafic schists show simple normal zoning, recording no discontinuous growth during crystal formation. There are no index HP mineral inclusions in the garnet, and thus no evidence suggesting eclogite facies conditions. Quartz inclusions in garnet of the pelitic and mafic schists show residual pressure values (?ω₁) of >8.5 cm^?1 and <8.5 cm^?1 respectively. The combination of Raman geobarometry and conventional thermodynamic calculations gives peak P–T conditions of 1.6–2.1 GPa at 460–520°C for the pelitic schists. The ?ω₁ values of quartz inclusions in mafic schists are converted to a metamorphic pressure of 1.2–1.4 GPa at 466–549°C based on Raman geothermometry results. These results indicate that a pressure gap definitely exists between the mafic schists and the almost adjacent pelitic schists, which have experienced a different metamorphic history. Furthermore, the peak P–T values of the Asemi‐gawa eclogite unit are compatible with those of Sanbagawa eclogite unit in the Besshi region of central Shikoku, suggesting that these eclogite units share a similar P–T trajectory. The Asemi‐gawa eclogite unit exists in a limited area and is composed of mostly pelitic schists. We infer that these abundant pelitic schists played a key role in buoyancy‐driven exhumation by reducing bulk rock density and strength.     

Coexisting different types of zoned garnet in kyanite‐quartz eclogites from the Sanbagawa metamorphic belt: Evidence of deformation‐induced lithological mixing during prograde metamorphism

Garnet grains in Sanbagawa quartz eclogites from the Besshi region, central Shikoku commonly show a zoning pattern consisting of core and mantle/rim that formed during two prograde stages of eclogite and subsequent epidote–amphibolite facies metamorphism, respectively. Garnet grains in the quartz eclogites are grouped into four types (I, II, III, and IV) according to the compositional trends of their cores. Type I garnet is most common and sometimes coexists with other types of garnet in a thin section. Type I core formed with epidote and kyanite during the prograde eclogite facies stage. The inner cores of types II and III crystallized within different whole‐rock compositions of epidote‐free and kyanite‐bearing eclogite and epidote‐ and kyanite‐free eclogite at the earlier prograde stage, respectively. The inner core of type IV probably formed during the pre‐eclogite facies stage. The inner cores of types II, III, and IV, which formed under different P–T conditions of prograde metamorphism and/or whole‐rock compositions, were juxtaposed with the core of type I, probably due to tectonic mixing of rocks at various points during the prograde eclogite facies stage. After these processes, they have shared the following same growth history: (i) successive crystal growth during the later stage of prograde eclogite facies metamorphism that formed the margin of the type I core and the outer cores of types II, III, and IV; (ii) partial resorption of the core during exhumation and hydration stage; and (iii) subsequent formation of mantle zones during prograde metamorphism of the epidote–amphibolite facies. The prograde metamorphic reactions may not have progressed under an isochemical condition in some Sanbagawa metamorphic rocks, at least at the hand specimen scale. This interpretation suggests that, in some cases, material interaction promoted by mechanical mixing and fluid‐assisted diffusive mass transfer probably influences mineral reactions and paragenesis of high‐pressure metamorphic rocks.     

Analytical method for stable background reduction for Raman spectra of carbon-containing meteorite and terrestrial samples suffering from intense fluorescence

Chemical states of carbon in terrestrial (meta) sediments and carbonaceous chondrites gather attention as a geothermometer. As a nondestructive analytical method, Raman spectroscopy has been widely used to study their electronic properties, crystallinity, and structural defects through so-called D and G bands. For the analysis of Raman spectra, a common problem is coexistence of a fluorescence background, which should be subtracted prior to the peak-fitting analysis. However, we recently faced a problem that the band shape noticeably changed depending on the background function assumed although the background seemed to be well subtracted at a first glance regardless of the choice of the background function. For the application of the Raman spectroscopy as a geothermometer, a standard background subtraction method must be established to suppress the arbitrariness. In the present study, Raman spectra of seven carbon-containing natural samples, whose background intensities were significantly different, were measured, and their background shape was evaluated by first-, second-, and third-order polynomials. The results indicated that the third-order polynomial was necessary and sufficient as a standard background function. Importantly, although lower order polynomials seem to successfully fit the background at a first glance, they falsely caused dispersion of the shoulder band shape.     

Clumped isotope composition of marbles from the Backbone Range of Taiwan

The clumped isotope composition of carbonates provides a new way to retrieve temperatures for ancient geological systems without knowing the isotopic compositions of co‐existing fluid/minerals. The application of this new thermometer in the past decade, however, has been largely restricted to low‐temperature (<~250 °C) geological processes. In this study, we present clumped isotope analyses for marbles collected from the Backbone Range of Taiwan, which has been subjected to greenschist facies metamorphism during the ongoing arc–continent collision. We find that the ∆₄₇ temperatures either indicate temperatures of the last dynamic open‐system recrystallization of marbles due to tectonic movement/stress or signify closed‐system closure temperatures during rock exhumation, demonstrating that clumped information from marbles has great potential for revealing process characteristics during mountain building.     

US-Russian Civilian Research and Development Fund Project： An origin of microdiamonds in metamorphic rocks of the Kokchetav Massif, Northern Kazakhstan

The Kokchetav Massif of northern Kazakhstan is a typelocality of occurrence of microdiamonds in ultrahighpressure metamorphic“ rocks. It records continental subduction and exhumation from depths greater than 120 km and provides unparalleled insights into mantle dynamics, global material recycling and the processes responsible for the genesis and destruction of continent. Through the support of a US Civilian Development and Research Fund, a group of Russian, US, Taiwanese and Kazakhstan geologists visited the reconstructed 800-m underground gallery to conduct field survey and sample collections. This gallery provides a useful geologic laboratory for international community to undertake similar geotectonic or different ecological and environmental studies.